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    Method for producing flexible block foam polyols
    61.
    发明专利
    Method for producing flexible block foam polyols 未知

    公开(公告)号：AU7514400A

    公开(公告)日：2001-04-24

    申请号：AU7514400

    申请日：2000-09-05

    Applicant: BASF AG

    Inventor： GROSCH GEORG HEINRICH ,  LARBIG HARALD ,  LORENZ REINHARD ,  JUNGE DIETER ,  HARRE KATHRIN

    IPC: C08G18/48 ,  C08G65/26 ,  C08G101/00

    Abstract: The invention relates to polyether alcohols that are produced by a ring-opening polymerization of ethylene oxide and at least one alkylene oxide with at least 3 carbon atoms in the molecule to H-functional starting substances. The inventive method is further characterized in that ethylene oxide or a mixture of ethylene oxide and at least one alkylene oxide with at least 3 carbon atoms in the molecule with an ethylene oxide content of at least 98 %, based on the mixture, is added to the starting substance in an amount of maximally 40 % by weight, based on the weight of the polyether alcohol. At least one alkylene oxide with at least 3 carbon atoms in the molecule or a mixture of ethylene oxide and at least one alkylene oxide with at least 3 carbon atoms in the molecule and an ethylene oxide content of maximally 20 % by weight, based on the mixture, is added.

    62.
    发明专利
    未知

    公开(公告)号：DE19944762A1

    公开(公告)日：2001-03-22

    申请号：DE19944762

    申请日：1999-09-17

    Applicant: BASF AG

    Inventor： GROSCH GEORG HEINRICH ,  LARBIG HARALD ,  LORENZ REINHARD ,  JUNGE DIETER ,  HARRE KATHRIN

    IPC: C08G18/48 ,  C08G65/26 ,  C08G101/00 ,  C08G65/10

    Abstract: The invention relates to polyether alcohols that are produced by a ring-opening polymerization of ethylene oxide and at least one alkylene oxide with at least 3 carbon atoms in the molecule to H-functional starting substances. The inventive method is further characterized in that ethylene oxide or a mixture of ethylene oxide and at least one alkylene oxide with at least 3 carbon atoms in the molecule with an ethylene oxide content of at least 98 %, based on the mixture, is added to the starting substance in an amount of maximally 40 % by weight, based on the weight of the polyether alcohol. At least one alkylene oxide with at least 3 carbon atoms in the molecule or a mixture of ethylene oxide and at least one alkylene oxide with at least 3 carbon atoms in the molecule and an ethylene oxide content of maximally 20 % by weight, based on the mixture, is added.

    65.
    发明专利
    未知

    公开(公告)号：DE19840846A1

    公开(公告)日：2000-03-09

    申请号：DE19840846

    申请日：1998-09-07

    Applicant: BASF AG

    Inventor： GROSCH GEORG HEINRICH ,  LARBIG HARALD ,  LORENZ REINHARD ,  JUNGE DIETER ,  OPPENLAENDER KNUT ,  GUENTHER WOLFGANG ,  KAHMEN MARTIN AUS DEM ,  MOHR JUERGEN ,  HARRE KATHRIN

    IPC: C07C41/03 ,  C07C43/13 ,  C07C67/31 ,  C08G65/26 ,  C07C67/29 ,  B01J31/22 ,  C07C69/30 ,  C07C69/66

    Abstract: The invention relates to a method for the preparation of fatty alcohol alkoxylates by alkoxylation of monovalent aliphatic alcohols with 6 to 24 C atoms or esters from hydroxycarboxylic acids with 6 to 24 C atoms and monovalent or polyvalent alcohols with alkylene oxides in the presence of a double metal cyanide catalyst, containing a double metal cyanide complex compound of general formula (I): M a[M (CN)b(A)c]d . fM gXn . h(H2O). eL, wherein M and M represent certain metal ions which are identical or different; A and X represent anions from the group consisting of halogenide, hydroxide, sulfate, carbonate, cyanide, thiocyanate, isocyanate, cyanate, carboxylate, oxalate or nitrate; L represents a ligand that may be mixed with water from the group consisting of alcohols, aldehyde, ketone, ether, polyether, ester, urea, amide, nitrile and sulfide, wherein a, b, c, d, g and n are selected in such a way that electroneutrality of the compound is guaranteed, e represents a coordination number of the ligand and f and h represent a fractional or whole number higher than 0 or equal 0.

    66.
    发明专利
    未知

    公开(公告)号：DE19742978A1

    公开(公告)日：1999-04-01

    申请号：DE19742978

    申请日：1997-09-29

    Applicant: BASF AG

    Inventor： GROSCH GEORG HEINRICH DR ,  LARBIG HARALD DR ,  LORENZ REINHARD DR ,  JUNGE DIETER ,  GEHRER EUGEN DR ,  TREULING ULRICH DR

    IPC: B01J31/18 ,  B01J27/26 ,  C07F15/02 ,  C07F15/06 ,  C07F19/00 ,  C08G65/10 ,  C08G65/26 ,  C08G65/28 ,  B01J31/16

    Abstract: The invention relates to a crystalline multi-metal cyanide complex of general formula (I) M a[M (CN)bL c]d*e(M fXg)*hL 'iH2O, in which M represents at least one element from the group comprised of Zn(II), Fe(II), Co(III), Ni(II), Mn(II), Co(II), Sn(II), Pb(II), Fe(III), Mo(IV), Mo(VI), Al(III), V(IV), V(V), Sr(II), W(IV), W(VI), Cu(II) and Cr(III). M represents at least one element from the group comprised of Fe(II), Fe (III), Co(III), Cr(III), Mn(II), Mn(III), Ir(III), Rh(III), Ru(II), V(IV), V(V), Co(II) and Cr(II). L represents at least one ligand from the group comprised of cyanide, carbonyl, cyanate, isocyanate, nitrile, thiocyanate and nitrosyl. X represents one formate anion, acetate anion or propionate anion. L represents one ligand which is mixable with water and from the group comprised of alcohols, aldhydes, ketones, ethers, polyethers, esters, urea derivatives, amides, nitriles and sulfides. a, b, c, d, e, f, g, h, i are whole numbers, whereby a, b, c and d are selected such that the electroneutrality condition is fulfilled and f and g are selected such that the electroneutrality condition is also fulfilled. According to the invention, the inventive complex has x-ray diffractogram reflexes at determined d-values and can be used as a catalyst.

    PROCESS FOR PREPARING TWO-METAL CYANIDE CATALYSTS
    68.
    发明专利
    PROCESS FOR PREPARING TWO-METAL CYANIDE CATALYSTS 未知

    公开(公告)号：CA2228651A1

    公开(公告)日：1998-09-06

    申请号：CA2228651

    申请日：1998-03-05

    Applicant: BASF AG

    Inventor： DE VOCHT PETER ,  HOEPPNER GERD ,  LARBIG HARALD ,  GROSCH GEORG HEINRICH ,  GEELEN DANIELLA ,  JUNGE DIETER

    IPC: B01J31/18 ,  B01J27/26 ,  C08G18/48 ,  C08G65/10 ,  C08G65/26 ,  C08F4/54 ,  B01J37/00 ,  C08F4/42 ,  C08G65/28

    Abstract: A process for preparing two-metal cyanide catalysts, comprises combining an aqueous solution of a metal salt of the formula M1m(X)n, where M1 is a metal ion selected from the group consisting of Zn(II), Fe(II), Co(III), Ni(II), Mn(II), Co(II), Sn(II), Pb(II), Fe(III), Mo(IV), Mo(VI), Al(III), V(IV), V(V), Sr(II), W(IV), W(VI), Cr(II), Cr(III), X is an anion selected from the group consisting of halide, hydroxide, sulfate, carbonate, cyanate, thiocyanate, isocyanate, carboxylate, oxalate or nitrate and m and n are derived from the valences of M1 and X, with an aqueous solution of a cyanometalic acid of the formula HaM2(CN)b(A)c, where M2 is a metal ion selected from the group consisting of Fe(II), Fe(III), Co(III), Cr(III), Mn(II), Mn(III), Rh(III), Ru(II), V(IV), V(V), Co(II) and Cr(II), where M2 can be identical to or different from M1. A is an anion selected from the group consisting of halide, hydroxide, sulfate, carbonate, cyanide, thiocyanate, isocyanate, cyanate, carboxylate, oxalate or nitrate, where A can be identical to or different from X, a, b and c are integers and are selected such that the cyanide compound is electrically neutral, where one or both aqueous solutions may comprise at least one water-miscible organic ligand selected from the group consisting of alcohols, aldehydes, ketones, ethers, polyethers, esters, ureas, amides, nitriles or sulfides, if desired, combining the aqueous suspension thus obtained with at least one water-miscible organic ligand selected from the abovementioned group, which ligand may be identical to or different from any previously added ligand, and separating the resulting two-metal cyanide complex from the suspension.

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