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公开(公告)号：DE10160146A1
公开(公告)日：2003-06-18
申请号：DE10160146
申请日：2001-12-07
Applicant: BASF AG
Inventor： HAESE FRANK , EBEL KLAUS , BURKART KIRSTEN , UNVERRICHT SIGNE , MUENSTER PETER
Abstract: The invention relates to a method for isomerizing educt allyl alcohols into product allyl alcohols in the presence of a catalyst. The inventive method is characterized in that educt allyl alcohol is rearranged in a semicontinuous or continuous operation whereby forming product allyl alcohol inside a suitable reactor containing a catalyst.
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公开(公告)号：DE10160143A1
公开(公告)日：2003-06-18
申请号：DE10160143
申请日：2001-12-07
Applicant: BASF AG
Inventor： GOEBBEL HANS-GEORG , GERLACH TILL , FUNKE FRANK , EBEL KLAUS , UNVERRICHT SIGNE , KAIBEL GERD
Abstract: Selective hydrogenation of alpha , beta -ethylenically unsaturated aldehydes (II) to corresponding unsaturated alcohols (I) comprises performing reaction in a reactor containing a liquid phase, suspended catalyst and optionally a gas phase, The liquid phase and gas phase (if present) are supplied to the reactor through a device (A) with openings or channels having a hydraulic diameter of 0.5-2 mm. Selective hydrogenation of unsaturated aldehydes of formula R R C=CR -CHO (II) to corresponding alcohols of formula R R C=CR -CH2OH (I) comprises performing the reaction in a reactor containing a liquid phase, suspended catalyst and optionally a gas phase. The liquid phase and optionally the gas phase are supplied to the reactor through a device (A) with openings or channels having a hydraulic diameter of 0.5-2 mm. R , R = H, optionally substituted mono- or polyunsaturated 1-20C alkyl (sic; some of the groups exemplified in the disclosure are saturated), optionally substituted aryl or optionally substituted heterocyclyl; R = H or 1-4C alkyl.
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公开(公告)号：AU2002358592A8
公开(公告)日：2003-06-17
申请号：AU2002358592
申请日：2002-12-04
Applicant: BASF AG
Inventor： HAESE FRANK , BURKART KIRSTEN , UNVERRICHT SIGNE , EBEL KLAUS , MUNSTER PETER
Abstract: The present invention relates to a process for isomerizing reactant allyl alcohols to product allyl alcohols in the presence of a catalyst, wherein the reactant allyl alcohol is rearranged to product allyl alcohol in semicontinuous or continuous mode in a catalyst-containing suitable reactor. In particular, the process according to the invention is used to prepare linalool from Geraniol and/or nerol.
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公开(公告)号：DE10156050A1
公开(公告)日：2003-06-05
申请号：DE10156050
申请日：2001-11-15
Applicant: BASF AG
Inventor： WEIGL HAGEN , WARTINI ALEXANDER , EBEL KLAUS
IPC: C07D207/34
Abstract: Production of substituted pyrrole-2-carboxylic esters comprises reaction of alpha -nitroso- beta -oxoesters with beta -carbonyl compounds, in a hydrogen-containing atmosphere, in the presence of a noble metal-containing catalyst. Production of substituted pyrrole-2-carboxylic esters of formula (I) comprises reaction of alpha -nitroso- beta -oxoesters of formula (II) with beta -carbonyl compounds of formula (III), in a hydrogen-containing atmosphere, in the presence of a noble metal-containing catalyst. R -R = optionally functionalized aliphatic, cycloaliphatic, aromatic, araliphatic or 1-20C heterocycle. Where: (1) R and R can additionally be -CHO, -COOH (both in protected form) or -CN; (2) R can additionally be -OH, with the proviso that R = optionally functionalized aliphatic, cycloaliphatic, aromatic, araliphatic or heterocyclic of 1-20C; and (3) R can additionally be H.
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公开(公告)号：DE59805432D1
公开(公告)日：2002-10-10
申请号：DE59805432
申请日：1998-06-04
Applicant: BASF AG
Inventor： EBEL KLAUS , PINKOS ROLF
IPC: B01J23/80 , C07B61/00 , C07C29/149 , C07C29/36 , C07C31/133 , C07C51/353 , C07C67/347
Abstract: 2-Cyclododecyl-propanol [sic], which is in demand as musk scent, is prepared in an advantageous industrial process by reacting cyclododecene with an excess of propionic acid or of a propionic acid derivative in the presence of catalytic amounts of a free-radical initiator, and subsequently catalytically hydrogenating the 2-cyclododecylpropionic acid which is formed or the corresponding 2-cyclododecylpropionic acid derivatives.
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Patent Agency Ranking
公开(公告)号：DE59804528D1
公开(公告)日：2002-07-25
申请号：DE59804528
申请日：1998-07-20
Applicant: BASF AG
Inventor： HIEBER GISELA , EBEL KLAUS
IPC: C07B61/00 , C07C41/42 , C07C41/56 , C07C43/303
Abstract: A process for preparing acetals of the formula Iwherea) the Rs are, independently of one another, a C1-C20-alkyl or C3-C20-alkenyl radical, orb) the two R radicals together form the members of an unsubstituted or C1-C10-alkyl-substituted 5- to 7-membered cyclic acetal,by reacting 3-methyl-2-butenal in the presence of sulfamic acid, of a N-(C1-C8-alkyl)sulfamic acid or of a N,N-di(C1-C8-alkyl)sulfamic acid as catalyst with:an alcohol of the formula R-OH (IIa), oran orthoester of the formula HC-(OR)3 (III) ora mixture of an alcohol of the formula (IIa) and an orthoester of the formula (III), oran alcohol of the formula HO-(CH2)m-OH (IIb), where m is a number from 2 to 4, and (CH2)m group in the alcohol IIb may be substituted by a C1-C10-alkyl group.
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公开(公告)号：NO312238B1
公开(公告)日：2002-04-15
申请号：NO970246
申请日：1997-01-20
Applicant: BASF AG
Inventor： KROPP RUDOLF , HICKMANN ECKHARD , EBEL KLAUS , GUENTHER WOLFGANG , RATH HANS PETER , SCHWAHN HARALD
IPC: C10L1/234 , C07C205/02 , C07C205/15 , C07C211/09 , C07C211/13 , C07C215/08 , C07C215/18 , C08F8/30 , C08F10/10 , C10L1/14 , C10L1/18 , C10L1/22 , C10L1/222 , C10L1/23 , C10L1/236 , C10L1/238 , C10L10/00 , C10L10/08 , C10M133/02 , C10M133/52 , C10M133/54 , C10M149/14 , C10M159/12 , C10N40/25
Abstract: Reaction products of polyisobutenes having an average degree of polymerization P of from 10 to 100 and a content E of from 60 to 90% of double bonds which can react with maleic anhydride, E=100% corresponding to the theoretical value for the case where each molecule of the polyisobutene has such a reactive double bond, with oxides of nitrogen or mixtures of oxides of nitrogen and oxygen, are suitable as additives for fuels, in particular for gasoline engines, and for lubricants.
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68.发明专利
公开(公告)号：DE10046865A1
公开(公告)日：2002-03-28
申请号：DE10046865
申请日：2000-09-20
Applicant: BASF AG
Inventor： STOCK FRANK , EBEL KLAUS
IPC: C07D215/30 , B01J23/30 , B01J31/18 , B01J31/22 , C07B61/00 , C07C29/56 , C07C33/03 , C07C211/65 , C07C215/08 , C07C215/76 , C07D213/16 , C07F11/00 , C07B37/08 , C07B41/02 , C07C33/02
Abstract: Tungstyl peroxide complexes (I) are new. Tungstyl peroxide complexes of formula (I) are new. L1 = H2O, OH, alkoxy, a free coordination site or a ligand selected from aminoalcohols, aminophenols and/or aminocarboxylic acids or mixtures of amines with alcohols, phenols or carboxylic acids; L2 = a ligand selected from aminoalcohols, aminophenols and/or aminocarboxylic acids or mixtures of amines with alcohols, phenols or carboxylic acids; m = 1 or 2; n, p = 1-6.
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公开(公告)号：SK7152001A3
公开(公告)日：2002-01-07
申请号：SK7152001
申请日：1999-11-22
Applicant: BASF AG
Inventor： EIERMANN MATTHIAS , TRAGUT CHRISTIAN , EBEL KLAUS
IPC: C07C303/16 , C07C309/04
Abstract: The invention relates to a process for the prepartaion of alkanesulfonic acids, comprising the following steps:(a) oxidation of alkylmercaptans and/or dialkyl disulfides and/or dialkyl polysulfides having from three to nine sulfur atoms with nitric acid to form alkanesulfonic acids, water, nitrogen oxides and other byproducts,(b) regeneration of the nitrogen oxides obtained from step (a) with oxygen to give nitric acid and recycling of the nitric acid to step (a),where steps (a) and (b) are carried out in reaction chambers separate from one another.
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公开(公告)号：DE10026139A1
公开(公告)日：2001-11-29
申请号：DE10026139
申请日：2000-05-26
Applicant: BASF AG
Inventor： SCHULZ GERHARD , WEIGL HAGEN , GELDER RICHARD VAN , RAULS MATTHIAS , EBEL KLAUS
Abstract: The invention relates to a method for the selective crystallization of poly- or monomethylol alkanoic acids of the general formula (I), wherein R is the same or different and represents a methylol group or a substituted or unsubstituted aliphatic hydrocarbon, with an essentially monomodal particle size distribution. This particle size distribution is achieved by crystallization in a temperature interval of from 85 DEG C to 50 DEG C observing a cooling rate of
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