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公开(公告)号:DE59106886D1
公开(公告)日:1995-12-21
申请号:DE59106886
申请日:1991-05-07
Applicant: BASF AG
Inventor: OFTRING ALFRED DR , KAPPES ELISABETH DR , BAUR RICHARD DR , KUD ALEXANDER DR
Abstract: New alkylmono- and alkylpolyglucoside ether carboxylate of formula (I) are claimed. In (I) R = 1-24C alkyl or alkylphenyl, hydroxy-(2-6C) alkyl, hydroxy(1-24C)alkyl-phenyl -C(COOX)H-C(COOXH2, -CH2-C(COOX)H-CH2-COOX or H; R1 = H or CH3; R2 = C(COOX)H- C(COOX)H2 or -CH2-C(COOX)H-CH2-COOX; X = H, alkali metal, HN4 and/or substd. NH4; x = 1-10; y = 0-10; z = 1-4.
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公开(公告)号:DE59008897D1
公开(公告)日:1995-05-18
申请号:DE59008897
申请日:1990-12-18
Applicant: BASF AG
Inventor: KUD ALEXANDER DR , BOECKH DIETER DR , TRIESELT WOLFGANG DR , JAEGER HANS-ULRICH DR , HARTMANN HEINRICH DR
IPC: C08G63/20 , C08G63/16 , C08G63/66 , C08G63/668 , C08G63/685 , C11D3/37 , C11D7/60 , D06L3/00 , G03F7/004 , G03F7/032
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公开(公告)号:DE4328670A1
公开(公告)日:1995-03-02
申请号:DE4328670
申请日:1993-08-26
Applicant: BASF AG
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公开(公告)号:DE4311854A1
公开(公告)日:1994-10-13
申请号:DE4311854
申请日:1993-04-10
Applicant: BASF AG
Inventor: KRONER MATTHIAS DR , SCHORNICK GUNNAR DR , BAUR RICHARD DR , KUD ALEXANDER DR , SCHWENDEMANN VOLKER DR
Abstract: PCT No. PCT/EP94/00982 Sec. 371 Date Oct. 10, 1995 Sec. 102(e) Date Oct. 10, 1995 PCT Filed Mar. 29, 1994 PCT Pub. No. WO94/24254 PCT Pub. Date Oct. 27, 1994Use of carboxyl-containing reaction products of (a) maleic anhydride, maleic acid and/or fumaric acid, and (b) proteins or protein hydrolyzates having an acid number of at least 1.5 mmol of NaOH/g of reaction product, as ingredient of reduced-phosphate and phosphate-free detergents and cleaners.
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公开(公告)号:DE4223807A1
公开(公告)日:1994-01-27
申请号:DE4223807
申请日:1992-07-20
Applicant: BASF AG
Inventor: BOECKH DIETER DR , FUNHOFF ANGELIKA DR , KRONER MATTHIAS DR , HARTMANN HEINRICH DR , BAUR RICHARD DR , KUD ALEXANDER DR , SCHWENDEMANN VOLKER DR
IPC: C07C229/22 , C07C235/10 , C07C235/12 , C07D317/34 , C08B31/04 , C08G16/00 , C08G63/91 , C08G69/00 , C08G69/50 , C08G73/02 , C11D3/16 , C11D3/37 , C08G73/00 , C08F8/16
Abstract: The invention concerns condensation products containing N,O-acetal- or carbonamide structures, the products being characterized in that they are obtained by the condensation of (a) compounds containing at least once the structural element (I) or (II) in which X=OH or NHR, R being C1 to C6 alkyl or -CH2-COOH, with (b) aldehydes, ketones or aldehydic or ketonic carboxylic acids to give acetal lactones and by subsequently splitting the acetal lactones with (c) aminocarboxylic acids, primary or secondary amines and/or polyethylenimines to give condensation products containing N,O-acetal- or carbonamide structures. The invention also concerns methods of preparing such products and their use as additives in washing and cleaning agents. The invention further concerns condensation products containing acetal lactone structures produced by reacting (a) hydroxycarboxylic acids or secondary aminoacids with polyhydroxy compounds and condensing with (b) aldehydes, ketones or aldehydic or ketonic carboxylic acids.
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公开(公告)号:DE4221875A1
公开(公告)日:1994-01-05
申请号:DE4221875
申请日:1992-07-03
Applicant: BASF AG
Inventor: KRONER MATTHIAS DR , HARTMANN HEINRICH DR , BOECKH DIETER DR , FUNHOFF ANGELIKA DR , BAUR RICHARD DR , KUD ALEXANDER DR , SCHWENDEMANN VOLKER DR , POTTHOFF-KARL BIRGIT DR , BUECHNER KARL-HEINZ
IPC: C02F5/12 , C08F222/00 , C08F267/00 , C08F283/04 , C08G69/10 , C08G73/10 , C11D3/37 , C13B25/00 , C13B30/02 , C08G69/36 , C08G69/44 , C02F5/10 , C13F1/00
Abstract: Modified polyaspartic acids are obtained by polycondensing (a) 1 to 99.9 mol % aspartic acid with (b) 99 to 0.1 mol % fatty acids, polybasic carboxylic acids, anhydrides of polybasic carboxylic acids, polybasic hydroxycarboxylic acids, monobasic polyhydroxycarboxylic acids, alcohols, amines, alkoxylated alcohols and amines, amino sugars, carbohydrates, sugar carboxylic acids and/or non-proteinogenic aminocarboxylic acids, or by polymerising monoethylenically unsaturated monomers in the presence of polyaspartic acids, in the manner of radically initiated graft copolymerisation. Also disclosed is a process for preparing these modified polyaspartic acids, as well as the use of these modified polyaspartic acids as additives to washing and cleaning agents, as water conditioning agents and as deposit inhibitors during the condensation of sugar juice.
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公开(公告)号:DE4213282A1
公开(公告)日:1993-10-28
申请号:DE4213282
申请日:1992-04-23
Applicant: BASF AG
Inventor: BOECKH DIETER DR , HARTMANN HEINRICH DR , KAPPES ELISABETH DR , OFTRING ALFRED DR , BAUR RICHARD DR , KUD ALEXANDER DR , SCHWENDEMANN VOLKER DR
Abstract: Process for the production of polyesters from (a) citric acid or isocitric acid which may be replaced to the extent of up to 29 mol.% by mono or dibasic hydroxy carboxylic acids or by up to 60 mol.% of other di to tetrabasic aliphatic carboxylic acids, and (b) polyhydroxy compounds of the polysaccharide and modified polysaccharide or polyvinyl alcohol group or their mixtures in such a molar ratio (a):(b) that 1.25 to 12 mol of component (a) is used per quantity of component (b) containing 1 mol hydroxy groups, to form condensation products with a K of 8 to 120, and the use of the polyesters as additives in low-phosphate or phosphate-free washing and cleaning agents in quantities of 0.1 to 30 wt % related to the formulation employed.
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公开(公告)号:DE3868688D1
公开(公告)日:1992-04-09
申请号:DE3868688
申请日:1988-04-14
Applicant: BASF AG
Inventor: SEELMANN-EGGEBERT HANS-PETER D , BOECKH DIETER DR , HARTMANN HEINRICH DR , TRIESELT WOLFGANG DR , KUD ALEXANDER DR
IPC: A01C1/06 , A01N25/26 , C08F2/10 , C08F20/10 , C08F220/04 , C08F220/20 , C08F222/02 , C08F290/00 , C08F299/00 , C08L101/16
Abstract: Water-sol. copolymers have K-value 8-100, pH 7 and Na salt polymer concn. 1 wt.%, and are derived from 99-15 mol.% unsatd. 3-6C moncarboxylic acid(s) (I), 0.5-84.5 mol.% unsatd. 4-6C dicarboxylic acid(s) (II), 0-20 mol.% 2-6C hydroxyalkyl ester(s) (III) of (I), 0-30 mol.% other water-soln. unsatd. comonomers (IV) and 0.5-15 mol.% comonomer(s) (V) with at least 2 non-conjugated double bonds, obtd. by esterification of (I) with polyhydric 2-6C alcohols, polyalkylene glycols of mol. wt. up to 400 (400-10,O00 if water-sol.), polyglycerol of max., mol. wt. 2000, PV-alcohol of max. mol. wt. 10,000 or unsatd. 3-6C mono-ols; polymer segments linked together by units (V) have max. mol. wt. 15,000. Prodn. comprises copolymerisation of (I)-(IV) in aq. soln. in the presence of initiators and of (V), and with 0.2-25 wt.% regulator (can be omitted if amt. of initiator is above 4 wt.%).
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公开(公告)号:AT73146T
公开(公告)日:1992-03-15
申请号:AT88105965
申请日:1988-04-14
Applicant: BASF AG
Inventor: SEELMANN-EGGEBERT HANS-PETER D , BOECKH DIETER DR , HARTMANN HEINRICH DR , TRIESELT WOLFGANG DR , KUD ALEXANDER DR
IPC: A01C1/06 , A01N25/26 , C08F2/10 , C08F20/10 , C08F220/04 , C08F220/20 , C08F222/02 , C08F290/00 , C08F299/00 , C08L101/16
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公开(公告)号:DE4019418A1
公开(公告)日:1992-01-02
申请号:DE4019418
申请日:1990-06-19
Applicant: BASF AG
Inventor: KUD ALEXANDER DR , BOECKH DIETER DR , HARTMANN HEINRICH DR , BAUR RICHARD DR , DIESSEL PAUL
IPC: C08F283/06 , C11D3/00 , C11D3/37
Abstract: Use of graft copolymers obtained by: a) grafting alkylene glycols, polyalkylene glycols with molar masses up to 50,000, polytetrahydrofuran, glycerin, polyglycerin, addition products of alkylene oxides with 2 to 4 carbon atoms on mono- or polyvalent C1-C6 alcohols, as well as chain-lengthened reaction products of the above-mentioned compounds with polyvalent carboxylic acids or polyvalent isocyanates with: b) monoethylenically unsaturated C3-C8 carboxylic acids and possibly: c) other monoethylenically unsaturated compounds at temperatures of 40 to 100 DEG C in the presence of radical-forming initiators, as additives in phosphate-free or low-phosphate washing and cleaning products. The invention relates also to washing and cleaning products containing 0.1 to 15 wt. % of the above-mentioned graft polymerizates.
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