63.
    发明专利
    未知

    公开(公告)号:DE59505070D1

    公开(公告)日:1999-03-25

    申请号:DE59505070

    申请日:1995-06-16

    Applicant: BASF AG

    Abstract: The prodn. of aliphatic and cycloaliphatic oximes (1) comprises reacting the corresp. imine (2) with oxygen or oxygen-contg. gas in the presence of a catalyst, except for catalysts of formula (Tix(M*D1-x)(2n/3*E1-x))O2 (I), where D = Si or Ge; E = Ce of Al; x = 0.06-0.9; m = 1 if n = 0; m = 0 if n = 1. Also claimed is a process for the prodn. of (1) comprising (a) imination of the corresp. ketone with ammonia by known methods followed by (b) catalytic oxidn. of the imine as above.

    70.
    发明专利
    未知

    公开(公告)号:DE19641481A1

    公开(公告)日:1998-04-16

    申请号:DE19641481

    申请日:1996-10-09

    Applicant: BASF AG

    Abstract: The invention concerns a process for preparing polytetrahydrofuran, copolymers of tetrahydrofuran and 2-butin-1,4-diol, diesters of these polymers with C2-C20 monocarboxylic acids or monoesters of these polymers with C1-C10 monocarboxylic acids by polymerizing tetrahydrofuran in the presence of one of the following telogens, water, 1,-4-butane diol, 2-butin-1,4-diol, polytetrahydrofuran with a molecular weight of between 200 and 700 Dalton, or of a C1-C10 monocarboxylic acid or a carboxylic acid anhydride produced from C2-C20 monocarboxylic acids or mixtures of these telogens on a heterogeneous carrier catalyst which contains a catalytically active amount of an oxygenous molybdenum and/or tungsten compound on an oxidic carrier material, and which has been calcined at temperatures of between 500 DEG C and 1000 DEG C after application of the precursor compounds of the oxygenous molybdenum and/or tungsten compounds to the carrier material precursors. Before it is used as a polymerization catalyst, the catalyst is activated by treatment with a reducing agent.

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