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    2.
    发明专利
    未知

    公开(公告)号：ES2111895T3

    公开(公告)日：1998-03-16

    申请号：ES94900129

    申请日：1993-11-11

    Applicant: BASF AG

    Inventor： PERNER JOHANNES ,  DIESSEL PAUL ,  GUEMBEL HELMUT ,  DENZINGER WALTER ,  HARTMANN HEINRICH ,  KRONER MATTHIAS

    IPC: C02F5/10 ,  C08L33/02 ,  C08L35/00 ,  H04L27/20 ,  C08L51/02 ,  C08L77/04 ,  C11D3/37 ,  H04B7/00 ,  H04J3/16 ,  H04J3/22 ,  H04J3/24 ,  H04J11/00 ,  H04J13/00 ,  H04J13/18 ,  H04L20060101 ,  H04L1/00 ,  H04L1/08 ,  H04L12/00 ,  H04L27/30 ,  H04L29/06 ,  H04Q7/38

    Abstract: PCT No. PCT/EP93/03159 Sec. 371 Date May 22, 1995 Sec. 102(e) Date May 22, 1995 PCT Filed Nov. 11, 1993 PCT Pub. No. WO94/12571 PCT Pub. Date Jun. 9, 1994Mixtures of (I) polymers of monoethylenically unsaturated dicarboxylic acids having a molecular weight of from 200 to 5,000 and (II) (1) copolymers having a molecular weight of from 10,000 to 150,000 and comprising (a) from 10 to 70% by weight of monoethylenically unsaturated C4-C8-dicarboxylic acids or the salts thereof and (b) from 30 to 90% by weight of monoethylenically unsaturated C3-C10-monocarboxylic acids and/or the salts thereof, (2) graft polymers having a molecular weight of from 5,000 to 150,000, which are obtainable by free radical graft polymerization of (A) monoethylenically unsaturated C3-C10-carboxylic acids or the anhydrides and/or the salts thereof in the presence of (B) mono-, oligo- or polysaccharides and the derivatives thereof in a weight ratio (A) : (B) of (95 to 20) : (5 to 80), and/or (3) polyaminocarboxylic acids and/or polymers containing aminocarboxylic acid groups contain the components (I) and (II) in a weight ratio of from 10 : 0.5 to 0.5 : 10 and are used as additives for phosphate-free or low-phosphate textile detergents or as dispersants or coating inhibitors in cleaners for hard surfaces.

    3.
    发明专利
    未知

    公开(公告)号：DE59204523D1

    公开(公告)日：1996-01-11

    申请号：DE59204523

    申请日：1992-09-04

    Applicant: BASF AG

    Inventor： KRONER MATTHIAS ,  HARTMANN HEINRICH ,  WOLF GERHARD ,  BAUR RICHARD ,  DIESSEL PAUL ,  JAEGER HANS-ULRICH ,  SCHWENDEMANN VOLKER ,  PERNER JOHANNES

    IPC: C08F16/14 ,  C08F216/14 ,  C11D3/37

    Abstract: PCT No. PCT/EP92/02041 Sec. 371 Date Feb. 10, 1994 Sec. 102(e) Date Feb. 10, 1994 PCT Filed Sep. 4, 1992 PCT Pub. No. WO93/06142 PCT Pub. Date Apr. 1, 1993Copolymers of hydroxyalkyl vinyl ethers are obtainable by cationic or free radical copolymerization of (a) from 99 to 1% by weight of a hydroxyalkyl vinyl ether, (b) from 1 to 99% by weight of an adduct of a C2-C4-alkylene oxide with a hydroxyalkyl vinyl ether and (c) from 0 to 98% by weight of other copolymerizable monomers, and the stated copolymer and hydroxyalkyl vinyl ethers polymerized by cationic or free radical polymerization, which contain the monomers (a) or (b) as sole monomers or as a mixture with other copolymerizable monomers in the form of polymerized units, are used as additives for detergents and cleaning agents in amounts of from 0.1 to 50% by weight.

    4.
    发明专利
    未知

    公开(公告)号：DE58908529D1

    公开(公告)日：1994-11-24

    申请号：DE58908529

    申请日：1989-11-06

    Applicant: BASF AG

    Inventor： PERNER JOHANNES DR ,  DIESSEL PAUL ,  HARTMANN HEINRICH DR ,  DENZINGER WALTER ,  OFTRING ALFRED DR ,  SCHOENLEBEN WILLIBALD DR

    IPC: C11D3/32 ,  C11D3/37

    Abstract: The use of copolymers which contain as essential copolymerised units (a) 50 to 99 mol% of units of monoethylenically unsaturated (a) C3- to C8-monocarboxylic acids, monoethylenically unsaturated C4- to C8-dicarboxylic acids, hemiesters of monoethylenically unsaturated C4- to C8-dicarboxylic acids, esters of monoethylenically unsaturated C3- to C8-carboxylic acids, C2- to C30-olefins, styrene, C1- to C3-alkylstyrenes, C1- to C28-alkyl vinyl ethers, vinyl esters of saturated C1- to C8- carboxylic acids or mixtures of units of these monomers and (b) 50 to 1 mol% of units of amides of monoethylenically unsaturated C3- to C8-carboxylic acids with amide groups of the structure … … in which R = C8- to C28- alkyl, … … R , R = H, CH3, C2H5 R = C1- to C28-alkyl, n = 2 to 100 and R = H, R have K values of 8 to 200, or of salts of these copolymers, as additive to liquid detergent compositions in an amount of 0.1 to 20% by weight and aqueous liquid detergent compositions which contain these copolymers.

    5.
    发明专利
    未知

    公开(公告)号：DE58906888D1

    公开(公告)日：1994-03-17

    申请号：DE58906888

    申请日：1989-10-21

    Applicant: BASF AG

    Inventor： DIESSEL PAUL ,  PERNER JOHANNES DR ,  DENZINGER WALTER ,  HARTMANN HEINRICH DR ,  RAUBENHEIMER HANS-JUERGEN

    IPC: C08F8/14 ,  C08L67/00 ,  C11D3/37

    Abstract: The use of partially esterified copolymers which can be obtained by copolymerisation of (a) at least one C4- to C28-olefin and (b) ethylenically unsaturated dicarboxylic anhydrides with 4 to 8 C atoms in the molar ratio 1:1 and subsequent partial esterification of the copolymers with reaction products of (A) C1- to C30-alcohols, C8- to C22-fatty acids, C1- to C12-alkylphenols or secondary C2- to C30-amines with (B) at least one C2- to C4-alkylene oxide or tetrahydrofuran in the molar ratio (A):(B) of 1:2 to 50 and hydrolysis of the anhydride groups of the copolymers to carboxyl groups, where the partial esterification of the copolymers is continued until more than 5 to 50% of the carboxyl groups in the copolymers are esterified, as additive to liquid detergent compositions in an amount of 0.1 to 20% by weight and liquid detergent compositions which contain the partially esterified copolymers.

    USE OF PARTIALLY ESTERIFIED COPOLYMERS IN LIQUID DETERGENTS
    8.
    发明专利
    USE OF PARTIALLY ESTERIFIED COPOLYMERS IN LIQUID DETERGENTS 未知

    公开(公告)号：AU4384089A

    公开(公告)日：1990-05-03

    申请号：AU4384089

    申请日：1989-10-30

    Applicant: BASF AG

    Inventor： DIESSEL PAUL ,  PERNER JOHANNES ,  DENZINGER WALTER ,  HARTMANN HEINRICH ,  RAUBENHEIMER HANS-JUERGEN

    IPC: C08F8/14 ,  C08L67/00 ,  C11D3/37 ,  C11D3/60

    Abstract: The use of partially esterified copolymers which can be obtained by copolymerisation of (a) at least one C4- to C28-olefin and (b) ethylenically unsaturated dicarboxylic anhydrides with 4 to 8 C atoms in the molar ratio 1:1 and subsequent partial esterification of the copolymers with reaction products of (A) C1- to C30-alcohols, C8- to C22-fatty acids, C1- to C12-alkylphenols or secondary C2- to C30-amines with (B) at least one C2- to C4-alkylene oxide or tetrahydrofuran in the molar ratio (A):(B) of 1:2 to 50 and hydrolysis of the anhydride groups of the copolymers to carboxyl groups, where the partial esterification of the copolymers is continued until more than 5 to 50% of the carboxyl groups in the copolymers are esterified, as additive to liquid detergent compositions in an amount of 0.1 to 20% by weight and liquid detergent compositions which contain the partially esterified copolymers.

    USE OF PARTIALLY ESTERIFIED COPOLYMERS IN LIQUID DETERGENTS
    9.
    发明专利
    USE OF PARTIALLY ESTERIFIED COPOLYMERS IN LIQUID DETERGENTS 未知

    公开(公告)号：CA2000731A1

    公开(公告)日：1990-04-30

    申请号：CA2000731

    申请日：1989-10-16

    Applicant: BASF AG

    Inventor： DIESSEL PAUL ,  PERNER JOHANNES ,  DENZINGER WALTER ,  HARTMANN HEINRICH ,  RAUBENHEIMER HANS-JUERGEN

    IPC: C08F8/14 ,  C08L67/00 ,  C11D3/37

    Abstract: O.Z. 0050/40290 Liquid, alkaline detergent formulations which contain as essential constituents a surfactant, water and 0.1-20% by weight of partially esterified copolymers are obtainable by the copolymerization of (a) one or moxe C4-C28-olefins and (b) ethylenically unsaturated dicarboxylic anhydrides of from 4 to 8 carbon atoms in a molar ratio of 1:1 and subsequent partial esterification of the copolymers of the reaction products (A) C1-C30-alcohols,C8-C22-fatty acids,C1-C12-alkylphenols or secondary C2-C30-amines with (B) one or more C2-C4-alkylene oxides or tetrahydrofuran in a molar ratio of (A):(B) of from 1:2 to 1:50 and hydrolysis of the anhyaride groups of the copolymer to carboxyl groups, the partial esterification of the copolymers being carried on until more than 5 to 50% of the carboxyl groups of the copolymers have been esterified.

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