公开(公告)号：EP3980581A1

公开(公告)日：2022-04-13

申请号：EP20728762.4

申请日：2020-05-28

Applicant: BASF SE ,  thyssenkrupp AG ,  thyssenkrupp Industrial Solutions AG

Inventor： SCHEIFF, Frederik ,  LEDUC, Marc ,  KOLIOS, Grigorios ,  DALOZ, William ,  BUEKER, Karsten ,  ANTWEILER, Nicolai ,  BODE, Andreas

IPC: C25C3/06 ,  C25C3/12 ,  C25C7/02

公开(公告)号：EP3833471A1

公开(公告)日：2021-06-16

申请号：EP19748545.1

申请日：2019-08-05

Applicant: BASF SE

Inventor： KOLIOS, Grigorios ,  ZOELS, Bernd ,  APPEL, Hagen ,  BERNNAT, Jens ,  GLENK, Friedrich ,  FLICK, Dieter ,  OLBERT, Gerhard ,  SCHEIFF, Frederik ,  ANDERLOHR, Christopher Alec

IPC: B01J19/24 ,  C04B35/01

公开(公告)号：EP3512628A1

公开(公告)日：2019-07-24

申请号：EP17764612.2

申请日：2017-09-12

Applicant: BASF SE

Inventor： KERN, Matthias ,  KOLIOS, Grigorios ,  SCHMIDT, Sabine ,  LAIB, Heinrich ,  SCHEIFF, Frederik ,  ZOELS, Bernd

IPC: B01J19/24 ,  F28F7/02 ,  F28F21/04

公开(公告)号：EP3194333A1

公开(公告)日：2017-07-26

申请号：EP15754117.8

申请日：2015-08-13

Applicant: BASF SE

Inventor： MAASS, Hans-Jürgen ,  MACHHAMMER, Otto ,  BODE, Andreas ,  KOLIOS, Grigorios

IPC: C01B3/24 ,  C01B3/28 ,  C01B32/40 ,  C10J3/00 ,  C01B3/34

CPC classification number: C01B3/28 ,  C01B3/24 ,  C01B5/00 ,  C01B31/18 ,  C01B32/40 ,  C01B2203/0216 ,  C01B2203/0222 ,  C01B2203/0238 ,  C01B2203/0272 ,  C01B2203/0838 ,  C01B2203/1235 ,  Y02P20/13 ,  Y02P20/142

Abstract: The invention relates to a method for generating syngas (5). Hydrocarbon (2) is thermally decomposed into hydrogen and carbon in a first reaction zone (Z1), and hydrogen produced in the process is conducted from the first reaction zone (Z1) to a second reaction zone (Z2) in order to react the hydrogen with carbon monoxide (4) in the second reaction zone so as to produce water and carbon monoxide. The invention is characterized in that the energy required for the thermal hydrocarbon decomposition in the first reaction zone (Z1) is supplied from the second reaction zone (Z2).

Abstract translation: 本发明涉及用于产生合成气（5）的方法。 烃（2）在第一反应区（Z1）中热分解成氢和碳，并且在该过程中产生的氢从第一反应区（Z1）传导到第二反应区（Z2）以使氢气 与第二反应区中的一氧化碳（4）反应以产生水和一氧化碳。 本发明的特征在于，第一反应区（Z1）中热烃分解所需的能量从第二反应区（Z2）供给。

公开(公告)号：EP2935098A1

公开(公告)日：2015-10-28

申请号：EP13865384.5

申请日：2013-12-17

Applicant: BASF SE

Inventor： KERN, Matthias ,  GLENK, Friedrich ,  KLINGLER, Dirk ,  BODE, Andreas ,  KOLIOS, Grigorios ,  SCHUNK, Stephan ,  WASSERSCHAFF, Guido ,  BERNNAT, Jens ,  ZOELS, Bernd ,  SCHMIDT, Sabine ,  KÖNIG, Rene

IPC: C01B31/18 ,  C01B3/24

CPC classification number: C01B3/24 ,  C01B3/38 ,  C01B32/40 ,  C01B2203/0238 ,  C01B2203/0272 ,  C01B2203/0283 ,  C01B2203/1235 ,  C10J3/06 ,  C10K3/026 ,  Y02P20/129 ,  Y02P20/146

Abstract: The invention relates to a process for the parallel preparation of hydrogen, carbon monoxide and a carbon-comprising product, wherein one or more hydrocarbons are thermally decomposed and at least part of the pyrolysis gas formed is taken off from the reaction zone of the decomposition reactor at a temperature of from 800 to 1400°C and reacted with carbon dioxide to form a gas mixture comprising carbon monoxide and hydrogen (synthesis gas).

公开(公告)号：EP2729405B1

公开(公告)日：2015-08-19

申请号：EP12734811.8

申请日：2012-07-05

Applicant: Linde Aktiengesellschaft ,  BASF SE

Inventor： MASS, Hans-Jürgen ,  GÖKE, Volker ,  MACHHAMMER, Otto ,  GUZMANN, Marcus ,  SCHNEIDER, Christian ,  HORMUTH, Wolfgang Alois ,  BODE, Andreas ,  KLINGLER, Dirk ,  KERN, Matthias ,  KOLIOS, Grigorios

IPC: C01B31/18 ,  C01B3/34 ,  C01B31/02

CPC classification number: C01B3/344 ,  C01B32/40 ,  C01B2203/0222 ,  C01B2203/042 ,  C01B2203/0425 ,  C01B2203/049 ,  C01B2203/0822 ,  C01B2203/085 ,  C01B2203/0872 ,  C01B2203/1241 ,  Y02P20/128 ,  Y02P20/584

公开(公告)号：EP2506963B1

公开(公告)日：2014-11-05

申请号：EP10784530.7

申请日：2010-11-30

Applicant: BASF SE

Inventor： KOLIOS, Grigorios ,  RUPPEL, Wilhelm ,  WEGERLE, Ulrike ,  KESSEL, Jasmina ,  GERLINGER, Wolfgang ,  MABANDE, Godwin, Tafara, Peter ,  SCHINDLER, Goetz-Peter ,  KOSTOVA, Albena ,  OLBERT, Gerhard ,  PFAB, Peter

IPC: B01J19/24

CPC classification number: B01J19/2485 ,  B01J2219/182

公开(公告)号：EP2739388A1

公开(公告)日：2014-06-11

申请号：EP12740994.4

申请日：2012-08-01

Applicant: BASF SE

Inventor： OLBERT, Gerhard ,  WEGERLE, Ulrike ,  KOLIOS, Grigorios ,  TELLAECHE HERRANZ, Carlos ,  HÖCHST, Reinhold ,  GIENGER, Andrea ,  BAUER, Roland

IPC: B01J19/24 ,  C07C5/48

CPC classification number: B01J19/2485 ,  B01J2219/00155 ,  B01J2219/2411 ,  B01J2219/2416 ,  B01J2219/2419 ,  B01J2219/2422 ,  B01J2219/2443 ,  C07C5/32 ,  Y02P20/52 ,  C07C11/06 ,  C07C11/08 ,  C07C15/46

Abstract: The invention relates to a reactor (1) in the form of a cylinder or prism for carrying out autothermal gas-phase dehydrogenation of a gas flow (2) containing hydrocarbons by means of a gas flow (3) containing oxygen so as to obtain a reaction gas mixture, on a heterogeneous catalyst, which is designed as a monolith (4), the interior of the reactor (1) being divided by a circular cylindrical or prismatic gas-tight housing (G) arranged in the longitudinal direction of the reactor (1) into an inner region (A) having one or more catalytically active zones (5), in each of which a respective packing of monoliths (4) stacked one on the other, one next to the other, and one behind the other and, before each catalytically active zone (5), a respective mixing zone (6) having fixed installations are provided, and an outer region (B) arranged coaxial with the inner region (A), said reactor being characterized in that the inner region (A) is insulated from the outer region (B) of the reactor by means of a microporous high-performance insulating material (15) having a thermal conductivity value (λ) less than 0.05 W/m*K at temperatures up to 700 °C.

公开(公告)号：EP2729404A2

公开(公告)日：2014-05-14

申请号：EP12743884.4

申请日：2012-07-05

Applicant: Linde Aktiengesellschaft ,  BASF SE

Inventor： MAA , Hans-Jürgen ,  GÖKE, Volker ,  MACHHAMMER, Otto ,  GUZMANN, Marcus ,  SCHNEIDER, Christian ,  HORMUTH, Wolfgang Alois ,  BODE, Andreas ,  KLINGLER, Dirk ,  KERN, Matthias ,  KOLIOS, Grigorios

IPC: C01B3/28 ,  C01B31/02 ,  C01B3/30

CPC classification number: C01B3/24 ,  C01B3/28 ,  C01B3/30 ,  C01B32/05 ,  C01B2203/0272 ,  C01B2203/04 ,  C01B2203/0425 ,  C01B2203/0485 ,  C01B2203/049 ,  C01B2203/06 ,  C01B2203/0805 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/0827 ,  C01B2203/0866 ,  C01B2203/1235 ,  C01B2203/1258 ,  C10B57/005 ,  Y02P20/128

Abstract: The invention relates to a method for the parallel production of hydrogen and of one or more carbon-containing products. In the method, hydrocarbons are introduced into a reaction chamber (R) and are thermally decomposed into carbon and hydrogen in the presence of a carbon-rich granulated material (W). The invention is characterised in that at least a portion of the thermal energy necessary for the decomposition of the hydrocarbon is introduced into the reaction chamber (R) via a gaseous heat transfer medium.

公开(公告)号：EP2681178A1

公开(公告)日：2014-01-08

申请号：EP12706605.8

申请日：2012-03-02

Applicant: BASF SE

Inventor： KOSTOVA, Albena ,  BENFER, Regina ,  GÖTZ, Jochen ,  REZAI, Alireza ,  MORILLO, Aristides ,  OLBERT, Gerhard ,  PFAB, Peter ,  KOLIOS, Grigorios ,  WEBER, Markus ,  WECK, Alexander

IPC: C07C7/04 ,  C07C7/08 ,  C07C7/11 ,  C07C11/08 ,  C07C11/167 ,  C07C9/10

CPC classification number: B01D3/40 ,  C07C7/04 ,  C07C7/08 ,  C07C7/11 ,  C07C11/16 ,  C07C11/167

Abstract: The invention relates to a process for workup of a stream (1) comprising butene and/or butadiene, butane, hydrogen and/or nitrogen and carbon dioxide, comprising the following steps: (a) absorption of the stream (1) comprising butene and/or butadiene, butane, hydrogen and/or nitrogen, with or without carbon dioxide, with a mixture (5) comprising 80 to 97% by weight of N-methylpyrrolidone and 3 to 20% by weight of water to obtain a stream (9) comprising N-methylpyrrolidone, water, butene and/or butadiene, and butane, with or without carbon dioxide, and a stream (7) comprising hydrogen and/or nitrogen and butane, (b) extractive distillation of the stream (9) comprising N-methylpyrrolidone, water, butene and/or butadiene, and butane, with or without carbon dioxide, with a stream (13) comprising 80 to 97% by weight of N-methylpyrrolidone and 3 to 20% by weight of water to separate the stream (9) comprising N-methylpyrrolidone, water, butene and/or butadiene, and butane, with or without carbon dioxide, into a stream (17) comprising N-methylpyrrolidone, water, butene and/or butadiene, and a stream (15) comprising essentially butane, with or without carbon dioxide, (c) distillation of the stream (17) comprising N-methylpyrrolidone, water, butene and/or butadiene into a stream (23) comprising essentially N-methylpyrrolidone and water, and a stream (21) comprising butene and/or butadiene.

Abstract translation: 本发明涉及包含丁烯和/或丁二烯，丁烷，氢气和/或氮气和二氧化碳的物流（1）的处理方法，其包括以下步骤：（a）将包含丁烯和 （5）包含80-97重量％的N-甲基吡咯烷酮和3-20重量％的水以获得流（9），所述混合物（5）包含具有或不具有二氧化碳的丁二烯，丁烷，氢和/ ）包含N-甲基吡咯烷酮，水，丁烯和/或丁二烯和丁烷（含有或不含二氧化碳）以及包含氢和/或氮和丁烷的物流（7），（b）物流（9）的萃取蒸馏包含 （13）包含80-97重量％的N-甲基吡咯烷酮和3-20重量％的水以分离含有或不含二氧化碳的N-甲基吡咯烷酮，水，丁烯和/或丁二烯和丁烷， 包含N-甲基吡咯烷酮，水，丁烯和/或丁二烯和丁烷的物流（9），有或没有汽车 （17），包含N-甲基吡咯烷酮，水，丁烯和/或丁二烯，以及基本上包含丁烷的物流（15），其中含有或不含有二氧化碳，（c）蒸馏包含N （23）和包含丁烯和/或丁二烯的物流（21），所述物流（23）基本上包含N-甲基吡咯烷酮和水。