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公开(公告)号：ZA200710451B
公开(公告)日：2010-02-24
申请号：ZA200710451
申请日：2007-12-03
Applicant: BASF AG
Inventor： HAUK ALEXANDER , GROPP STEFAN , LENZ ROBERT , HEILEK JOERG , RIECK DANIELA , LAUX GERHARD
IPC: C07C20100101
Abstract: The calculation of the above balance shows that the division of stream (5) into the streams (5a) and (5b) used here leads to the fact that in the neutralization stage no excess sodium formate is produced, so that any ejection can be omitted. Furthermore, the water content of the stream (14) comprising sodium formate recirculated to the first crystallization stage in this case can be set to a very low value.
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公开(公告)号：BRPI0514558A
公开(公告)日：2008-06-17
申请号：BRPI0514558
申请日：2005-08-22
Applicant: BASF AG
Inventor： KARL J RN , HAUK ALEXANDER
Abstract: The present invention relates to a process for preparing formic acid by thermally decomposing ammonium formates of tertiary amines A, wherein the tertiary amine A on which the ammonium formate is based has a boiling point at atmospheric pressure in the range from 105 to 175° C.
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公开(公告)号：PL1682476T3
公开(公告)日：2007-10-31
申请号：PL04797653
申请日：2004-11-05
Applicant: BASF AG
Inventor： HAUK ALEXANDER , KARL JÖRN , PASCHOLD JÜRGEN , GROPP STEFAN , LOHMANN ANNA VALESKA , LENZ ROBERT , LETZELTER THOMAS , HEINZ ROBERT
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公开(公告)号：NO20071045A
公开(公告)日：2007-03-22
申请号：NO20071045
申请日：2007-02-23
Applicant: BASF AG
Inventor： HAUK ALEXANDER , KARL JORN
IPC: C07C53/02
CPC classification number: C07C51/02 , C07C51/09 , Y02P20/582 , C07C53/02
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公开(公告)号：DE102005020890A1
公开(公告)日：2006-11-09
申请号：DE102005020890
申请日：2005-05-04
Applicant: BASF AG
Inventor： HAUK ALEXANDER , GROPP STEFAN , LENZ ROBERT , RIECK DANIELA , HEILEK JOERG , LAUX GERHARD
Abstract: The calculation of the above balance shows that the division of stream (5) into the streams (5a) and (5b) used here leads to the fact that in the neutralization stage no excess sodium formate is produced, so that any ejection can be omitted. Furthermore, the water content of the stream (14) comprising sodium formate recirculated to the first crystallization stage in this case can be set to a very low value.
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Patent Agency Ranking
公开(公告)号：NO20062261L
公开(公告)日：2006-07-27
申请号：NO20062261
申请日：2006-05-19
Applicant: BASF AG
Inventor： HEINZ ROBERT , HAUK ALEXANDER , LENZ ROBERT , LOHMANN ANNA VALESKA , KARL JORN , PASCHOLD JUERGEN , GROPP STEFAN , LETZELTER THOMAS
Abstract: A process is proposed for preparing acid formates in which a liquid stream I comprising formic acid and a liquid stream II comprising a metal formate are prepared, the liquid streams I and II are fed to a rectification column in such a manner that a higher or identical feed point to the rectification column is chosen for the liquid stream II than for the liquid stream I, the liquid streams I and II are mixed in the rectification column, with water being removed overhead from the rectification column and a bottoms stream comprising the acid formate is taken off from the rectification column, which comprises the bottoms stream being produced as melt comprising less than 0.5% by weight of water.
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公开(公告)号：AR044327A1
公开(公告)日：2005-09-07
申请号：ARP040101638
申请日：2004-05-14
Applicant: BASF AG
Inventor： HAUK ALEXANDER , KARL JOERN , LENZ ROBERT , ADAMI CHRISTOPH
IPC: C07C51/41 , C07C53/02 , C07C53/06 , C07C51/09 , A23L3/3508
Abstract: Un proceso para la preparación de formiatos ácidos mediante la provisión de una corriente líquida (I) que contiene ácido fórmico y una corriente líquida (II) que contiene un formiato de metal y la mezcla de la corriente líquida (I) con al corriente líquida (II), para obtener el correspondiente formiato ácido, que comprende la alimentación a la corriente líquida (I) o uno de sus precursores, a la corriente líquida (II) o uno de sus precursores, o a la mezcla de las corrientes líquidas(I) y (II), de una corriente líquida (III) que contiene los siguientes componentes en contenidos de, en cada caso, > 0,1 % en peso: formiato de metal, metóxido de metal, metanol y MeFo (MeFo), que se produce en un proceso para la preparación de MeFo por carbonilación de metanol en un reactor a una presión absoluta de hasta 50 MPa en presencia de un metóxido de metal como catalizador homogéneo. Uso de formiatos ácidos preparados en el proceso descripto para conservar y/o acidificar material vegetal y/o material animal, para el tratamiento de desechos biológicos, o como aditivo para la nutrición animal y/o como promotor del crecimiento de animales.
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公开(公告)号：PL373315A1
公开(公告)日：2005-08-22
申请号：PL37331503
申请日：2003-07-07
Applicant: BASF AG
Inventor： SCHOENHERR MICHAEL , KARL JOERN , HAUK ALEXANDER , DIEBOLD GERD , HABICH ANDREAS , LENZ ROBERT , LOHMANN ANNA VALESKA , SCHMIDT VOLKER
Abstract: The present invention relates to preparations comprising at least one diformate of the general formula XH(COOH) 2 , where X=Na, K, Cs, NH 4 and at least one short-chain carboxylic acids and/or at least one salt of the short-chain carboxylic acid and/or at least one ester and/or at least one derivative of the short-chain carboxylic acid, and to the use of these preparations.
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公开(公告)号：PL372605A1
公开(公告)日：2005-07-25
申请号：PL37260503
申请日：2003-07-07
Applicant: BASF AG
Inventor： SCHOENHERR MICHAEL , KARL JOERN , HAUK ALEXANDER , DIEBOLD GERD , HABICH ANDREAS , LENZ ROBERT , LOHMANN ANNA VALESKA , SCHMIDT VOLKER , HJORNEVIK LEIF
IPC: A23K3/03 , A23K1/00 , A23K1/16 , A23K1/175 , A23K1/18 , A23K3/00 , A23L1/00 , A23P1/04 , C05F11/00 , C05G3/00 , C05G3/60
Abstract: Coated formulation contains sodium, potassium, cesium and/or ammonium diformate(s) (I). Coated formulation contains diformate(s) of formula (I): [Image] X : Na, K, Cs, NH 4. Independent claims are also included for the following: (1) production of coated formulations by coating diformate(s) (I), optionally mixed with other constituents and/or additives, with a coating agent, optionally containing other constituents; (2) production of animal feed and/or animal feed additives by making a premix from (I) and optionally other constituents and/or additives and mixing this with the other constituents of the feed and/or additive; and (3) animal feed containing the formulation. ACTIVITY : Plant Growth Promoter; Fertilizer. MECHANISM OF ACTION : None given.
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公开(公告)号：BR0313245A
公开(公告)日：2005-06-14
申请号：BR0313245
申请日：2003-07-30
Applicant: BASF AG
Inventor： ADAMI CHRISTOPH , KARL JOERN , HAUK ALEXANDER , BOEHLING RALF , PASTRE JOERG , LENZ ROBERT
IPC: A23K1/16 , A01N1/00 , A01N3/00 , A61K31/19 , A61P3/00 , B01D9/02 , C07C51/09 , C07C51/41 , C07C53/06 , C07C53/02
Abstract: Formic acid-formates are produced by (a) partial hydrolysis of methyl formate (MF) with water, (b) distillation to give (S1) formic acid and water, (c) conversion of the other product from (b) (mainly MF) into a stream (S2) containing formate and water by reaction with aqueous strong base and distillation of methanol, and (d) combination of (S1) with (S2). A method for the production of formic acid-formates (I) involves: (a) partial hydrolysis of methyl formate (MF) with water; (b) distillation to give a stream (S1) containing formic acid and water; (c) conversion of the MF- and possibly methanol-containing stream from (b) into a formate- and water-containing stream (S2) by (i) reaction with a basic compound of an acid with a pKa value of at least 3 in presence of water followed by (ii) removal of methanol by distillation; and (d) combination of streams (S1) and (S2). An Independent claim is also included for apparatus for the production of (I), comprising: (A) a reactor for the hydrolysis of MF; (B) a distillation column for separating a stream containing MF, formic acid, methanol and water; (C) a column for the hydrolysis of MF with a basic compound with removal of methanol by distillation (with an inlet for the base above the inlet for the product from (B)); and (D) a column connected to the bottom of (B) for removing water from the stream containing formic acid and water.
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