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公开(公告)号:JPS53125495A
公开(公告)日:1978-11-01
申请号:JP4030077
申请日:1977-04-11
Applicant: TORAY INDUSTRIES
Inventor: MINAMI TOMOYUKI , SUZUKI MASARU , ODAJIMA AKIO
Abstract: PURPOSE:To prepare a polyester containing uniform and fine particles from coarse aggregated particles, by esterifying terephthalic acid with ethylene glycol (or by ester interchange of a terephthalate with ethylene glycol), and by adding the reaction product thus obtained to a slurry of inert inorganic particles in ethylene glycol after a specific treatment, followed by polycondensation.
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公开(公告)号:JPS5360952A
公开(公告)日:1978-05-31
申请号:JP13541476
申请日:1976-11-12
Applicant: TORAY INDUSTRIES
Inventor: SUZUKI MASARU , ODAJIMA AKIO , MINAMI TOMOYUKI , FUJITA SABUROU , MOGI MASAHIKO , OKAMOTO SATORU
IPC: B29C55/00 , B29C49/00 , B29C55/12 , C08G63/18 , C08G63/78 , C08J5/18 , C08K3/10 , C08K3/36 , C08K13/02 , C08L67/00 , C08L67/02
Abstract: PURPOSE:To manufacture the title film capable of being formed at high speed and having excellent transparency and handling easiness, by incorporating polyethylene terephthalate film with reactive fine particles consisting of compounds having a specific element such as calcium, and, as inert particles, a specific amount of silica compound.
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公开(公告)号:JP2002256140A
公开(公告)日:2002-09-11
申请号:JP2001057958
申请日:2001-03-02
Applicant: TORAY INDUSTRIES
Inventor: SHIMIZU YUZO , ODAJIMA AKIO
Abstract: PROBLEM TO BE SOLVED: To obtain a polyester composition for a film for lamination with a metallic sheet satisfactory in the dispersedness of particles and fabricability and excellent in whiteness, adhesion to metallic sheet, fabricability in a can making process, chipping resistance, printability, and resistance to film peel caused by heat in drying after can making, baking of print, retort sterilization, etc., heat resistance. SOLUTION: The polyester composition contains titanium oxide particles containing aluminum and satisfies the relationships (1) and (2): [η]=[η]0 -[η]8 g)}.
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公开(公告)号:JP2002241594A
公开(公告)日:2002-08-28
申请号:JP2001037418
申请日:2001-02-14
Applicant: TORAY INDUSTRIES
Inventor: OKUMURA MITSUO , SHIMIZU YUZO , ODAJIMA AKIO
Abstract: PROBLEM TO BE SOLVED: To obtain a polyester composition which is used for metal plate- laminated films and has good particle dispersibility, good film formability, excellent whiteness, excellent adhesivity to metal plates, excellent formability in can-forming processes, excellent abrasion resistance, excellent printability, and excellent heat resistance, and to obtain a film comprising the polyester composition. SOLUTION: This polyester composition for metal plate-laminated films contains silicon element and aluminum element and further contains titanium oxide particles having wettability at a specific value.
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公开(公告)号:JP2002226683A
公开(公告)日:2002-08-14
申请号:JP2001030708
申请日:2001-02-07
Applicant: TORAY INDUSTRIES
Inventor: FUJITA AKIHARU , SHIMIZU YUZO , ODAJIMA AKIO
Abstract: PROBLEM TO BE SOLVED: To obtain a polyester composition for a film used for laminating metal plates in which particle dispersion and film moldability are good and whiteness, adhesion to the metal plate, moldability in a can manufacturing process, shaving resistance, printability and heat resistance are also excellent, and also to obtain a film using the same. SOLUTION: The polyester composition for the film for laminating the metal plates contains aluminum element and titanium oxide particles treated with a polyol compound, and the film is produced with the same.
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公开(公告)号:JP2002201341A
公开(公告)日:2002-07-19
申请号:JP2001001810
申请日:2001-01-09
Applicant: TORAY INDUSTRIES
Inventor: SHIMIZU YUZO , MATSUOKA HIROSHI , ODAJIMA AKIO
Abstract: PROBLEM TO BE SOLVED: To obtain a polyester composition for a metal plate laminated film, having good particle dispersibility and formability of the film and having excellent whiteness, adhesion to the metal plate, formability during can manufacturing processes, chipping and heat resistances and printability and the film comprising the same polyester composition. SOLUTION: This polyester composition for the metal plate laminated film comprises titanium oxide particles containing silicon element and aluminum element. The film comprises the polyester composition.
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公开(公告)号:JPH10287800A
公开(公告)日:1998-10-27
申请号:JP9611497
申请日:1997-04-14
Applicant: TORAY INDUSTRIES
Inventor: ODAJIMA AKIO , UEMATSU KIMITAKE , SUGANUMA HEIROKU
Abstract: PROBLEM TO BE SOLVED: To obtain a composition being excellent in heat stability as a polymer and electrostatic application characteristic, giving a molding excellent in abrasion resistance and running performance and being excellent in productivity in film formation by adding a specified amount of aluminum silicate particles having a mean article diameter and an aluminum fraction in specified ranges to a polyester to form a composition which shows a specified resistance in a specified range when molten. SOLUTION: This composition contains 0.005-10 wt.% aluminum silicate particles having a means particle diameter of 0.001-3 μm and an aluminum fraction of 5-30 wt.% and shows a specific resistance of 1×10 to 5×10 Ω.cm when molten. It is desirable to use calcium carbonate or aluminum silicate particles in combination with the aluminum silicate particles. It is desirable that the calcium carbonate particles have a mean particle diameter larger than that of the aluminum silicate particles and are contained in an amount of 0.005-10 wt.% based on the composition. It is desirable that the aluminum oxide particles have a mean particle diameter of 0.001-0.5 μm and are contained in an amount of 0.01-3 wt.% based on the composition.
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公开(公告)号:JPH0967509A
公开(公告)日:1997-03-11
申请号:JP22640295
申请日:1995-09-04
Applicant: TORAY INDUSTRIES
Inventor: MIZOGUCHI MAMORU , HAYASHI GEN , ODAJIMA AKIO
Abstract: PROBLEM TO BE SOLVED: To provide a polyester composition which has excellent moldability and can give a film excellent in slipperiness, abrasion resistance and scratch resistance by using internal deposition type particles having a specified particle diameter and a specified particle diameter distribution. SOLUTION: This polyester composition contains internal deposition type particles prepared by performing the reaction for producing a polyester in the presence of 0.05-3.0mol%, based on the total dicarboxylic acid component, total of an alkali metal compound and an hlkaline earth metal compound and 0.05-1.5mol%, based on the total dicarboxylic acid component, phosphorus compound to deposit particles during the reaction. Because the internal deposition type particles have a mean particle diameter of 0.5-10.0μm and an at least bimodal particle diameter distribution, this composition has excellent moldability such as fiber-forming properties and film-forming properties and can give a molding excellent in slipperiness and surface properties.
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公开(公告)号:JP2507491B2
公开(公告)日:1996-06-12
申请号:JP28154487
申请日:1987-11-06
Applicant: TORAY INDUSTRIES
Inventor: SAEKI TOMOJI , ODAJIMA AKIO , SUZUKI MASARU
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公开(公告)号:JPH08127647A
公开(公告)日:1996-05-21
申请号:JP26883094
申请日:1994-11-01
Applicant: TORAY INDUSTRIES
Inventor: ODAJIMA AKIO , HAYASHI GEN , OYAMA MASAHIKO
IPC: C08L67/00 , C08G63/183 , C08G63/78 , C08L67/02 , C08L83/04
Abstract: PURPOSE: To obtain a polyester composition providing a film having uniform and fine surface, excellent wear resistance and falling resistance by adding organic particles and an organic polysiloxane to a reaction system at a specific stage of a polycondensation process. CONSTITUTION: First, terephthalic acid or its ester-forming derivative is transesterified or esterified with glycol. Then the reaction product is subjected to polycondensation reaction. At a stage in which the intrinsic viscosity in the polycondensation process does not exceed 0.2, organic particles (preferably cross-linked polymer particles having
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