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公开(公告)号:AT98271T
公开(公告)日:1993-12-15
申请号:AT88115295
申请日:1988-09-17
Applicant: BASF AG
Inventor: FIKENTSCHER ROLF DR , LACH DIETRICH DR , SCHAFFER ORTWIN DR , STREICHER ROLF , OFTRING ALFRED DR
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公开(公告)号:DE4216560A1
公开(公告)日:1993-11-25
申请号:DE4216560
申请日:1992-05-20
Applicant: BASF AG
Inventor: KNEIP MICHAEL DR , SCHNEIDER JUERGEN DR , OFTRING ALFRED DR
IPC: C07C227/02 , C07C227/00 , C07C227/14 , C07C227/26 , C07C229/16 , C11D3/33
Abstract: The invention relates to a process for producing beta-alanine diacetic acid (Ia) or its alkali metal or ammonium salts (Ib) in which imino diacetic acid is caused to react with acryl nitrile or C1-C4 alkyl acrylic acid esters in a slightly acid to slightly basic aqueous medium and then the nitrile or ester groups are saponified to the acid or a salt. The products made according to the invention are particularly useful as complex formers.
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公开(公告)号:DE4211140A1
公开(公告)日:1993-10-07
申请号:DE4211140
申请日:1992-04-03
Applicant: BASF AG
Inventor: BURKHART BERND DR , OFTRING ALFRED DR , SCHWENDEMANN VOLKER DR , GLASER KLAUS
Abstract: Phosphonium salts of formula (I) in which: R to R are C1 to C18 alkyl which may be substituted by carboxyl groups or C1 to C4 alkoxycarbonyl groups or cyano groups, C2 to C12 alkenyl, C2 to C12 alkinyl, C5 to C8 cycloalkyl, C7 to C12 phenylalkyl, phenyl which may be substitued by one or two C1 to C4 alkyl radicals, C1 to C4 alkoxy radicals, halogen atoms, hydroxyl groups, phenyl radicals or C1 to C4 alkoxy carbonyl groups, or mono or di(C1 to C4 alkyl)amino; R and R are hydrogen or C1 to C4 alkyl; A is hydrogen or a group of the formula -OCO-H, -CO-R , -CO-OH, -CO-OR , -CO-CH2-CO-OR , -O-CO-H, O-CO-R , -OR , -SO2-R , -SO2-OH, -SO2-OR , -PO(OH)2, PO(OH)(OR ), -PO(OR )2, -OPO(OH)2, -OPO(OH)(OR ) or -OPO(OR )2; where R is C1 to C12 alkyl, C2 to C12 alkenyl, C2 to C12 alkinyl, C5 to C8 cycloalkyl, C7 to C12 phenylalkyl or phenyl which may be substituted by one or two C1 to C4 alkyl radicals, C1 to C4 alkoxy radicals, halogen atoms, hydroxyl groups, phenyl radicals or C1 to C4 alkoxy carbonyl groups; Y stands for the group -CH=CH- or -C=C-; m is a number from 0 to 10; n is a number from 1 to 4; p is 0 or 1; and q is a number from 0 to 10; and X- is an n-valent inorganic or organic anion improving water solubility. The phosphonium salts I are suitable as brighteners for aqueous-acid galvanic nickel baths.
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公开(公告)号:AT92952T
公开(公告)日:1993-08-15
申请号:AT89115874
申请日:1989-08-29
Applicant: BASF AG
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公开(公告)号:DE4108626A1
公开(公告)日:1992-09-17
申请号:DE4108626
申请日:1991-03-16
Applicant: BASF AG
Inventor: KAPPES ELISABETH DR , OFTRING ALFRED DR , BAUR RICHARD DR , KUD ALEXANDER DR
IPC: C07C67/08 , C07C69/704 , C07C219/06 , C07H13/04 , C07H15/04 , C11D3/20 , C11D3/22 , C11D3/30
Abstract: Esters are disclosed of citric acid or acetylcitric acid anhydride with compounds containing at least 3 OH groups selected in the group formed by polyglycerine, sucrocarboxylic acids, alkylglucosides, derivates of oligosaccharides, aminosorbit, aminodisorbit, glucosamine, triethanolamine and trishydroxyethyl-melamine, in which each OH group of the ester alcohol components is esterified in average with 0.15 to 1 molecule citric acid or acetylcitric acid anhydride. Also disclosed is the use of these citric acid esters as additives to phosphate-poor or phosphate-free washing and cleaning products.
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公开(公告)号:DE4103968A1
公开(公告)日:1992-08-13
申请号:DE4103968
申请日:1991-02-09
Applicant: BASF AG
Inventor: HOUBEN JOCHEN DR , MUELLER JOSEF DR , OFTRING ALFRED DR , WIDDER RUDI DR
IPC: C07C303/24 , C07C305/06 , C07D213/20 , C07D231/14 , C07D233/60 , C07D295/08
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公开(公告)号:DE3868118D1
公开(公告)日:1992-03-12
申请号:DE3868118
申请日:1988-04-02
Applicant: BASF AG
Inventor: BAUR RICHARD DR , RICHTER FELIX DR , BIRNBACH STEFAN DR , FIKENTSCHER ROLF DR , OFTRING ALFRED DR , WINKLER EKHARD DR
IPC: C11D3/26 , C07C67/00 , C07C229/22 , C07C229/32 , C07C231/00 , C07C231/12 , C07C237/06 , C07C253/00 , C07C255/18 , C07C255/24 , C09K3/00 , C11D3/33 , C11D3/39
Abstract: Various new processes are claimed for the prodn. of serine N,N-diacetic acid and N,N-diacetonitrile derivs. if formula (I): (where Y is COOH (opt. in the form of an alkali metal, ammonium or substd. ammonium salt) or CH; and X is COOH (opt. in the form of an alkali metal, ammonium or substd. ammonium salts), CN or a residue CONR3R4 in which R3 and R4 are H or 1-4C alkyl; X not being CN when Y is COOH). The use of serine-N,N-diacetic acid (I,X=COOH, Y=COOH) and its Na, K, ammonium and organic amine salts as complexing agents for heavy metals and/or alkaline earth ions and an building agents and bleach stabilisers in washing and cleaning agents is now. Detergents and cleaning agents contg. 0.01-20 wt.% of (I) (X other than CN) are new and claimed. Serine-N,N-diacetonitrile (i.e. (I,X COOH, Y=CN)) is new and claimed per se.
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公开(公告)号:DE4015655A1
公开(公告)日:1991-11-21
申请号:DE4015655
申请日:1990-05-16
Applicant: BASF AG
Inventor: OFTRING ALFRED DR , KAPPES ELISABETH DR , BAUR RICHARD DR , KUD ALEXANDER DR
Abstract: New alkylmono- and alkylpolyglucoside ether carboxylate of formula (I) are claimed. In (I) R = 1-24C alkyl or alkylphenyl, hydroxy-(2-6C) alkyl, hydroxy(1-24C)alkyl-phenyl -C(COOX)H-C(COOXH2, -CH2-C(COOX)H-CH2-COOX or H; R1 = H or CH3; R2 = C(COOX)H- C(COOX)H2 or -CH2-C(COOX)H-CH2-COOX; X = H, alkali metal, HN4 and/or substd. NH4; x = 1-10; y = 0-10; z = 1-4.
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公开(公告)号:DE3925727A1
公开(公告)日:1991-02-07
申请号:DE3925727
申请日:1989-08-03
Applicant: BASF AG
Inventor: BAUR RICHARD DR , GOUSETIS CHARALAMPOS DR , BIRNBACH STEFAN DR , KNEIP MICHAEL DR , OFTRING ALFRED DR
IPC: C07H5/04 , C07C229/22 , C11D3/33 , C11D3/37 , C11D3/39
Abstract: The use of 2-hydroxy-3-aminopropionic acid derivatives of the general formula I … … in which X is hydrogen, an alkali metal or ammonium which can be substituted by C1-C4-alkyl groups or C1-C4-hydroxyalkyl groups, and in which the groups Y and Y have the following meanings …… A) omega -substituted alkyl groups of the general formula… -(CH2)m-R … in which R is hydrogen, a hydroxyl group or the groups -COOX, -NH-CH(COOX)-CH2-COOX or -NY Y , and m has values from 1 to 20, with the exception of the value m = 1 in the case where Y and Y are identical and R is the group -COOX, … B) polyether groups of the general formula… -(CH2CH2O)m-R … in which R is hydrogen or a C1-C4-alkyl group, … C) beta -hydroxy-substituted groups of the general formula … … in which R is the groups -COOX, -CH2OH and -CH2-NY Y and n has values from 1 to 5, … D) alpha -carboxy-substituted groups of the general formula … … in which R is hydrogen, a methyl group or a hydroxymethyl group, and R is a hydroxymethyl group or the groups -CH(OH)-COOX or -(CH2)p-COOX where p is 1 or 2, … E) pyranosyl or furanosyl groups of the general formula … … in which q has the value 3 or 2, or … F) polymer residues of polyvinylamine or polyethyleneimine as complexing agents, bleach stabilisers and builders in detergents and cleaners. …
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公开(公告)号:DE3901613A1
公开(公告)日:1990-08-16
申请号:DE3901613
申请日:1989-01-20
Applicant: BASF AG
Inventor: OFTRING ALFRED DR , BIRNBACH STEFAN DR , FIKENTSCHER ROLF DR , BAUR RICHARD DR , KUD ALEXANDER DR , GOECKEL ULRICH DR , PERNER JOHANNES DR
IPC: C11D1/72 , C07C229/24 , C07C309/13 , C09K3/00 , C09K23/28 , C09K23/42 , C11D3/33
Abstract: Glycerol aminocarboxylates of the formula (I) where n is from 0 to 10 and R is where L is iminodiacetate, aspartate, glutamate, sarcosinate, glycinate, serinate, hydroxyaspartate, ethanolaminoacetate, diethanolamino, alanate or taurinate and X is hydrogen, an alkali metal, ammonium or substituted ammonium, are prepared by esterifying glycerol or polyglycerols which contain up to 10 glycerol units with maleic anhydride or itaconic anhydride and addition of compound L-H where L is as defined above to the double bonds of the esters, and are used as complexing agents.
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