公开(公告)号：DE4039918A1

公开(公告)日：1992-06-17

申请号：DE4039918

申请日：1990-12-14

Applicant: BASF AG

Inventor： BRENNER KARL ,  GOETZ NORBERT ,  HENKELMANN JOCHEM DR ,  KUEKENHOEHNER THOMAS DR ,  SPIEGLER WOLFGANG DR

IPC: B01J23/48 ,  B01J23/72 ,  C07B61/00 ,  C07D309/06

Abstract: Disclosed is a method for the preparation of formyltetrahydropyrans (I) by dehydrogenating hydroxymethyltetrahydropyrans (II) in the presence of a copper, silver and/or gold catalyst. The formyltetrahydropyrans (I) thus obtained are useful intermediates in the preparation of pharmaceuticals and phytopathalogical products.

公开(公告)号：DE3700808A1

公开(公告)日：1988-07-28

申请号：DE3700808

申请日：1987-01-14

Applicant: BASF AG

Inventor： HEINZ GERHARD DR ,  KOCH JUERGEN DR ,  EGGERSDORFER MANFRED DR ,  HENKELMANN JOCHEM DR

IPC: C08G65/40 ,  C08G61/00

Abstract: Polyaryl ether ketones are prepared by reacting aromatic dihydroxy compounds with aromatic dihalogen compounds in polar aprotic solvents in the presence of alkali metal carbonates, in particular by reacting aromatic dihydroxy compounds I (I) or ring-substituted C1-C8-alkyl, C1-C8-alkoxy, aryl, chlorine or fluorine derivatives thereof, n and m each being 0 or 1, with aromatic dihalogen compounds (II) or ring-substituted C1-C8-alkyl, C1-C8-alkoxy, aryl, chlorine or fluorine derivatives thereof, r and s each being 0 or 1, A being oxygen or a chemical bond and X being chlorine or fluorine.

公开(公告)号：ES2151216T3

公开(公告)日：2000-12-16

申请号：ES97117797

申请日：1997-10-14

Applicant: BASF AG

Inventor： PREISS THOMAS DR ,  HENKELMANN JOCHEM DR ,  WULFF-DORING JOACHIM DR ,  STUTZ SUSANNE DR ,  RUHL THOMAS DR

IPC: C07B61/00 ,  C07C213/00 ,  B01J23/72 ,  C07C213/02 ,  C07C215/08 ,  C07C217/08

Abstract: Preparation of N-hydroxyalkyl -substituted amino-alkynol derivatives of formula (I) involves reaction of an alkyne of formula R1-C IDENTICAL CH (II) with a 1-oxa-3-aza-heterocycloalkane of formula (III) over a heterogeneous catalyst comprising a compound of a first or second transition group metal. R1= H, alkyl, haloalkyl, cycloalkyl, aryl, alkoxy, alkoxyalkyl, hydroxyalkyl or -CR2R3-N(R4)-A-OH; R2-R4 = H, alkyl, haloalkyl, cycloalkyl, aryl, alkoxy, alkoxyalkyl or hydroxyalkyl; A = 2-5C alkylene (optionally substituted by one or more of alkyl, haloalkyl, aryl, alkoxy, hydroxy and hydroxyalkyl).

公开(公告)号：DE59602064D1

公开(公告)日：1999-07-08

申请号：DE59602064

申请日：1996-08-28

Applicant: BASF AG

Inventor： HENKELMANN JOCHEM DR ,  HEIDER MARC DR ,  RUEHL THOMAS DR

IPC: C07C269/06 ,  C07D263/22

Abstract: Prodn. of N-alkenylcarbamic acid esters of formula HR C=CR -N(R )-C(O)-O-R (I) is new, in which at least one of the R gps. = H and the other = H or 1-4C alkyl; R = aliphatic, cycloaliphatic, araliphatic or aromatic gp., opt. combined with R to form a 2- to 10-membered bridging gp.; and R = aliphatic, cycloaliphatic or aromatic gp. The process comprises reacting an alkenyl ester of formula HR C=CR -O-C(O)-R (II) (in which R = H or an aliphatic, cycloaliphatic or aromatic gp.) with a carbamate ester of formula HR N-C(O)-O-R (III) in presence of a base. Pref. in the formulae, R = H; R = 1-20C alkyl, or R + R = 2-7C alkylene.

公开(公告)号：DE19753458A1

公开(公告)日：1999-06-10

申请号：DE19753458

申请日：1997-12-02

Applicant: BASF AG

Inventor： BOETTCHER ARND DR ,  HENKELMANN JOCHEM DR ,  PREISS THOMAS DR ,  BRUNNER MELANIE DR

IPC: B01J23/84 ,  B01J31/22 ,  C07B61/00 ,  C07C29/42 ,  C07C33/042 ,  C07C209/60 ,  C07C211/23 ,  C07C213/00 ,  C07C213/02 ,  C07C215/24 ,  B01J31/00 ,  C07B43/04 ,  C07C41/26 ,  C07C211/20 ,  C07C215/22 ,  C07D211/04 ,  C07D295/04

Abstract: The invention relates to a method for preparing a catalyst through activation of a catalytic material comprising a) at least one metal from the first or second side group or one compound thereof and b) optionally a carrier. This catalyst is characterised in that the material is treated with an alkine of formula (I): R1-CC-R , in which R represents alkyl, cycloalkyl, aryl, hydroxyalkyl, alkyl halide, alkoxy or alkoxyalkyl, R represents hydrogen, alkyl, cycloalkyl or aryl, as well as with a carbonyl compound of formula (II), in which R and R represent independently from each other hydrogen, alkyl, alkyl halide, cycloalkyl or aryl. The invention also relates to catalysts obtained according to said method, and to alkinylations and aminoalkylations using said catalysts.

公开(公告)号：DE19747407A1

公开(公告)日：1999-04-29

申请号：DE19747407

申请日：1997-10-27

Applicant: BASF AG

Inventor： BOETTCHER ARND DR ,  HENKELMANN JOCHEM DR ,  BROECKER FRANZ JOSEF DR

IPC: B01J23/46 ,  C01B15/013 ,  C01B15/023 ,  C07C37/00 ,  C07C45/61 ,  C07C49/737 ,  C07C39/08

Abstract: In the catalytic hydrogenation of anthraquinone compounds, the homogeneous catalyst comprises sub-group VIII metals, deposited in situ on a support.

公开(公告)号：DE59503848D1

公开(公告)日：1998-11-12

申请号：DE59503848

申请日：1995-11-21

Applicant: BASF AG

Inventor： KARCHER MICHAEL DR ,  HEIDER MARC DR ,  RUEHL THOMAS DR ,  HENKELMANN JOCHEM DR

IPC: C07C249/12 ,  C07C251/54 ,  C09D129/10 ,  C09J129/10

Abstract: Novel oxime ethers of formula (I) are claimed as are also (i) prepn. of (I) by reaction of an oxime ether alcohol of formula (II) with an alkyne of formula (III) in presence of a base; and (ii) use of (i) as a comonomer in the prodn. of polymeric coatings or adhesives. R and R = H, 1-20C alkyl, 4-10C cycloalkyl, or 6-10C aryl or together form a 3-14C bridge; R = H, 1-4C alkyl or phenyl opt. with an inert substit.; n = 1-100; and A = 2-10C alkylene opt. with an inert substit.

公开(公告)号：CZ74198A3

公开(公告)日：1998-09-16

申请号：CZ74198

申请日：1996-09-11

Applicant: BASF AG

Inventor： RUTTER HEINZ DR ,  RUHL THOMAS DR ,  BREITSCHEIDEL BORIS DR ,  HENKELMANN JOCHEM DR ,  HENNE ANDREAS DR ,  WETTLING THOMAS DR

IPC: B01J23/46 ,  B01J21/04 ,  B01J23/89 ,  B01J35/10 ,  C07B61/00 ,  C07C209/72 ,  C07C211/35

Abstract: Aromatic compounds in which at least one amino group is bonded to an aromatic nucleus are catalytically hydrogenated in the liquid phase by a process in which the catalyst consists essentially of ruthenium and, optionally at least one metal of subgroup I, VII or VIII in an amount of from 0.01 to 30% by weight, based on the total weight of the catalyst, applied to a carrier which has a mean pore diameter of at least 0.1 mu m and a surface area of not more than 15 m2/g.

公开(公告)号：DE59502089D1

公开(公告)日：1998-06-10

申请号：DE59502089

申请日：1995-08-09

Applicant: BASF AG

Inventor： RUEHL THOMAS DR ,  HENKELMANN JOCHEM DR ,  HEIDER MARC DR ,  FIECHTER BERND

IPC: C07C231/14 ,  C07C231/08 ,  C07C231/12 ,  C07C233/03 ,  C07C233/04 ,  C07C233/05 ,  C07C233/58 ,  C07C233/65

公开(公告)号：DE59209291D1

公开(公告)日：1998-05-28

申请号：DE59209291

申请日：1992-01-22

Applicant: BASF AG

Inventor： KARCHER MICHAEL DR ,  ZIMMERMANN HORST DR ,  HENKELMANN JOCHEM DR

IPC: C07C37/50 ,  C07C39/08 ,  C07C41/28 ,  C07C43/23

Abstract: Pyrocatechol monoethers or pyrocatechols of the general formula Ia and Ib, respectively, (R and R = H or C1-C8-hydrocarbon radicals; R = C1-C8-hydrocarbon radical) are prepared by a) reacting a 2-hydroxycyclohexanone dialkyl ketal II in the gas phase in the presence of a platinum metal or of a compound of one of these metals as catalyst, so as to obtain the compounds Ia, and b) carrying out step a) in the presence of water so as to obtain the compounds Ib. The products can be used as intermediates for the synthesis of pharmaceutical products, odoriferous substances and flavourings.