公开(公告)号：CA2352377A1

公开(公告)日：2000-06-08

申请号：CA2352377

申请日：1999-11-23

Applicant: BASF AG

Inventor： SCHWAB PETER ,  WOLF JUSTIN ,  WERNER HELMUT ,  SCHULZ MICHAEL

IPC: B01J31/24 ,  C07F15/00

Abstract: The invention relates to a method of producing ruthenium complexes of genera l formula (I): RuX2(=CH-CH2R)L1L2, wherein X is an anionic ligand, R is hydrog en or an optionally substituted C1-20 alkyl radical or C6-20 aryl radical, and L1 and L2 independently are neutral electron-donor ligands. Said ruthenium complexes are produced by a) reacting RuX3 with a diene in a solvent on the basis of one or several aliphatic secondary alcohols in the presence of a reducing adjuvant, reacting said mixture with L1 and L2 in the presence of a t least one coordinating weak base and hydrogen and without isolating any intermediates, b) reacting the mixture with compounds of general formula (II ): R-C~CH, wherein R has the meaning indicated above, in the presence of a soluble chloride source.

公开(公告)号：CA2264305A1

公开(公告)日：1999-09-27

申请号：CA2264305

申请日：1999-03-25

Applicant: BASF AG

Inventor： MEYER GERALD ,  SCHWAB PETER ,  BREITSCHEIDEL BORIS ,  SCHULZ RALF ,  SCHULZ MICHAEL

IPC: B01J23/36 ,  C07B61/00 ,  C07C6/02 ,  C07C7/163 ,  C07C11/06 ,  C07C41/06 ,  C10G35/06 ,  C07C11/02 ,  C07C7/08

Abstract: The preparation of olefins from steam cracker or refinery C4 streams is carried out by A) if desired, extractive distillation of butadiene from the C4 stream using a butadiene-selective solvent, B) selective hydrogenation of butadienes and acetylenic impurities in the steam cracker or refinery C4 stream or the stream from step A), with simultaneous or subsequent, at least partial isomerization of 1-butene to 2-butene, C) removal of i-butene from the C4 stream obtained in step B) by reaction with an alcohol to form an ether, D) removal of oxygen-containing impurities from the C4 stream obtained in step C) using adsorber materials, E) two-stage metathesis of the butenes in the C4 stream obtained in step D) by conversion of 1-butene and 2-butene present in the C4 stream into propene and 2-pentene and subsequent reaction of the 2-pentene with ethene in the presence of a metathesis catalyst to form propene and 1-butene.

公开(公告)号：DE19805716A1

公开(公告)日：1999-08-19

申请号：DE19805716

申请日：1998-02-12

Applicant: BASF AG

Inventor： SCHWAB PETER ,  BREITSCHEIDEL BORIS ,  OOST CARSTEN ,  SCHULZ RALF ,  SCHULZ MICHAEL

IPC: B01J23/36 ,  B01J23/46 ,  C07B61/00 ,  C07C2/10 ,  C07C4/10 ,  C07C6/04 ,  C07C11/06 ,  C07C11/08 ,  C08F2/00

Abstract: Preparation of propene and optionally 1-butene comprises converting butene isomers to propene isomers using metathesis catalyst and converting formed 2-pentene to propene and 1-butene, isolating and recycling the 2-butene fraction. Preparation of propene and optionally 1-butene comprises: (a) converting 1-butene and 2-butene in the presence of a metathesis catalyst containing group VIb, VIIb or VIII metals; (b) removing propene and 2-pentene formed; (c) converting the 2-pentene using ethene to propene and 1-butene in the presence of the metathesis catalyst in (a); (d) removing propene and 1-butene formed; and (e) discharging the 1-butene and partially isomerizing 1-butene to 2-butene in the presence of a catalyst and recycling the 1-butene and 2-butene with a part of the unreacted 4C-fraction from (a) to (a). An Independent claim is also included for the apparatus for carrying out the preparation of propene and 1-butene comprising a metathesis reactor (R01) connected to a distillation column (K101) for removing 2/3C low boiling, 4C middle boiling and 5C+ high boiling phases; column (K301) for removing ethene and propene; and reactor (R02) for reacting 2-pentene with ethene.

公开(公告)号：MX9810300A

公开(公告)日：1999-04-30

申请号：MX9810300

申请日：1998-12-07

Applicant: BASF AG

Inventor： GROSCH GEORG HEINRICH ,  MUELLER ULRICH ,  SCHULZ MICHAEL ,  RIEBER NORBERT ,  WUERZ HARALD

IPC: C07D301/06 ,  B01J29/04 ,  B01J29/89 ,  C07D301/04 ,  C07D301/10 ,  C07D303/04

Abstract: PCT No. PCT/EP97/02821 Sec. 371 Date Dec. 14, 1998 Sec. 102(e) Date Dec. 14, 1998 PCT Filed May 30, 1997 PCT Pub. No. WO97/47386 PCT Pub. Date Dec. 18, 1997An oxidation catalyst based on titanium silicalites or vanadium silicalites having a zeolite structure and containing from 0.01 to 30% by weight of one or more noble metals selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium, platinum, rhenium, gold and silver has been molded by a compacting shaping process. This oxidation catalyst is used for the preparation of epoxides, in particular propylene oxide, from olefins, hydrogen and oxygen.

公开(公告)号：BG62166B1

公开(公告)日：1999-04-30

申请号：BG10182497

申请日：1997-08-08

Applicant: BASF AG

Inventor： TELES JOAQUIM H ,  SCHNURR WERNER ,  FISCHER ROLF ,  RIEBER NORBERT ,  SCHULZ MICHAEL

IPC: C07C45/41 ,  C07D301/14 ,  C07D303/04

Abstract: The invention concerns the production of epoxides fromolefins using aromatic peroxycarboxylic acids. Followingepoxidisation (step A), the aromatic carboxylic acids therebyproduced are separated from the epoxides and catalyticallyhydrated (step B) to form the corresponding aromatic aldehydeswhich are then oxidised (step C) with oxygen or with anoxygen-containing gas mixture to form again the aromaticperoxycarboxylic acids which can be used again to produce theepoxides.

公开(公告)号：AU9345198A

公开(公告)日：1999-03-16

申请号：AU9345198

申请日：1998-08-20

Applicant: BASF AG

Inventor： SCHWAB PETER ,  SCHULZ MICHAEL ,  WOLF JUSTIN ,  STUER WOLFRAM ,  WERNER HELMUT

IPC: B01J31/00 ,  B01J31/22 ,  C07F9/50 ,  C07F15/00 ,  C08F4/80 ,  C08F32/04 ,  C08G61/08

Abstract: Ruthenium complexes of the formula I or IVwhereX, Y are anionic ligands,R is hydrogen or a substituted or unsubstituted C1-C20-alkyl radical or C6-C20-aryl radical andL1 and L2 are, independently of one another, uncharged electron donor ligands, are prepared by(a) reaction of RuX3 with L1 and L2 in an inert solvent in the presence of a reducing agent and hydrogen and(b) reaction with compounds of the formula IIwhere R is as defined above, in the presence or absence of water, and, if desired after isolation of the intermediate, with HY, [HL1]Y or [HL2]Y.

公开(公告)号：HU9801678A2

公开(公告)日：1998-11-30

申请号：HU9801678

申请日：1996-02-10

Applicant: BASF AG

Inventor： FISCHER ROLF ,  RIEBER NORBERT ,  SCHNURR WERNER ,  SCHULZ MICHAEL ,  TELES JOAQUIM HENRIQUE

IPC: C07C45/41 ,  C07D301/14 ,  C07D303/04

Abstract: PCT No. PCT/EP96/00578 Sec. 371 Date Aug. 5, 1997 Sec. 102(e) Date Aug. 5, 1997 PCT Filed Feb. 10, 1996 PCT Pub. No. WO96/26198 PCT Pub. Date Aug. 29, 1996Preparation of epoxides from olefins by means of aromatic peroxycarboxylic acids comprises a step A of epoxidizing the olefin and removing the resulting aromatic carboxylic acid from the epoxide, a step B of catalytically hydrogenating the removed aromatic carboxylic acid to the corresponding aromatic aldehyde, and a step C of oxidizing this aldehyde with oxygen or an oxygen-containing gas mixture back to the aromatic peroxycarboxylic acid for re-use for epoxidizing an olefin.

公开(公告)号：MX9801801A

公开(公告)日：1998-08-30

申请号：MX9801801

申请日：1998-03-06

Applicant: BASF AG

Inventor： SCHULZ MICHAEL ,  TELES JOAQUIM HENRIQUE ,  SUNDERMEYER JOERG ,  WAHL GUENTER

IPC: B01J31/16 ,  B01J31/18 ,  B01J31/22 ,  C07B61/00 ,  C07D301/06 ,  C07D301/12 ,  C07D303/04

Abstract: Las olefinas se pueden epoxidar usando los catalizadores I: (Ver Formula) donde M es una metal del grupo de transicion 4. a 7?? de la Tabla periodica de los Elementos, L1 es una ligadura de oxido de amina, oxido de fosfina, oxido de areina, N-oxido de piridina o piridina, de las formulas II, III, VII o VII, L2 es una ligadura auxiliar acostumbrada o una ligadura ulterior L1, o un sitio de coordinacion libre, X es oxígeno de oxo o una ligadura de imido, m es 1 o 2, y n es 1, 2 o 3.

公开(公告)号：CA2256383A1

公开(公告)日：1997-12-18

申请号：CA2256383

申请日：1997-05-30

Applicant: BASF AG

Inventor： WUERZ HARALD ,  RIEBER NORBERT ,  GROSCH GEORG HEINRICH ,  SCHULZ MICHAEL ,  MUELLER ULRICH

IPC: C07D301/06 ,  B01J29/04 ,  B01J29/89 ,  C07D301/04 ,  C07D301/10 ,  C07D303/04 ,  C07D301/08

Abstract: An oxidation catalyst based on titanium or vanadium silicalites with a zeolithic structure and containing 0.01 to 30 wt.% of one or more noble metals from the group ruthenium, rhodium, palladium, osmium, iridium, platinum, rhenium, gold and silver, in which the oxidation catalyst is formed by solidifying shaping processes. Said oxidation catalyst is used in the production of epoxides, especially propylene oxide, from olefines, hydrogen and oxygen.

公开(公告)号：MX9706068A

公开(公告)日：1997-10-31

申请号：MX9706068

申请日：1996-02-10

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE ,  SCHNURR WERNER ,  FISCHER ROLF ,  RIEBER NORBERT ,  SCHULZ MICHAEL

IPC: C07C45/41 ,  C07D301/14 ,  C07D303/04

Abstract: La preparacion de epoxidos de olefinas por medio de ácidos peroxicarboxílicos aromáticos comprende un paso A de epoxidar la olefina y remover el ácido carboxílico aromático resultante del epoxido, un paso B de hidrogenar catalíticamente elácido carboxílico aromático removido el aldehído aromático correspondiente y un paso C de oxidar este aldehído con oxígeno o una mezcla de gas que contiene oxígeno de nuevo en el ácido peroxicarboxílico aromático para re-utilizacion para oxidar una olefina.