公开(公告)号：KR1020120118240A

公开(公告)日：2012-10-26

申请号：KR1020110035698

申请日：2011-04-18

Applicant: 한국화학연구원

Inventor： 황진수 ,  장종산 ,  드니쉬쿠마미스라 ,  강인중 ,  하산주바르 ,  칸나쯔물아베딘 ,  정성화

IPC: C07F11/00 ,  B01J31/16 ,  C07D493/04 ,  B01J20/22

CPC classification number: C07F11/00 ,  B01D2257/60 ,  B01J20/226 ,  B01J20/28066 ,  B01J20/3085 ,  B01J31/1616 ,  B01J35/1028 ,  B01J37/00 ,  C07C1/24

Abstract: PURPOSE: A functionalizing method of porous metal-organic backbone materials, a solid catalyst using the same and a hydration method using the same are provided to effectively dehydrate alcohol as being operated as solid acid catalyst. CONSTITUTION: A functionalizing method of porous metal-organic backbone materials comprises the following steps: manufacturing suspended solution by mixing a compound which concurrently has thiol group and a location which can be coordinated with the porous metal - organic backbone material; heating the suspended solution from the first step; oxidizing the heated suspended solution with an oxidizer or oxidizing solid material obtained by solid-liquid separating the heated suspended solution by using the oxidizer; separating the solid from the reactant; and drying the separated solid.

Abstract translation: 目的：提供多孔金属有机骨架材料的功能化方法，使用其的固体催化剂和使用其的水合方法，以有效地将醇作为固体酸催化剂进行脱水。 构成：多孔金属有机骨架材料的功能化方法包括以下步骤：通过混合同时具有硫醇基的化合物和可与多孔金属 - 有机骨架材料配位的位置制备悬浮溶液; 从第一步加热悬浮溶液; 通过使用氧化剂将加热的悬浮溶液进行固液分离而获得的氧化剂或氧化性固体物质氧化加热的悬浮液; 从反应物中分离固体; 并干燥分离的固体。

公开(公告)号：KR100867665B1

公开(公告)日：2008-11-10

申请号：KR1020070108908

申请日：2007-10-29

Applicant: 한국화학연구원

Inventor： 황영규 ,  장종산 ,  정성화 ,  황진수 ,  이혜영

IPC: C01G3/00 ,  C01B17/00 ,  C01B19/00 ,  C01G15/00

CPC classification number: C01B19/002 ,  B82Y30/00 ,  C01P2002/72 ,  C01P2004/64 ,  Y10S977/777 ,  Y10S977/813

Abstract: A manufacturing method of chalcopyrite type compound by radiating a microwave is provided to supply the chalcopyrite type compound in which non-interactant or oxide is not mixed by improving solubilities of the VI family elemental powder Cu salt which is generated reactant when manufacturing the chalcopyrite type compound consisting of III family element and VI family element, III family element and VI family elemental powder, and to mass-produce efficiently a high purity of chalcopyrite compound because a reaction time is short and a non-interactant does not remain. A mixed solution is manufactured by mixing a Cu salt, a III group element salt and a Vl family elemental powder into a mixture of a chelating agent, and an ionic liquid or the chelating agent and the ionic liquid. The mixed solution is injected in a reactor and heat by irradiating a microwave. The Chalcopyrite type compound is expressed by chemical formula 1 of CuM^1M^22. In the chemical formula 1, M is one or more selected from the III group element. M is one or more selected from the Vl group element.

Abstract translation: 提供通过辐射微波的黄铜矿型化合物的制造方法，通过提高在制造黄铜矿型化合物时产生的反应物的VI族元素粉末Cu盐的溶解度来提供不混合不相互作用剂或氧化物的黄铜矿型化合物 由III族元素和VI族元素，III族元素和VI族元素粉末组成，并且由于反应时间短并且不残留非相互作用剂，因此有效地大量生产高纯度的黄铜矿化合物。 通过将Cu盐，III族元素盐和Vl族元素粉末混合到螯合剂和离子液体或螯合剂和离子液体的混合物中来制备混合溶液。 将混合溶液注入反应器中并通过照射微波加热。 黄铜矿型化合物由CuM ^ 1M ^ 22的化学式1表示。 在化学式1中，M是选自III族元素中的一种或多种。 M是从Vl组元素中选择的一个或多个。

公开(公告)号：KR100803964B1

公开(公告)日：2008-02-18

申请号：KR1020060127343

申请日：2006-12-13

Applicant: 한국화학연구원

Inventor： 장종산 ,  황영규 ,  정성화 ,  홍도영 ,  서유경

IPC: B01J20/00 ,  B01J20/02 ,  B01J20/22

CPC classification number: Y02A50/235

Abstract: A porous organic-inorganic hybrid and a moisture adsorbent using the same are provided to increase the amount of adsorbed moisture and facilitate the desorption of moisture even at a temperature of no more than 100°C, by using an iron-containing porous organic-inorganic hybrid. A moisture adsorbent is formed by using iron-terephthalate or iron-benzene tricarbonate. The moisture adsorbent is produced by heating a reactant mixture solution through electric heating and microwave irradiation. The reactant mixture solution is prepared by an iron precursor such as iron or iron salt, an organic ligand such as terephthalic acid or benzene tricarboxylic acid, a solvent, and a reaction accelerant such as a mixture of hydrofluoric acid and nitric acid. The moisture adsorbent has a surface area of 1,700-10,000 m^2/g and a pore volume of 0.8-10 mL/g. Further, a temperature of heating the reactant mixture solution is 100-250°C.

Abstract translation: 提供一种多孔有机 - 无机杂化物和使用该多孔有机 - 无机杂化物的水分吸附剂，以增加吸附水分的含量，并且即使在不超过100℃的温度下，也可通过使用含铁多孔有机 - 无机物 混合。 通过使用对苯二甲酸铁或三苯甲酸铁形成水分吸附剂。 通过电加热和微波照射加热反应物混合物溶液来制备水分吸附剂。 反应物混合物溶液通过铁或铁盐等铁前体，对苯二甲酸或苯三甲酸等有机配体，溶剂以及氢氟酸和硝酸的混合物等反应促进剂制备。 水分吸附剂的表面积为1,700-10,000m 2 / g，孔体积为0.8-10mL / g。 此外，加热反应物混合溶液的温度为100-250℃。

公开(公告)号：KR100786613B1

公开(公告)日：2007-12-21

申请号：KR1020060086303

申请日：2006-09-07

Applicant: 한국화학연구원

Inventor： 정성화 ,  장종산 ,  윤지웅 ,  이지선 ,  이희두 ,  추대현 ,  이성준

IPC: C07C2/34 ,  C07C2/08 ,  C07C2/24

Abstract: A method for preparing an olefin trimer and a method for preparing an alkylate having a high boiling point by using the olefin timer are provided to increase conversion rate and yield. An olefin trimer is prepared by using an acid catalyst comprising both Bronsted acid and Lewis acid or an acid catalyst obtained by sintering or washing the acid catalyst. Preferably the acid catalyst is prepared by introducing BF3, BCl3, BI3, SbF5, SbCl5, AlCl3, AlBr3, TiCl4, TiBr4, ZrCl4, PF5, FeCl3, FeBr3, SnBr4 or SnCl4 to a porous body such as hydrogen type zeolite or aluminophosphate, or an ion exchange resin having at least one acid group selected from a sulfonic acid group, a carboxyl group and a phosphoric acid group.

Abstract translation: 提供烯烃三聚体的制备方法和使用烯烃定时器制备具有高沸点的烷基化物的方法，以提高转化率和产率。 通过使用包含布朗斯台德酸和路易斯酸的酸催化剂或通过烧结或洗涤酸催化剂获得的酸催化剂制备烯烃三聚体。 优选地，通过将​​BF 3，BCl 3，BI 3，SbF 5，SbCl 5，AlCl 3，AlBr 3，TiCl 4，TiBr 4，ZrCl 4，PF 5，FeCl 3，FeBr 3，SnBr 4或SnCl 4引入多孔体如氢型沸石或磷酸铝，或 具有至少一个选自磺酸基，羧基和磷酸基的酸基的离子交换树脂。

公开(公告)号：KR1020070111918A

公开(公告)日：2007-11-22

申请号：KR1020060045350

申请日：2006-05-19

Applicant: 한국화학연구원

Inventor： 정성화 ,  장종산 ,  황진수 ,  황영규 ,  이지혜

IPC: B01J37/34 ,  B01J35/10 ,  B01J35/04

CPC classification number: B01J35/023 ,  B01J35/04 ,  B01J35/10 ,  B01J37/08 ,  B01J37/346

Abstract: A preparation method of porous molecular sieves is provided to make it possible to prepare porous molecular sieves with various particle sizes and allow the prepared porous molecular sieves to be applied to various purposes by performing a hydrothermal or solvothermal reaction and controlling the temperature increasing rate of a heating process for obtaining a high temperature. In a preparation method of a porous molecular sieve by heat-treating a metal precursor and an oxygen precursor or an organic ligand as reaction raw materials in a state that a solvent presents, the preparation method comprises varying a temperature increasing rate that reaches a heat treatment temperature to control the size of an obtained porous molecular sieve. The preparation method comprises using microwave heating or an infrared lamp to maintain a high temperature increasing rate. The preparation method comprises using electrical heating to maintain a low temperature increasing rate. The preparation method comprises injecting reactants into a continuous reactor and reacting the reactants to minimize the temperature increasing rate that reaches a heat treatment temperature.

Abstract translation: 提供了一种多孔分子筛的制备方法，使得可以制备各种粒径的多孔分子筛，并且通过进行水热或溶剂热反应并使得制备的多孔分子筛可以应用于各种目的，并控制温度升高速率 用于获得高温的加热过程。 在通过在溶剂存在的状态下通过热处理金属前体和氧前体或有机配体作为反应原料的多孔分子筛的制备方法中，制备方法包括改变达到热处理的升温速率 温度以控制获得的多孔分子筛的尺寸。 该制备方法包括使用微波加热或红外灯保持高温升高速率。 该制备方法包括使用电加热来维持低温升高速率。 制备方法包括将反应物注入连续反应器中并使反应物反应以使达到热处理温度的升温速率最小化。

公开(公告)号：KR1020070108086A

公开(公告)日：2007-11-08

申请号：KR1020070043652

申请日：2007-05-04

Applicant: 주식회사 엘지화학 ,  한국화학연구원

Inventor： 장성균 ,  방의용 ,  박희상 ,  이기영 ,  박성용 ,  황영규 ,  장종산 ,  김덕규 ,  정성화

IPC: H01M4/36 ,  H01M4/02 ,  H01M10/38

CPC classification number: H01M4/131 ,  H01M4/0438 ,  H01M4/134 ,  H01M4/1391 ,  H01M4/366

Abstract: An electrode active material is provided to reduce a side reaction with an electrolyte and to ensure structural stability, thereby improving performances of a battery. An electrode active material includes acid sites on a partial or whole surface thereof. The electrode active material having controlled acid strength on the surface is manufactured by a step of treating a partial or whole surface of an electrode active material with a resultant formed by chemically reacting (a) a proton-donating or accepting compound, or an electron-pair-donating or accepting compound with (b) a compound having acid sites. The acid strength in the acid site has a Hammett indicator ranging from -10 to 10.

Abstract translation: 提供电极活性材料以减少与电解质的副反应并确保结构稳定性，从而提高电池的性能。 电极活性材料包括其局部或整个表面上的酸性部位。 具有表面受控酸强度的电极活性材料通过以下步骤制造：用电子活性物质的部分或全部表面处理通过化学反应（a）质子供体或接受的化合物或电子 - 配对或接受化合物与（b）具有酸性位点的化合物。 酸性位点的酸强度为-10〜10。

公开(公告)号：KR1020070106473A

公开(公告)日：2007-11-01

申请号：KR1020070050677

申请日：2007-05-25

Applicant: 한국화학연구원

Inventor： 정성화 ,  장종산 ,  윤지웅 ,  이지혜 ,  이희두 ,  추대현 ,  김태진

IPC: C07C2/28 ,  C07C11/02

Abstract: A method for preparing an olefin trimer is provided to improve the selectivity and productivity of the trimerization of an olefin by using a catalyst with improved lifespan, and to allow conversion of the olefin trimer into a high boiling point alkylate useful as an additive for a high-quality solvent and gasoline. A method for preparing an olefin trimer comprises the use of zeolite as a catalyst, wherein the zeolite has inter-crossing micropores formed of micropores containing 12 oxygen atoms, and micropores containing 12 oxygen atoms and/or micropores containing 10-6 oxygen atoms crossing over the same. The olefin trimer obtained by the method is further hydrogenated to provide a high boiling point alkylate. The zeolite having inter-crossing micropores has a Beta, Al-rich Beta, boron-containing Beta zeolite, gallium-containing Beta zeolite, titanium-containing Beta zeolite, CIT-6, Beta zeolite merely formed of silica or Tschernichite structure.

Abstract translation: 提供一种制备烯烃三聚体的方法，以通过使用具有改善的寿命的催化剂来提高烯烃三聚的选择性和生产率，并且允许将烯烃三聚体转化成可用作高添加剂的高沸点烷基化物 质量溶剂和汽油。 制备烯烃三聚体的方法包括使用沸石作为催化剂，其中沸石具有由含有12个氧原子的微孔形成的交叉微孔，以及含有12个氧原子的微孔和/或含10-6个氧原子的微孔， 一样。 通过该方法获得的烯烃三聚体进一步氢化以提供高沸点烷基化物。 具有相互交叉的微孔的沸石具有仅由二氧化硅或Tschernichite结构形成的β，富Al的β，含硼的β沸石，含镓的β沸石，含钛的β沸石，CIT-6，β沸石。

公开(公告)号：KR1020070092592A

公开(公告)日：2007-09-13

申请号：KR1020060121071

申请日：2006-12-02

Applicant: 한국화학연구원

Inventor： 장종산 ,  정성화 ,  황영규

IPC: B01J20/02 ,  B01J20/00 ,  B01J20/22 ,  B82Y30/00

CPC classification number: B01J20/226 ,  B01D53/263 ,  B01D53/28 ,  B01D2253/204 ,  B01D2253/304 ,  B01D2253/306 ,  B01D2253/308 ,  B01D2253/311 ,  B01J20/02 ,  B01J20/0214 ,  B01J20/0218 ,  B01J20/0229 ,  B01J20/28033 ,  B01J20/28066 ,  B01J20/28076 ,  B01J20/2808 ,  B01J20/30 ,  B01J20/3078 ,  B01J20/3085 ,  B01J20/3204 ,  B01J20/3208 ,  B01J20/3236 ,  B01J20/3242 ,  B01J20/3248 ,  B01J20/3255 ,  B01J2220/68 ,  C07F11/005

Abstract: An adsorbent which adsorbs water in a large amount, and can desorb water easily even at a relatively low temperature, and an adsorbent that is excellent in the adsorption amount and adsorption properties by applying a porous organic-inorganic complex are provided. A water adsorbent using a porous organic-inorganic complex is characterized in that the adsorbent has a surface area of not less than 1000 m^2/g, a pore volume of not less than 1.0 ml/g and a pore size of 0.5 to 2 nm, and is obtained by the reaction between a metal precursor and a ligand. A ratio of the water adsorption amount at 100 deg.C to that at a room temperature of the porous organic-inorganic complex is less than 0.2. The metal precursor is at least one metal selected from Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Re, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Hg, Mg, Ca, Sr, Ba, Sc, Y, Al, Ga, In, Tl, Si, Ge, Sn, Pb, As, Sb and Bi, or compounds thereof. The porous organic-inorganic complex is prepared by a method comprising the steps of: (1) mixing a metal precursor, an organic material functioning as a ligand, and a solvent to prepare a reactant mixed solution; and (2) irradiating 0.3 to 300 GHz of microwave onto the reactant mixed solution, thereby heating the reactant mixed solution to a temperature or 100 deg.C or more. The porous organic-inorganic complex is prepared in the form of a thick film, a thin film, or a membrane.

Abstract translation: 提供了大量吸附水分并且即使在相对低的温度下也容易解吸水的吸附剂，并且提供了通过施加多孔有机 - 无机复合物而具有优异的吸附量和吸附性能的吸附剂。 使用多孔有机 - 无机复合物的吸水剂的特征在于，吸附剂的表面积不小于1000m 2 / g，孔体积不小于1.0ml / g，孔径为0.5-2 并且通过金属前体和配体之间的反应获得。 多孔有机 - 无机络合物在100℃下的水吸附量与室温下的吸附量的比小于0.2。 金属前体是选自Ti，Zr，Hf，V，Nb，Ta，Cr，Mo，W，Mn，Re，Fe，Ru，Os，Co，Rh，Ir，Ni，Pd，Pt， Cu，Ag，Au，Zn，Cd，Hg，Mg，Ca，Sr，Ba，Sc，Y，Al，Ga，In，Tl，Si，Ge，Sn，Pb，As，Sb和Bi或其化合物。 通过包括以下步骤的方法制备多孔有机 - 无机复合物：（1）将金属前体，用作配体的有机材料和溶剂混合以制备反应物混合溶液; 和（2）将0.3〜300GHz的微波照射到反应物混合溶液上，从而将反应物混合溶液加热至100℃以上。 多孔有机 - 无机复合体以厚膜，薄膜或膜的形式制备。

公开(公告)号：KR100757031B1

公开(公告)日：2007-09-07

申请号：KR1020060038895

申请日：2006-04-28

Applicant: 한국화학연구원

Inventor： 정성화 ,  장종산 ,  윤지웅 ,  이지혜 ,  이희두 ,  추대현 ,  김태진

IPC: C07C2/10 ,  C07C2/26

Abstract: A method for preparing a trimer by using an olefin, and a method for preparing an alkylate are provided to improve the selectivity of trimers and to increase the viscosity of an alkylate. A preparation method of a trimer comprises the step of polymerizing an olefin in the presence of a zeolite catalyst comprising a pore having 12 oxygen atoms, a pore crossing with the pore and having 12 oxygen atoms and/or having 6-10 oxygen atoms. Preferably the reaction is carried out at a temperature of 50-100 deg.C and with a space velocity of 0.5-100 h^-1. Preferably the olefin is isobutene; and the zeolite catalyst is zeolite beta, Al-rich beta, boron-containing zeolite, gallium-containing beta zeolite, titanium-containing beta zeolite, CIT-6, beta zeolite comprising silica only, or zeolite having Tschernichite structure.

Abstract translation: 提供通过使用烯烃制备三聚体的方法和制备烷基化物的方法以提高三聚体的选择性和提高烷基化物的粘度。 三聚体的制备方法包括在沸石催化剂存在下聚合烯烃的步骤，所述沸石催化剂包含具有12个氧原子的孔，与该孔孔隙并且具有12个氧原子和/或具有6-10个氧原子的孔。 优选地，反应在50-100℃的温度和0.5-100h -1 -1的空间速度下进行。 优选地，烯烃是异丁烯; 沸石催化剂是β沸石，富含Al的β，含硼沸石，含镓β沸石，含钛β沸石，仅含二氧化硅的CIT-6，β沸石或具有Tschernichite结构的沸石。

公开(公告)号：KR100718014B1

公开(公告)日：2007-05-14

申请号：KR1020060022782

申请日：2006-03-10

Applicant: 한국화학연구원

Inventor： 정성화 ,  장종산 ,  윤지웅 ,  황영규 ,  이희두 ,  추대현 ,  이성준

IPC: C07C2/28 ,  C07C11/02

Abstract: 본 발명은 올레핀의 올리고머화 반응, 특히 삼량체의 생성반응에 관한 것이며 올리고머화 반응에 있어서 상호 교차하는 세공을 갖는 제올라이트를 촉매로 사용하여 선택적으로 삼량체를 얻는 방법을 제공하는 것이다. 본 발명의 삼량체는 네오산(neo-acid)등의 원료로 사용되기도 하며 수소화 반응을 거쳐 고비점 알킬레이트로 전환되어 고급 용제 및 경유 첨가제로 사용될 수 있다.
올리고머화, 제올라이트, 고비점알킬레이트, 삼량체, SUZ-4, ferrierite

Abstract translation: 本发明涉及低聚反应，所得到的反应，特别是在使用具有相交在催化剂中的低聚反应提供了一种方法选择性地获得的三元共聚物的孔的沸石烯烃的三元共聚物。 也可以使用本发明的三元共聚物为原料转化，如新酸（新酸），并且在高沸点的烷基化物的氢化反应后可以被用作溶剂，和先进的柴油添加剂。