Aqueous surfactant mixture useful for solubilizing harmful organic substances in a solid matrix such as contaminated soils, comprises a selected anionic surfactant and a selected nonionic surfactant

    公开(公告)号:DE19954070A1

    公开(公告)日:2000-05-11

    申请号:DE19954070

    申请日:1999-11-10

    Applicant: BASF AG

    Abstract: Aqueous surfactant mixtures comprising at least one selected anionic surfactant and at least one selected nonionic surfactant useful for solubilizing harmful organic substances in a solid matrix such as contaminated soil. Aqueous surfactant formulations comprising (a) at least one anionic surfactant selected from alkylaryl sulfonates of formula (I) R = 6-24 C linear or branched alkyl R = Na, K, Ca or NR 3 R (same or different) = H or 1-8 C alkyl m = 1, 2 or 3 and sulfosuccinates of formula (II) R = as above R and R independently = H or linear or branched 2-22 C alkyl with the proviso that R and R are not both H simultaneously; and (b) at least one nonionic surfactant selected from alkoxylated alcohols of formula (III) R = 6-32 C linear or branched alkyl or alkenyl residue R (same or different) = linear or branched 1-6 C alkyl n = 1-80 R = H, linear or branched 1-6 C alkyl or -CO-R R = linear or branched 1-6 C alkyl carboxylic acid amidoalkoxylates of formula (IV) R = linear or branched 5-30 C alkyl or alkenyl residue R = H or linear or branched 1-6 C alkyl R (same or different) = linear or branched 1-6 C alkyl n = 1-50 R = H or linear or branched 1-6 C alkyl; alkylglycosides in which at least one linear or branched 4-30 C alcohol is linked to a mono-, di-, oligo- or polysaccharide by way of an ether link; and polyalkylene oxide block copolymers with at least one terminal polyethylene oxide block and at least one block of propylene oxide and/or butylene oxide and having an average molecular weight of 500-20000.

    Alkoxylated polyalkyleneimine dispersants

    公开(公告)号:AU4512299A

    公开(公告)日:2000-01-10

    申请号:AU4512299

    申请日:1999-06-12

    Applicant: BASF AG

    Abstract: The present invention relates to an alkoxylated polyalkyleneimine soil dispersant having the formula: wherein R is C2-C6 linear alkylene, C3-C6 branched alkylene, and mixtures thereof; B is a continuation by branching; E is an alkyleneoxy unit having the formula:-(R1O)m(R2O)nR3wherein R1 is 1,2-propylene, 1,2-butylene, and mixtures thereof; R2 is ethylene; R3 is hydrogen, C1-C4 alkyl, and mixtures thereof; m is from about 1 to about 10; n is from about 10 to about 40; w, x and y are each independently from about 4 to about 200; provided at least one -(R1O) unit is attached to the backbone prior to attachment of an -(R2O) unit and further provided m+n is at least 12.

    64.
    发明专利
    未知

    公开(公告)号:AT180284T

    公开(公告)日:1999-06-15

    申请号:AT95924249

    申请日:1995-06-16

    Applicant: BASF AG

    Abstract: Aminomethylene phosphinic acid derivs. contg. units of formula (I), soluble in hydrocarbons, or aminomethylene phosphonic acid derivs. contg. units of formula (Ia), or aminomethylene phosphonic acid derivs. of formula R R N-(A-N(R ))pR (II), are used in the extn. of Fe ions from aq. solns. In the formulae: R and R = H, 1-30 C alkyl (opt. carrying up to 15 OH gps. and/or broken by up to 14 non-adjacent O atoms), or 2-30 C alkenyl, 7-18C aralkyl, or 6-14C aryl (opt. substd. with up to 3 1-12C alkyl or alkoxy, halogen, CN, OH or 1-4C alkoxycarbonyl; R -R = H, 1-30 C alkyl (opt. carrying up to 15 OH gps. and/or broken by up to 14 non-adjacent O atoms), 2-30 C alkenyl, 7-18C aralkyl, 6-14C aryl (opt. substd. with up to 3 1-12C alkyl or alkoxy, halogen, CN, OH or 1-4C alkoxycarbonyl), or are gps. of formulae -CR R -PO3H2, -CH2-COOH or -CH2-CH(OH)-R ; at least one of the gps. R -R = -CR R -PO3H2, and at least one other is 6-30C alk(en)yl, 7-18C aralkyl, (substd.) 6-14C aryl or -CH2-CH(OH)-R ; R = 6-30 C alk(en)yl, 7-18C aralkyl or (substd.) 6-14 C aryl; A = 1-12C alkylene (opt. substd. with up to 3 1-30 C alkyl, 2-30C alkenyl, 7-18C aralkyl, or 6-14C aryl, which in their turn may be substd. by up to 3 1-12C alkyl or alkoxy, halogen, CN, OH, or 1-4C alkoxycarbonyl); and p = 0-30,000. Also claimed is a modifier for use in the sepn. of metal ions from aq. solns. by solvent extn..

    66.
    发明专利
    未知

    公开(公告)号:NO965555L

    公开(公告)日:1997-02-20

    申请号:NO965555

    申请日:1996-12-23

    Applicant: BASF AG

    Abstract: Aminomethylene phosphinic acid derivs. contg. units of formula (I), soluble in hydrocarbons, or aminomethylene phosphonic acid derivs. contg. units of formula (Ia), or aminomethylene phosphonic acid derivs. of formula R R N-(A-N(R ))pR (II), are used in the extn. of Fe ions from aq. solns. In the formulae: R and R = H, 1-30 C alkyl (opt. carrying up to 15 OH gps. and/or broken by up to 14 non-adjacent O atoms), or 2-30 C alkenyl, 7-18C aralkyl, or 6-14C aryl (opt. substd. with up to 3 1-12C alkyl or alkoxy, halogen, CN, OH or 1-4C alkoxycarbonyl; R -R = H, 1-30 C alkyl (opt. carrying up to 15 OH gps. and/or broken by up to 14 non-adjacent O atoms), 2-30 C alkenyl, 7-18C aralkyl, 6-14C aryl (opt. substd. with up to 3 1-12C alkyl or alkoxy, halogen, CN, OH or 1-4C alkoxycarbonyl), or are gps. of formulae -CR R -PO3H2, -CH2-COOH or -CH2-CH(OH)-R ; at least one of the gps. R -R = -CR R -PO3H2, and at least one other is 6-30C alk(en)yl, 7-18C aralkyl, (substd.) 6-14C aryl or -CH2-CH(OH)-R ; R = 6-30 C alk(en)yl, 7-18C aralkyl or (substd.) 6-14 C aryl; A = 1-12C alkylene (opt. substd. with up to 3 1-30 C alkyl, 2-30C alkenyl, 7-18C aralkyl, or 6-14C aryl, which in their turn may be substd. by up to 3 1-12C alkyl or alkoxy, halogen, CN, OH, or 1-4C alkoxycarbonyl); and p = 0-30,000. Also claimed is a modifier for use in the sepn. of metal ions from aq. solns. by solvent extn..

    68.
    发明专利
    未知

    公开(公告)号:AT343547T

    公开(公告)日:2006-11-15

    申请号:AT04739694

    申请日:2004-06-08

    Applicant: BASF AG

    Abstract: Use of aqueous dispersions comprising at least one at least partially neutralized ethylene copolymer wax selected from among ethylene copolymer waxes which comprise, as comonomers in copolymerized form, (A) from 26.1 to 39% by weight of at least one ethylenically unsaturated carboxylic acid and (B) from 61 to 73.9% by weight of ethylene, and ethylene copolymer waxes which comprise, in copolymerized form, (A') from 20.5 to 38.9% by weight of at least one ethylenically unsaturated carboxylic acid, (B') from 60 to 79.4% by weight of ethylene and (C') from 0.1 to 15% by weight of at least one ethylenically unsaturated carboxylic ester, as auxiliaries for wastewater treatment.

    69.
    发明专利
    未知

    公开(公告)号:DE69901034D1

    公开(公告)日:2002-04-18

    申请号:DE69901034

    申请日:1999-06-12

    Applicant: BASF AG

    Abstract: The present invention relates to an alkoxylated polyalkyleneimine soil dispersant having the formula: wherein R is C2-C6 linear alkylene, C3-C6 branched alkylene, and mixtures thereof; B is a continuation by branching; E is an alkyleneoxy unit having the formula:-(R1O)m(R2O)nR3wherein R1 is 1,2-propylene, 1,2-butylene, and mixtures thereof; R2 is ethylene; R3 is hydrogen, C1-C4 alkyl, and mixtures thereof; m is from about 1 to about 10; n is from about 10 to about 40; w, x and y are each independently from about 4 to about 200; provided at least one -(R1O) unit is attached to the backbone prior to attachment of an -(R2O) unit and further provided m+n is at least 12.

    70.
    发明专利
    未知

    公开(公告)号:NO312247B1

    公开(公告)日:2002-04-15

    申请号:NO965555

    申请日:1996-12-23

    Applicant: BASF AG

    Abstract: Aminomethylene phosphinic acid derivs. contg. units of formula (I), soluble in hydrocarbons, or aminomethylene phosphonic acid derivs. contg. units of formula (Ia), or aminomethylene phosphonic acid derivs. of formula R R N-(A-N(R ))pR (II), are used in the extn. of Fe ions from aq. solns. In the formulae: R and R = H, 1-30 C alkyl (opt. carrying up to 15 OH gps. and/or broken by up to 14 non-adjacent O atoms), or 2-30 C alkenyl, 7-18C aralkyl, or 6-14C aryl (opt. substd. with up to 3 1-12C alkyl or alkoxy, halogen, CN, OH or 1-4C alkoxycarbonyl; R -R = H, 1-30 C alkyl (opt. carrying up to 15 OH gps. and/or broken by up to 14 non-adjacent O atoms), 2-30 C alkenyl, 7-18C aralkyl, 6-14C aryl (opt. substd. with up to 3 1-12C alkyl or alkoxy, halogen, CN, OH or 1-4C alkoxycarbonyl), or are gps. of formulae -CR R -PO3H2, -CH2-COOH or -CH2-CH(OH)-R ; at least one of the gps. R -R = -CR R -PO3H2, and at least one other is 6-30C alk(en)yl, 7-18C aralkyl, (substd.) 6-14C aryl or -CH2-CH(OH)-R ; R = 6-30 C alk(en)yl, 7-18C aralkyl or (substd.) 6-14 C aryl; A = 1-12C alkylene (opt. substd. with up to 3 1-30 C alkyl, 2-30C alkenyl, 7-18C aralkyl, or 6-14C aryl, which in their turn may be substd. by up to 3 1-12C alkyl or alkoxy, halogen, CN, OH, or 1-4C alkoxycarbonyl); and p = 0-30,000. Also claimed is a modifier for use in the sepn. of metal ions from aq. solns. by solvent extn..

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