51.
    发明专利
    未知

    公开(公告)号:FR2488263B1

    公开(公告)日:1986-05-02

    申请号:FR8114956

    申请日:1981-07-31

    Applicant: DEGUSSA

    Abstract: The invention relates to complex compounds of rhodium, iridium or ruthenium with a silicic acid-like structure with a least one phosphine ligand, the trivalent phosphorus of which is bonded to silicon via at least one divalent organic residue, the remaining three valences of the silicon building, via oxygen bridges arising from the hydrolysis of functional substituents originally bound there, a inter- or intra-molecularly crosslinked polycondensate. The required charge equalization is effected by an anion. Also disclosed are processes for recovery of the polymeric complexes and their use in heterogeneous catalysis of various chemical reactions.

    PROCEDEU SI DISPOZITIV PENTRU OBTINEREA ACIDULUI CIANHIDRIC

    公开(公告)号:RO84538B

    公开(公告)日:1984-08-30

    申请号:RO10198380

    申请日:1980-08-15

    Applicant: DEGUSSA

    Abstract: Prezenta inventie se refera la un procedeu pentru obtinerea acidului cianhidric dupa asa numitul procedeu BMA, procedeu ce consta în insuflarea, totala sau partiala, a amestecului de gaze format din amoniac si hidrocarburi alifatice cu catena scurta, de preferinta metan, printr-un tub de introducere prevazut cu unul sau mai multe orificii, dispus în tubul de reactie, la o presiune preliminare de cel putin 1,2 bar, amestecul gazos fiind lasat sa curga cu o viteza de peste circa 200m/s din orificiile tubului, dupa care gazele produse sunt prelucrate în mod obisnuit. Drept hidrocarburi ce pot fi luate în consideratie, în afara de metan, ca hidrocarburi alifatice cu 3 si 4 atomi de carbon, sunt gazele lichefiate propan, n-butan si i-butan, la utilizarea acestor gaze lichefiate trebuind sa fie prezent si hidrogenul, si anume, într-un raport atomic C:N:H de 1:1:7,1 pîna la 1:1,33:12. în prezent, la scara industriala se utilizeaza, în special, metan, care se foloseste atît în stare pura, cît si sub forma obisnuita, de exemplu ca gaz de pamînt sau gaz de rafinarie. în cazul utilizarii gazului de pamînt si a gazului de rafinarie, se prefera gazele cu un continut total de metan de 60 pîna aproape de 100% în volume, care contin doar mici cantitati de hidrocarburi superioare...

    BIS-(SILYL-ETHYL)-OLIGOSULPHIDES AND A PROCESS FOR THEIR PRODUCTION

    公开(公告)号:CA1144936A

    公开(公告)日:1983-04-19

    申请号:CA342418

    申请日:1979-12-20

    Applicant: DEGUSSA

    Abstract: Bis-(silyl-ethyl)-oligosulphide obtained by reacting a vinyl silane having the formula (CH2=CH)m-SiR?R4-(m+n) wherein R represents chlorine, iodine, C1-C3-alkoxy, 2-methoxy-ethoxy, 2-ethoxy-ethoxy or hydroxy, R1 represents C1-C3-alkyl, phenyl or C5-C7-cycloalkyl, n is 0, 1 or 2, m is 1 or 2 and m + n is 1, 2 or 3, with sulphur and, when required, with hydrogen sulphide in a molar ratio ranging from 1:2.5 to 1:10 and of vinyl silane to hydrogen sulphide from 1:0 to 0:5 at a temperature between approximately 100 and 200.degree.C under a pressure ranging from 1 to 25 bars (total pressure at the reaction temperature) and in the presence of Sulphidation catalysts and when required hydrolysis or partial hydrolysis of the reaction product. The corresponding process of production and the use of a bis-(silyl-ethyl)-oligosulphide as a reinforcing additive (adhesion promoter) in a crosslinkable rubber mixture containing a silicate filler and when required carbon black as well as sulphur and other conventional mixture components are also disclosed.

    A METHOD OF PREPARING HYDROGEN CYANIDE

    公开(公告)号:ZA816619B

    公开(公告)日:1982-09-29

    申请号:ZA816619

    申请日:1981-09-23

    Applicant: DEGUSSA

    Abstract: In order to be independent of the situation in regard to methane and natural gas and at the same time to obtain a heating gas there is employed in the hydrocyanic acid-methane-ammonia process (the BMA process) in place of methane an alkanol or alkanediol having 2-4 carbon atoms, preferably ethyl alcohol, and this is reacted with ammonia in a C:N ratio of 0.8:1 to 2:1. Optionally additional hydrogen can be present.

    55.
    发明专利
    未知

    公开(公告)号:BR8104922A

    公开(公告)日:1982-08-31

    申请号:BR8104922

    申请日:1981-07-30

    Applicant: DEGUSSA

    Abstract: In order to be independent of the situation in regard to methane and natural gas and at the same time to obtain a heating gas there is employed in the hydrocyanic acid-methane-ammonia process (the BMA process) in place of methane an alkanol or alkanediol having 2-4 carbon atoms, preferably ethyl alcohol, and this is reacted with ammonia in a C:N ratio of 0.8:1 to 2:1. Optionally additional hydrogen can be present.

    56.
    发明专利
    未知

    公开(公告)号:DD153805A5

    公开(公告)日:1982-02-03

    申请号:DD22364480

    申请日:1980-09-01

    Applicant: DEGUSSA

    Abstract: By introducing the reaction gas mixture of hydrocarbons and ammonia at increased velocity through an inlet tube with one or more openings in a customary reaction tube in the hydrocyanic acid-methane-ammonia (BMA) process the yield of HCN is increased considerably.

    59.
    发明专利
    未知

    公开(公告)号:DE3685999D1

    公开(公告)日:1992-08-20

    申请号:DE3685999

    申请日:1986-05-15

    Applicant: DEGUSSA

    Abstract: New organopolysiloxanes contain units of formula in which all 3 isomers, w.r.t. the position of the SiO3/2-R1 gps., may be present. In(I), R1 = -CH2CH2- or CH3-CH=; The free valencies of the O atom may be satd. by the Si atoms of further gps. of formula (I) and/or by cross-linking bridging gps. of formula MO4/2, R'MO3/2, (R')MO2/2, AlO3/2 or R'AlO2/2; the ratio of the sum of the Si atoms in I:Si, Ti, Zr or Al in the bridging gps. is 1:0-15. M = Si, Ti or Zr; R' = Me or Et.

Patent Agency Ranking