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公开(公告)号:DE10029027A1
公开(公告)日:2001-12-20
申请号:DE10029027
申请日:2000-06-13
Applicant: BASF AG
Inventor: ANDRE VALERIE , BERTLEFF WERNER , BORZYK OLIVER , HUFF JUERGEN , NOERENBERG RALF
IPC: C08J7/04 , C08F8/00 , C08G65/26 , C08J3/12 , C09D139/02 , D06M15/356 , D06M15/61 , C08J7/16 , C09D175/12 , C09D171/02 , C08G59/10
Abstract: Novel alkoxylated polyvinylamines comprise at least a portion of polyvinylamine-nitrogen groups of specified formula. Novel alkoxylated polyvinylamines comprise at least a portion of the polyvinylamine-nitrogen groups of formula (I). Independent claims are included for: (1) particulate, linear, flat or three-dimensional objects (O) containing at least on one surface, a hydrophilic effective amount of the claimed alkoxylated polyvinylamine; (2) processes for the modification of the surface properties of the objects (O) by application of the alkoxylated polyvinylamine of the claim, either to the object itself, or to the material from which the object is made followed by manufacture of the object; and (3) a process for the production of the alkoxylated polyvinylamine of the claim by reaction of a polyvinylamine with at least 1 mole of an epoxide of formula (II) per mole of amine groups in the polyvinylamine and optionally reacting the resulting alkoxylated product with ethylene oxide and/or propylene oxide. R = 2-28C alkyl or alkenyl, 6-16C aryl or 7-16C arylalkyl; R , R = H or methyl; m = 1-20; and n = 0-100
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公开(公告)号:DE10027636A1
公开(公告)日:2001-12-13
申请号:DE10027636
申请日:2000-06-06
Applicant: BASF AG
Inventor: BOECKH DIETER , NOERENBERG RALF , DETERING JUERGEN , BERTLEFF WERNER , SCHOEPKE HOLGER , LEYRER REINHOLD , HUFF JUERGEN
IPC: C11D1/38 , C11D1/86 , C11D3/00 , C11D3/02 , C11D3/37 , C11D11/00 , D06M15/263 , D06M23/08 , C09D5/02 , C09D7/02 , C09D133/26 , C08G69/48 , B01F17/00 , C09K3/18
Abstract: The use of particulate, hydrophobic polymers with a particle size of 10 nm to 100 microns, cationically modified by surface-coating with multivalent metal ions and/or cationic surfactants, as additives in rinsing, care, washing and cleaning materials. Independent claims are also included for: (i) a treatment for laundry, textile surfaces, leather, wood and hard surfaces, containing: (a) 0.05-40 wt.% of modified polymer as above (I); (b) 0.01-20 wt.% of water-soluble salts of calcium, magnesium, aluminum and/or zinc and/or 0.01-30 wt.% of cationic surfactant; (c) 0-80 wt.% of additive(s) such as acids, bases, inorganic builders, organic co-builders, other surfactants, polymeric color-transfer inhibitors, polymeric greying inhibitors, soil release polymers, enzymes, complex-formers, corrosion inhibitors, wax, silicone oils, light stabilizers, dyes, solvents, hydrotropic additives, thickeners and/or alkanolamines; and (d) water to make up 100 wt.%; (ii) laundry after-treatment and care material containing: (a) 0.1-30 wt.% of (I) (containing ethylenically-unsaturated monomer unit(s)), dispersed in water; (b) 0.05-20 wt.% of acid; (c) 0.1-30 wt.% of water-soluble salt(s) of magnesium, calcium, zinc or aluminum and/or a cationic surfactant; (d) 0-10 wt.% of additives such as perfume, silicone oil, light stabilizers, dyes, complex-formers, greying inhibitors, soil-release polyesters, color-transfer inhibitors, non-aqueous solvents, hydrotropic additives, thickeners and/or alkanolamines; and (e) water to make up 100 wt.% of; (iii) a laundry after-treatment and care material containing: (a) 0.5-25 wt.% of hydrophobic polymer particles (size as above) containing 5-45 wt.% of unsaturated monomer units with carboxylic acid groups, dispersed in water with an anionic emulsifier and/or anionic protective colloid; (b) 0.05-10 wt.% of acid; (c) 0.1-30 wt.% of metal salt and/or surfactant as above; (d) 0-10 wt.% of additives (as in ii); and (e) water (to 100 wt.%); (iv) a liquid cleaning and care formulation containing: (a) 0.05-30 wt.% of (I); (b) 0.01-40 wt.% of non-ionic or anionic surfactant; (c) 0.01-30 wt.% of metal salt and/or surfactant as above; (d) 0-10 wt.% of complex-former(s); (e) 0-20 wt.% of pH regulator, thickener, solvent, hydrotropic agent, polycarboxylic acid, silicone, brightener, perfume and/or dye; and (f) 0-90 wt.% of water; (v) a liquid acid cleaning formulation containing: (a) 0.1-30 wt.% of (I) (as in ii above); (b) 0.05-20 wt.% of acid; and (c) other components as in (iv); (vi) a liquid acid cleaning formulation containing: (a) 0.5-25 wt.% of (I) (as in (iii) above), dispersed as described; (b) 0.1-40 wt.% of non-ionic or anionic surfactant; (c) 0.1-30 wt.% of metal salt and/or surfactant as above; (d) 0.1-20 wt.% of acid, and other components as in (iv); (vii) a solid detergent formulation containing: (a) 0.05-20 wt.% of (I); (b) 0.1-40 wt.% of non-ionic, cationic and/or anionic surfactant(s); (c) 0-50 wt.% of inorganic builder; (d) 0-10 wt.% of organic co-builder; and (e) 0-60 wt.% of other ingredients such as regulators, enzymes, perfumes, complex-formers, corrosion inhibitors, bleaching agents, activators and/or catalysts, color-transfer inhibitors, greying inhibitors, soil-release polyesters, dyes, solubilizers and/or break-up agents; (viii) a liquid detergent formulation containing: (a) 0.05-20 wt.% of (I); (b) 0.1-40 wt.% of surfactant(s) as in (vii); (c) 0-20 wt.% of inorganic builder; (d) 0-10 wt.% of organic co-builder; (e) 0-10 wt.% of additives such as soda, enzymes, perfume, complex formers, corrosion inhibitors, bleaching agents, activators and/or catalysts, color-transfer inhibitors, greying inhibitors, soil-release polyesters, dyes, non-aqueous solvents, hydrotropic agents, thickeners and/or alkanolamines; and (f) 0-90 wt.% of water.
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公开(公告)号:DE10027634A1
公开(公告)日:2001-12-13
申请号:DE10027634
申请日:2000-06-06
Applicant: BASF AG
Inventor: BOECKH DIETER , NOERENBERG RALF , HILDEBRANDT SOEREN , MOHR BERNHARD , SCHOEPKE HOLGER , LEYRER REINHOLD , HUFF JUERGEN
IPC: D06L1/12 , C08J3/205 , C11D3/37 , C11D17/06 , D06M15/267 , D06M15/285 , D06M15/356 , C09D5/02 , C09D7/02 , C09D133/26 , C08G69/48 , B01F17/00 , C09K3/18
Abstract: The use of particulate, hydrophobic polymers with a particle size of 10 nm to 100 micro m, cationically modified by coating with cationic polymers, as additives in washing or care materials for textiles and as additives in detergents. Independent claims are also included for: (i) a treatment for laundry and textile surfaces, containing: (a) 0.05-40 wt.% of the modified polymer (I); (b) 0.01-10 wt.% of a cationic polymer; and (c) 0-80 wt.% of additive(s) such as acids, bases, inorganic builders, organic co-builders, surfactants, polymeric color-transfer inhibitors, polymeric greying inhibitors, soil release polymers, enzymes, complex-formers, corrosion inhibitors, wax, silicone oils, light stabilizers, dyes, solvents, hydrotropic additives, thickeners and/or alkanolamines; (ii) a laundry after-treatment and care material containing: (a) 0.1-30 wt.% of (I) (containing ethylenically unsaturated monomer unit(s)), dispersed in water; (b) 0.05-20 wt.% of acid; (c) 0.1-10 wt.% of a cationic polymer; (d) 0-30 wt.% of water-soluble salt(s) of magnesium, calcium, zinc or aluminum and/or a cationic surfactant; and (e) 0-10 wt.% of additives such as perfume, silicone oil, light stabilizers, dyes, complex-formers, greying inhibitors, soil-release polyesters, color-transfer inhibitors, non-aqueous solvents, hydrotropic additives, thickeners and/or alkanolamines; (iii) a solid detergent formulation containing: (a) 0.05-20 wt.% of (I) (optionally also modified with multivalent metal ions and/or cationic surfactants); (b) 0.1-40 wt.% of non-ionic, cationic and/or anionic surfactant(s); (c) 0-50 wt.% of inorganic builder; (d) 0-10 wt.% of organic co-builder; and (e) 0-60 wt.% of other ingredients such as regulators, enzymes, perfumes, complex-formers, corrosion inhibitors, bleaching agents and/or activators, color-transfer inhibitors, greying inhibitors, soil-release polyesters, dyes, solubilizers and/or break-up agents; (iv) a liquid detergent formulation containing: (a) , (b) , (c) , (d) , (e) (f) (a) 0.05-20 wt.% of (I) (optionally further modified as in Independent Claim (iii)); (b) 0.1-40 wt.% of surfactant(s) as in Independent Claim (iii); (c) 0-20 wt.% of inorganic builder; (d) 0-10 wt.% of organic co-builder; (e) 0-10 wt.% of additives such as soda, enzymes, perfume, complex formers, corrosion inhibitors, bleaching agents, activators and/or catalysts, color-transfer inhibitors, greying inhibitors, soil-release polyesters, dyes, non-aqueous solvents, hydrotropic agents, thickeners and/or alkanolamines; and (f) 0-90 wt.% of water.
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公开(公告)号:DK0901515T3
公开(公告)日:2000-07-17
申请号:DK97923959
申请日:1997-05-21
Applicant: BASF AG
Inventor: HUFF JUERGEN , JAEGER HANS-ULRICH , AUS DEM KAHMEN MARTIN , KRONER MATTHIAS , LUX JUERGEN ALFRED , OETTER GUENTER
Abstract: PCT No. PCT/EP97/02590 Sec. 371 Date Nov. 19, 1998 Sec. 102(e) Date Nov. 19, 1998 PCT Filed May 21, 1997 PCT Pub. No. WO97/44426 PCT Pub. Date Nov. 27, 1997The use of at least trihydric alcohols and their reaction products with ethylene oxide and/or propylene oxide as additive to particulate detergent formulations, especially compact detergents, to increase their rate of dissolving in water in amounts of from 0.1 to 5% by weight based on the detergent formulations.
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