Abstract:
Provided are a butyraldehyde dehydrogenase (Bld) mutant, a polynucleotide having a nucleotide coding the same, a vector including the polynucleotide, a microorganism including the nucleotide coding the mutant, and a method for producing 1,4-butanediol using the same.
Abstract:
PURPOSE: An electrode active material is provided to prevent the deterioration of a battery in high temperature and high voltage condition. CONSTITUTION: An electrode active material comprises a core; and a coating layer formed on at least a part of the core. The coating layer comprises an alkali metal and a composite metal halogenide containing two or more metals. A manufacturing method for the electrode active material comprises: a step of contacting a core, which comprises a positive electrode active material or negative electrode active material, with a composite metal halogenide or a precursor thereof, which contains an alkali metal and a metal of an oxidation number of two or more; and a step of selectively sintering the result.
Abstract:
PURPOSE: An electrode active material is provided to improve high-temperature stability, high-temperature life time and high rate performance of lithium battery by surface-treating a core which can absorb and emit lithium by lithium-non-containing oxide with spinel structure. CONSTITUTION: An electrode active material comprises: a core capable of absorbing and emitting lithium; a surface treatment layer formed on at least a part of the core. The surface treatment layer comprises lithium-non-containing oxide with a spinel structure. A manufacturing method of the electrode active material comprises a step of preparing an outcome by contacting a core, which comprises a positive electrode active material or negative electrode active material, and the lithium-non-containing oxide with a spinel structure or precursor thereof; and a step of selectively sintering the outcome.
Abstract:
PURPOSE: An electrolyte for lithium secondary battery is provided to prevent oxidation of an electrolyte in a positive electrode surface, and to prevent decomposition of the electrolyte in high temperature condition. CONSTITUTION: An electrolyte for lithium secondary battery comprises lithium salt, non-aqueous organic solvent, and additives. The additives are one or more selected from vitamin G(riboflavin), vitamine B3(niacin), vitamin B4(adenine), vitamin B5(patothenic acid), vitamin H(biotin), vitamin M(folic acid), vitamin BX(4-aminobenzoic acid), vitamin D2(ergocalciferol) vitamin D3 cholecalciferol, vitamin K1 (phylloquinone), palmitoyl ascrobic acid, or sodium ascorbate. A comprised amount of the additives is 0.005-5 weight% based on total weight of the electrolyte.
Abstract:
PURPOSE: An electrolyte is provided to have long life time in high temperatures and preservative properties in high temperatures by forming a polar thin film, and to have excellent lithium ion transfer ability by comprising a polar hydroxy group. CONSTITUTION: An electrolyte for lithium secondary battery comprises lithium salt, non-aqueous organic solvent, and an additive in chemical formula 1. In chemical formula 1, R1, R2, R3 and R4 is respectively hydrogen, halogen, hydroxy, a -N(R)(R') group, an ester group, a carbonate group, a carbonyl group, a nitro group, a cyano group, a thio group, a substituted or unsubstituted C1-20 alkyl group, a substituted or unsubstituted C1-20 alkyl group, a substituted or unsubstituted C1-20 alkoxy group, a substituted or unsubstituted C2-20 alkenyl group, a substituted or unsubstituted C2-20 alkynyl group, a C2-20 alkylene oxide group, a substituted or unsubstituted C3-30 cycloalkyl group, a substituted or unsubstituted C6-30 aryl group, a substituted or unsubstituted C6-30 aryloxy group, a substituted or unsubstituted C6-30 heteroaryl group, or combinations thereof.
Abstract:
PURPOSE: An electrolyte for lithium secondary battery is provided to prevent the oxidation of electrolyte on the surface of a positive electrode, and to prevent the eruption of metal ion of a positive electrode active material under high temperature condition. CONSTITUTION: An electrolyte for lithium secondary battery comprises a lithium salt, non-aqueous organic solvent, and an additive. The additive is a phenanthroline based compound containing one or more kinds of polar substituents selected from an alkoxy group, an amine group, an ester group, a carbonate group, a carbonyl group, a keto group, an epoxy group, and an alkylthio group. A lithium secondary battery comprises a positive electrode, a negative electrode, and the electrolyte. The positive electrode comprises a film formed on surface thereof. The film is originated from a part or whole of the additive in the electrolyte.