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公开(公告)号:FR2488263B1
公开(公告)日:1986-05-02
申请号:FR8114956
申请日:1981-07-31
Applicant: DEGUSSA
Inventor: PANSTER PETER , KLEINSCHMIT PETER
Abstract: The invention relates to complex compounds of rhodium, iridium or ruthenium with a silicic acid-like structure with a least one phosphine ligand, the trivalent phosphorus of which is bonded to silicon via at least one divalent organic residue, the remaining three valences of the silicon building, via oxygen bridges arising from the hydrolysis of functional substituents originally bound there, a inter- or intra-molecularly crosslinked polycondensate. The required charge equalization is effected by an anion. Also disclosed are processes for recovery of the polymeric complexes and their use in heterogeneous catalysis of various chemical reactions.
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公开(公告)号:RO84538B
公开(公告)日:1984-08-30
申请号:RO10198380
申请日:1980-08-15
Applicant: DEGUSSA
Inventor: BITTNER FRIEDRICH , VOIGT KARL , KLEINSCHMIT PETER
IPC: C01C3/02
Abstract: Prezenta inventie se refera la un procedeu pentru obtinerea acidului cianhidric dupa asa numitul procedeu BMA, procedeu ce consta în insuflarea, totala sau partiala, a amestecului de gaze format din amoniac si hidrocarburi alifatice cu catena scurta, de preferinta metan, printr-un tub de introducere prevazut cu unul sau mai multe orificii, dispus în tubul de reactie, la o presiune preliminare de cel putin 1,2 bar, amestecul gazos fiind lasat sa curga cu o viteza de peste circa 200m/s din orificiile tubului, dupa care gazele produse sunt prelucrate în mod obisnuit. Drept hidrocarburi ce pot fi luate în consideratie, în afara de metan, ca hidrocarburi alifatice cu 3 si 4 atomi de carbon, sunt gazele lichefiate propan, n-butan si i-butan, la utilizarea acestor gaze lichefiate trebuind sa fie prezent si hidrogenul, si anume, într-un raport atomic C:N:H de 1:1:7,1 pîna la 1:1,33:12. în prezent, la scara industriala se utilizeaza, în special, metan, care se foloseste atît în stare pura, cît si sub forma obisnuita, de exemplu ca gaz de pamînt sau gaz de rafinarie. în cazul utilizarii gazului de pamînt si a gazului de rafinarie, se prefera gazele cu un continut total de metan de 60 pîna aproape de 100% în volume, care contin doar mici cantitati de hidrocarburi superioare...
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公开(公告)号:CA1144936A
公开(公告)日:1983-04-19
申请号:CA342418
申请日:1979-12-20
Applicant: DEGUSSA
Inventor: SCHWARZ RUDOLF , KLEINSCHMIT PETER , LIEDTKE CHRISTA , WOLFF SIEGFRIED
IPC: C08L7/00 , C07F7/08 , C07F7/12 , C07F7/18 , C08G75/02 , C08G75/14 , C08K5/5425 , C08K5/548 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L101/00 , C08K5/54
Abstract: Bis-(silyl-ethyl)-oligosulphide obtained by reacting a vinyl silane having the formula (CH2=CH)m-SiR?R4-(m+n) wherein R represents chlorine, iodine, C1-C3-alkoxy, 2-methoxy-ethoxy, 2-ethoxy-ethoxy or hydroxy, R1 represents C1-C3-alkyl, phenyl or C5-C7-cycloalkyl, n is 0, 1 or 2, m is 1 or 2 and m + n is 1, 2 or 3, with sulphur and, when required, with hydrogen sulphide in a molar ratio ranging from 1:2.5 to 1:10 and of vinyl silane to hydrogen sulphide from 1:0 to 0:5 at a temperature between approximately 100 and 200.degree.C under a pressure ranging from 1 to 25 bars (total pressure at the reaction temperature) and in the presence of Sulphidation catalysts and when required hydrolysis or partial hydrolysis of the reaction product. The corresponding process of production and the use of a bis-(silyl-ethyl)-oligosulphide as a reinforcing additive (adhesion promoter) in a crosslinkable rubber mixture containing a silicate filler and when required carbon black as well as sulphur and other conventional mixture components are also disclosed.
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公开(公告)号:ZA816619B
公开(公告)日:1982-09-29
申请号:ZA816619
申请日:1981-09-23
Applicant: DEGUSSA
Inventor: VOIGT CARL , KLEINSCHMIT PETER , SCHREYER GERD , SPERKA GERHARD
Abstract: In order to be independent of the situation in regard to methane and natural gas and at the same time to obtain a heating gas there is employed in the hydrocyanic acid-methane-ammonia process (the BMA process) in place of methane an alkanol or alkanediol having 2-4 carbon atoms, preferably ethyl alcohol, and this is reacted with ammonia in a C:N ratio of 0.8:1 to 2:1. Optionally additional hydrogen can be present.
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公开(公告)号:BR8104922A
公开(公告)日:1982-08-31
申请号:BR8104922
申请日:1981-07-30
Applicant: DEGUSSA
Inventor: VOIGT CARL , KLEINSCHMIT PETER , SCHREYER GERD , SPERKA GERHARD
Abstract: In order to be independent of the situation in regard to methane and natural gas and at the same time to obtain a heating gas there is employed in the hydrocyanic acid-methane-ammonia process (the BMA process) in place of methane an alkanol or alkanediol having 2-4 carbon atoms, preferably ethyl alcohol, and this is reacted with ammonia in a C:N ratio of 0.8:1 to 2:1. Optionally additional hydrogen can be present.
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公开(公告)号:DD153805A5
公开(公告)日:1982-02-03
申请号:DD22364480
申请日:1980-09-01
Applicant: DEGUSSA
Inventor: BITTNER FRIEDRICH , VOIGT CARL , KLEINSCHMIT PETER
IPC: C01C3/02
Abstract: By introducing the reaction gas mixture of hydrocarbons and ammonia at increased velocity through an inlet tube with one or more openings in a customary reaction tube in the hydrocyanic acid-methane-ammonia (BMA) process the yield of HCN is increased considerably.
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公开(公告)号:CA2040792C
公开(公告)日:1997-03-04
申请号:CA2040792
申请日:1991-04-18
Applicant: DEGUSSA
Inventor: BRAND REINHOLD , ENGLER BERND , FOERSTER MARTIN , HARTMANN WERNER , KLEINSCHMIT PETER , KOBERSTEIN EDGAR , OHMER JOHANNES , SCHWARZ RUDOLF
Abstract: Manufacturing of titanium dioxide pressed articles wherein pyrogenically produced titanium dioxide in the presence of completely demineralized water is intensively mixed with a wetting agent and/or a base and/or, optionally, a binder and/or, optionally, a shaping adjuvant and/or, optionally, an expanding agent, the resulting material is extruded into moulded members at pressures between 5 and 100 bar, and the moulded members are dried at temperatures between 50 and 120.degree.C and then calcined in atmospheric air at temperatures of 400 to 700.degree.C for 1 to 5 hours.
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公开(公告)号:HRP920744A2
公开(公告)日:1995-06-30
申请号:HRP920744
申请日:1992-10-01
Applicant: DEGUSSA
Inventor: SEXTL GERHARD , REUTER ROLAND , STRACK HANS , KLEINSCHMIT PETER , SCHWARZ RUDOLF
IPC: B32B7/02 , B32B5/16 , B32B27/08 , B65D81/18 , B65D81/38 , C04B14/36 , C04B38/00 , E04B1/80 , F16L59/00 , F16L59/02 , F25D23/06
Abstract: Element, preferably in panel form, for use as thermal insulation, comprising …… a) a finely dispersed, pulverulant or fibrous substance, … b) a microporous covering and … c) a gas-tight and water-proof metal-free covering. …… The element is produced by drying the pulverulant or fibrous substance, if appropriate, introducing it into a microporous covering, if appropriate, compressing it, if appropriate, and then drying it, if appropriate. After that, the pulverulant substance with the microporous covering is introduced into a gas-tight and water-proof, metal-free covering. If appropriate, this gas-tight and water-proof covering is evacuated and sealed. … …
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公开(公告)号:DE3685999D1
公开(公告)日:1992-08-20
申请号:DE3685999
申请日:1986-05-15
Applicant: DEGUSSA
Inventor: PANSTER PETER , KLEINSCHMIT PETER
Abstract: New organopolysiloxanes contain units of formula in which all 3 isomers, w.r.t. the position of the SiO3/2-R1 gps., may be present. In(I), R1 = -CH2CH2- or CH3-CH=; The free valencies of the O atom may be satd. by the Si atoms of further gps. of formula (I) and/or by cross-linking bridging gps. of formula MO4/2, R'MO3/2, (R')MO2/2, AlO3/2 or R'AlO2/2; the ratio of the sum of the Si atoms in I:Si, Ti, Zr or Al in the bridging gps. is 1:0-15. M = Si, Ti or Zr; R' = Me or Et.
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60.
公开(公告)号:AT77617T
公开(公告)日:1992-07-15
申请号:AT88116479
申请日:1988-10-05
Applicant: DEGUSSA
Inventor: LOTZE MARION , MEHNER HANS , KLEINSCHMIT PETER
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