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公开(公告)号:DE3927619A1
公开(公告)日:1991-02-28
申请号:DE3927619
申请日:1989-08-22
Applicant: BASF AG
Inventor: REHMER GERD DR , AUCHTER GERHARD DR
IPC: C08F220/18 , C08F224/00 , C08F226/06 , C08F228/06 , C08F246/00 , C09D157/04 , C09J157/04
Abstract: The invention relates to copolymers built up from A) from 99.5 to 75 % of olefinically unsaturated monomers containing hetero atoms, B) from 0.5 to 25 % of unsaturated compounds of the formula I and C) from 0 to 20 % of further olefinically unsaturated monomers where X is O, S or NR and R is optionally substituted C2-C6-alkylene, and R is C1- to C8-alkyl or phenyl. The products according to the invention are suitable as coating and impregnation compositions and in particular as contact adhesives.
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公开(公告)号:DE3914374A1
公开(公告)日:1990-10-31
申请号:DE3914374
申请日:1989-04-29
Applicant: BASF AG
Inventor: REHMER GERD DR , BOETTCHER ANDREAS DR
IPC: C08L57/00 , C08F2/38 , C08F2/44 , C08F2/48 , C08F246/00 , C08K5/17 , C09J157/04
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公开(公告)号:DE3836968A1
公开(公告)日:1990-05-03
申请号:DE3836968
申请日:1988-10-31
Applicant: BASF AG
Inventor: REHMER GERD DR , BOETTCHER ANDREAS DR , PFOEHLER PETER DR , AYDIN ORAL DR , NESTLER GERHARD DR
IPC: C08J5/18 , C08F220/18 , C08L23/00 , C08L33/04 , C08L33/06 , C09J133/06
Abstract: Compositions which can be crosslinked under an atmospheric oxygen atmosphere by means of ultraviolet irradiation and are based on (meth)acrylate copolymers having a K value of from 10 to 100, obtained by free-radical polymerisation in solid phase or solution of a) 5 to 97.4% by weight of i-amyl acrylate and/or i-amyl methacrylate and b) 0 to 89.9% by weight of (meth)acrylates whose hompolymers have a glass transition temperature of below -30 DEG C, c) 2.5 to 30% by weight of alpha , beta -monoolefinically unsaturated compounds whose homopolymers have a glass transition temperature of above - 30 DEG C, d) 0 to 10% by weight of monoolefinically unsaturated acids and/or anhydrides thereof, e) 0 to 20% by weight of further olefinically unsaturated monomers containing at least one of the following functional groups: hydroxyl, amide, epoxide, ether, ester, urethane, urea, primary, secondary or tertiary amine and ether, and f) 0.1 to 5% by weight of a copolymerisable benzophenone or acetophenone derivative, the sum of the percentages by weight x = a + b + c + d + f in each case being 100.
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公开(公告)号:DE3828400A1
公开(公告)日:1990-03-08
申请号:DE3828400
申请日:1988-08-20
Applicant: BASF AG
Inventor: REHMER GERD DR
IPC: C08F265/04 , C09J4/02 , C09J4/06 , C09J201/00
Abstract: The invention relates to a process for the preparation of radiation-crosslinkable contact adhesive mixtures comprising polymers having a glass transition temperature of below 0 DEG C and a K value of from 20 to 80, derivatives of dihydroxypropyl (meth)acrylates as reactive thinners and small amounts of polymerisable tertiary amino compounds, in which the mixture is heated at temperatures of from 80 to 120 DEG C for up to 2 hours, and the solvent is then removed, if necessary at reduced pressure.
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公开(公告)号:DE3820464A1
公开(公告)日:1990-02-08
申请号:DE3820464
申请日:1988-06-16
Applicant: BASF AG
Inventor: REHMER GERD DR , BOETTCHER ANDREAS DR , PORTUGALL MICHAEL DR
IPC: C07C255/56 , C07C235/84 , C07C271/48 , C07C275/38 , C08F220/36 , C08F246/00 , C08F290/00 , C08F299/00 , C09D133/04 , C09D133/14 , C09D157/04 , C09D201/02 , C09J133/04 , C09J133/14 , C09J157/04 , C09J201/02
Abstract: This invention relates to UV-crosslinkable compositions based on (meth)acrylate copolymers which contain specific modified unsaturated benzophenone derivatives in copolymerised form, and to their use as hot-melt adhesives, for coating sheet-like mineral substrates and as paints.
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公开(公告)号:DE3732538A1
公开(公告)日:1989-04-06
申请号:DE3732538
申请日:1987-09-26
Applicant: BASF AG
Inventor: REHMER GERD DR , DRUSCHKE WOLFGANG DR
IPC: C08F2/14 , C08F257/02 , C09J7/02 , C09J151/00
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公开(公告)号:DE19701124A1
公开(公告)日:1997-08-07
申请号:DE19701124
申请日:1997-01-15
Applicant: BASF AG
Inventor: BLUM RAINER DR , BARWICH JUERGEN DR , FRICKE HANS-JOACHIM , REHMER GERD DR
IPC: C09J133/06 , C09J145/00 , C09J133/04 , C09J129/00 , C09J131/02 , C09J133/20 , C09J135/06 , C09J135/08
Abstract: Adhesive contains a free radical-polymerised polymer (I) with 0.5-90 wt.% units derived from (a) a monomer with dicyclopentadiene or dihydrodicyclopentadiene groups of formula (IIA) or (IIB); which is mono-substituted by R and optionally mono- or poly-substituted by R . R = an organic radical with a copolymerisable, ethylenically unsaturated group; R = a 1-12 carbon (C) alkyl or 5-20 C cycloalkyl, aryl or aralkyl group. Also claimed are a method of bonding substrates with the adhesive; and substrates coated with an adhesive, especially a pressure-sensitive adhesive or laminating adhesive of this type.
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公开(公告)号:DE59009177D1
公开(公告)日:1995-07-06
申请号:DE59009177
申请日:1990-08-14
Applicant: BASF AG
Inventor: REHMER GERD DR , AUCHTER GERHARD DR
IPC: C08F220/18 , C08F224/00 , C08F226/06 , C08F228/06 , C08F246/00 , C09D157/04 , C09J157/04
Abstract: The invention relates to copolymers built up from A) from 99.5 to 75 % of olefinically unsaturated monomers containing hetero atoms, B) from 0.5 to 25 % of unsaturated compounds of the formula I and C) from 0 to 20 % of further olefinically unsaturated monomers where X is O, S or NR and R is optionally substituted C2-C6-alkylene, and R is C1- to C8-alkyl or phenyl. The products according to the invention are suitable as coating and impregnation compositions and in particular as contact adhesives.
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公开(公告)号:ES2061887T3
公开(公告)日:1994-12-16
申请号:ES89120526
申请日:1989-11-06
Applicant: BASF AG
Inventor: HORN PETER DR , REHMER GERD DR , LUTTER HEINZ-DIETER DR , RAMLOW GERHARD DR , HINZ WERNER DR , SCHMIDT HANS ULRICH
IPC: C08F216/14 , C08F218/10 , C08F220/28 , C08F220/58 , C08F222/20 , C08F226/00 , C08F226/06 , C08F290/06 , C08F299/02 , C08G18/40 , C08G18/62 , C08L75/04
Abstract: The novel copolymers having K values of from 5 to 80 are prepared by free-radical polymerisation of A) 20 to 80% by weight, based on the total weight of (A) and (B), of at least one olefinically unsaturated polyoxyalkylene alcohol or polyester alcohol adduct, (B) 80 to 20% by weight, based on the total weight of (A) and (B), of at least one vinyl monomer from the group comprising N-vinylformamide, -2-pyrrolidone, -2-piperidone, -2-caprolactam, -imidazole, -2-ethyleneurea and -2-propyleneurea, C) 0.05 to 40 parts by weight of glycidyl acrylate and/or glycidyl methacrylate, D) 0 to 10 parts by weight of at least one alpha , beta -monoolefinically unsaturated acid and E) 0 to 30 parts by weight of at least one olefinically unsaturated carboxamide and/or carboxylate and/or styrene, the parts by weight of (C), (D) and (E) in each case being based on 100 parts by weight of the monomers (A) and (B). The copolymers are used as assistants and/or additives, for example as dispersion and/or emulsification assistants, or as additives for improving the mechanical properties, in formulations for the preparation of polyisocyanate polyaddition products.
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公开(公告)号:ES2061886T3
公开(公告)日:1994-12-16
申请号:ES89120525
申请日:1989-11-06
Applicant: BASF AG
Inventor: HORN PETER DR , REHMER GERD DR , LUTTER HEINZ-DIETER DR , RAMLOW GERHARD DR
IPC: C08F216/14 , C08F218/10 , C08F220/28 , C08F220/58 , C08F222/20 , C08F226/00 , C08F226/06 , C08F290/06 , C08F299/02 , C08G18/40 , C08G18/62 , C08L75/04 , C09K23/52
Abstract: The novel copolymers having K values of from 5 to 80 are prepared by free-radical polymerisation of A) 20 to 80% by weight, based on the total weight of (A) and (B), of at least one olefinically unsaturated polyoxyalkylene alcohol or polyester alcohol adduct, (B) 80 to 20% by weight, based on the total weight of (A) and (B), of at least one vinyl monomer from the group comprising N-vinylformamide, -2-pyrrolidone, -2-piperidone, -2-caprolactam, -imidazole, -2-ethyleneurea and -2-propyleneurea, C) 0 to 40 parts by weight of glycidyl acrylate and/or glycidyl methacrylate, D) 0 to 10 parts by weight of at least one alpha , beta -monoolefinically unsaturated acid and E) 0 to 30 parts by weight of at least one olefinically unsaturated carboxamide and/or carboxylate and/or styrene, the parts by weight of (C), (D) and (E) in each case being based on 100 parts by weight of the monomers (A) and (B). The copolymers are used as assistants and/or additives, for example as dispersion and/or emulsification assistants, or as additives for improving the mechanical properties, in formulations for the preparation of polyisocyanate polyaddition products.
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