-
公开(公告)号:DE60133726D1
公开(公告)日:2008-06-05
申请号:DE60133726
申请日:2001-03-14
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: ARGYROPOULOS JOHN NICHOLAS , KANEL JEFFREY SCOTT , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES , MORRISON DONALD LEE , FOLEY PAUL , BRYANT DAVID ROBERT , PHILLIPS AILENE GARDNER , ROESCH BRIAN MICHAEL , BRIGGS JOHN ROBERT , LEE MAX MIN , MAHER JOHN MICHAEL
IPC: B01D11/04 , C07B63/00 , B01J23/46 , B01J31/18 , B01J31/24 , B01J31/40 , B01J38/00 , C07B61/00 , C07C45/50 , C07C45/80 , C07C47/19 , C07F9/02
Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more nonpolar solvents and one or more polar solvents by phase separation wherein (i) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1which is a value greater than about 2.5, (ii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
-
公开(公告)号:CA2239696C
公开(公告)日:2007-05-22
申请号:CA2239696
申请日:1996-12-05
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: BRYANT DAVID ROBERT , NICHOLSON JAMES CLAIR , BUNNING DONALD LEROY , EISENSCHMID THOMAS CARL , MORRISON DONALD LEE
IPC: C07B61/00 , C07C45/50 , B01J19/18 , B01J27/18 , B01J31/02 , B01J31/18 , B01J31/22 , B01J31/40 , B01J38/74 , C07C45/49 , C07C47/02 , C07C47/228 , C07C47/277 , C07C51/00 , C07C51/255 , C07C51/265 , C07C51/42 , C07C51/43 , C07C63/00 , C07C63/15 , C07C63/26 , C07C67/347 , C07C69/716 , C07D209/46 , C07D333/22 , C07F9/02 , C07F9/141 , C07F9/145 , C07F9/50 , C07F9/6571 , C07F9/6574 , C07F15/00 , F04D25/08 , F04D29/28
Abstract: This invention relates to a process which comprises reacting one or more reactants in the presence of a metal-organophosphite ligand complex catalyst and dissolved water and optionally free organophosphite ligand to produce a reaction product fluid comprising one or more products, wherein said process is conducted in the presence of carbon dioxid e in an amount sufficient not to effect substantial degradation of any said organophosphite ligand and/or substantial deactivation of said metal-organophosphite ligand complex catalyst.
-
公开(公告)号:AT289577T
公开(公告)日:2005-03-15
申请号:AT99905553
申请日:1999-02-01
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: ARGYROPOULOS JOHN N , BRYANT DAVID ROBERT , MORRISON DONALD LEE , STOCKMAN KENNETH ELWOOD , ABATJOGLOU ANTHONY GEORGE
IPC: B01J31/18 , B01J31/40 , C07B63/00 , C07C45/50 , C07C45/80 , C07C49/92 , C07C51/373 , C07C51/48 , C07C59/147 , C07F9/02 , C07F9/50 , C07F9/655 , C07F9/6574
Abstract: This invention relates to a process for separating one or more products from a reaction product fluid comprising a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, a polar solvent and said one or more products, wherein said process comprises (1) mixing said reaction product fluid with a nonpolar solvent to obtain by phase separation a polar phase comprising said metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand and said polar solvent and a nonpolar phase comprising said one or more products and nonpolar solvent, and (2) recovering said nonpolar phase from said polar phase; wherein said organophosphorus ligand has a partition coefficient between the polar solvent and the nonpolar solvent of greater than about 10, and said one or more products have a partition coefficient between the nonpolar solvent and the polar solvent of greater than about 0.5.
-
公开(公告)号:RU2207332C2
公开(公告)日:2003-06-27
申请号:RU2000122844
申请日:1999-02-01
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: ARGYROPOULOS JOHN N , BRYANT DAVID ROBERT , MORRISON DONALD LEE , STOCKMANN KENNETH ELWOOD
IPC: B01J31/18 , B01J31/40 , C07B63/00 , C07C45/50 , C07C45/80 , C07C47/02 , C07C51/373 , C07C51/48 , C07C59/147 , C07F9/02 , C07F9/144 , C07F9/145 , C07F9/50 , C07F9/6574
-
公开(公告)号:NO20024359L
公开(公告)日:2002-11-13
申请号:NO20024359
申请日:2002-09-12
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: ARGYROPOULOS JOHN NICHOLAS , KANEL JEFFREY SCOTT , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES , MORRISON DONALD LEE , FOLEY PAUL , BRYANT DAVID ROBERT , PHILLIPS AILENE GARDNER , ROESCH BRIAN MICHAEL , BRIGGS JOHN ROBERT , LEE MAX MIN , MAHER JOHN MICHAEL
IPC: B01D11/04 , B01J23/46 , B01J31/18 , B01J31/24 , B01J31/40 , B01J38/00 , C07B61/00 , C07B63/00 , C07C45/50 , C07C45/80 , C07C47/19 , C07F9/02 , B01J31/00
Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more nonpolar solvents and one or more polar solvents by phase separation wherein (i) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1which is a value greater than about 2.5, (ii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
-
公开(公告)号:NO20024359A
公开(公告)日:2002-11-13
申请号:NO20024359
申请日:2002-09-12
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: ARGYROPOULOS JOHN NICHOLAS , KANEL JEFFREY SCOTT , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES , MORRISON DONALD LEE , FOLEY PAUL , BRYANT DAVID ROBERT , PHILLIPS AILENE GARDNER , ROESCH BRIAN MICHAEL , BRIGGS JOHN ROBERT , LEE MAX MIN , MAHER JOHN MICHAEL
IPC: B01D11/04 , B01J23/46 , B01J31/18 , B01J31/24 , B01J31/40 , B01J38/00 , C07B61/00 , C07B63/00 , C07C45/50 , C07C45/80 , C07C47/19 , C07F9/02 , B01J31/00
CPC classification number: C07C45/50 , C07B63/00 , Y02P20/582 , C07C47/02
-
公开(公告)号:NO20024357A
公开(公告)日:2002-10-25
申请号:NO20024357
申请日:2002-09-12
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: ARGYROPOULOS JOHN NICHOLAS , KANEL JEFFREY SCOTT , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES , MORRISON DONALD LEE , FOLEY PAUL , BRYANT DAVID ROBERT
IPC: B01J31/40 , B01J31/00 , B01J38/00 , C07B61/00 , C07B63/00 , C07C29/136 , C07C31/20 , C07C67/31 , C07C67/313 , C07C67/58 , C07C69/675 , C07C69/716 , C07C227/02 , C07C227/08 , C07C229/08
CPC classification number: C07B63/00 , C07C67/58 , Y02P20/582 , C07C69/716
-
公开(公告)号:NO20024358D0
公开(公告)日:2002-09-12
申请号:NO20024358
申请日:2002-09-12
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: ARGYROPOULOS JOHN NICHOLAS , KANEL JEFFREY SCOTT , TULCHINSKY MICHAEL LEO , MILLER DAVID JAMES , MORRISON DONALD LEE , FOLEY PAUL , BRYANT DAVID ROBERT , PHILLIPS AILENE GARDNER , ROESCH BRIAN MICHAEL , BRIGGS JOHN ROBERT , LEE MAX MIN , MAHER JOHN MICHAEL
Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more polar solvents and one or more nonpolar solvents by phase separation wherein (i) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
-
公开(公告)号:BR9908212A
公开(公告)日:2001-10-30
申请号:BR9908212
申请日:1999-02-01
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: ARGYROPOULOS JOHN N , BRYANT DAVID ROBERT , MORRISON DONALD LEE , STOCKMANN KENNETH ELWOOD
IPC: B01J31/18 , B01J31/40 , C07B63/00 , C07C45/50 , C07C45/80 , C07C47/02 , C07C51/373 , C07C51/48 , C07C59/147 , C07F9/02 , C07F9/144 , C07F9/145 , C07F9/50 , C07F9/6574
Abstract: This invention relates to a process for separating one or more products from a reaction product fluid comprising a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, a nonpolar solvent and said one or more products, wherein said process comprises (1) mixing said reaction product fluid with a polar solvent to obtain by phase separation a non-polar phase comprising said metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand and said nonpolar solvent and a polar phase comprising said one or more products and polar solvent, and (2) recovering said polar phase from said nonpolar phase; wherein said organophosphorus ligand has a partition coefficient between the nonpolar solvent and the polar solvent of greater than about 5, and said one or more products have a partition coefficient between the polar solvent and the nonpolar solvent of greater than about 0.5.
-
公开(公告)号:CA2403088A1
公开(公告)日:2001-09-20
申请号:CA2403088
申请日:2001-03-14
Applicant: UNION CARBIDE CHEM PLASTIC
Inventor: FOLEY PAUL , ROESCH BRIAN MICHAEL , MILLER DAVID JAMES , BRIGGS JOHN ROBERT , ARGYROPOULOS JOHN NICHOLAS , TULCHINSKY MICHAEL LEO , MORRISON DONALD LEE , MAHER JOHN MICHAEL , LEE MAX MIN , PHILLIPS AILENE GARDNER , BRYANT DAVID ROBERT , KANEL JEFFREY SCOTT
Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more polar solvents and one or more nonpolar solvents by phase separation wherein (i) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
-
-
-
-
-
-
-
-
-