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公开(公告)号：WO2017021139A1
公开(公告)日：2017-02-09
申请号：PCT/EP2016/067145
申请日：2016-07-19
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： MASSARI, Paola , CATHELIN, Caroline , CAVALIERI, Claudio , CIARAFONI, Marco , FELISATI, Andrea , FERRARO, Angelo , MORINI, Giampiero , PIEMONTESI, Fabrizio , VITALE, Gianni
CPC classification number: B32B27/32 , B32B7/04 , B32B27/08 , B32B27/18 , B32B2307/548 , C08F210/06 , C08F210/16 , C08F2500/04 , C08F2500/12 , C08F2500/26 , C08F2800/20 , C08J5/18 , C08J2323/14 , C08J2423/14 , C08L23/14 , C08L23/142 , C08L2201/10 , C08L2203/162 , C08L2205/025 , C08L2308/00 , C08F210/08 , C08F2/001 , C08F4/6492
Abstract: A polyolefin composition comprising: A) from 19 wt% to 50 wt% of a propylene ethylene copolymer having an ethylene derived units content ranging from 1.5 wt% to 6.0 wt% B) from 50 wt% to 81 wt% of a propylene ethylene 1-butene terpolymer having an ethylene derived units content ranging from 1.5 wt% and 6.0 wt% and 1-butene derived units content of between 4.8 wt% and 12.4 wt%; the sum of the amount of component A) and B) being 100.
Abstract translation: 一种聚烯烃组合物，其包含：A）19重量％至50重量％的乙烯衍生单元含量范围为1.5重量％至6.0重量％的丙烯乙烯共聚物B）50重量％至81重量％的丙烯乙烯1 乙烯衍生单元含量为1.5重量％至6.0重量％，1-丁烯衍生单元含量为4.8重量％至12.4重量％的丁烯三元共聚物; 组分A）和B）的量的总和为100。
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82.发明申请
公开(公告)号：WO2017021137A1
公开(公告)日：2017-02-09
申请号：PCT/EP2016/067143
申请日：2016-07-19
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： MASSARI, Paola , CATHELIN, Caroline , CAVALIERI, Claudio , CIARAFONI, Marco , FELISATI, Andrea , FERRARO, Angelo , MORINI, Giampiero , PIEMONTESI, Fabrizio , VITALE, Gianni
CPC classification number: C08L23/14 , B32B27/08 , B32B27/32 , B32B2307/412 , B32B2307/414 , B32B2307/548 , B32B2307/732 , B32B2307/75 , C08L23/142 , C08L2201/10 , C08L2203/162 , C08L2205/025 , C08L2308/00 , C08F210/06 , C08F2/001 , C08F4/6492 , C08F4/6574
Abstract: A polyolefin composition comprising: A) from 19 wt% to 50 wt% of a propylene ethylene copolymer having an ethylene derived units content ranging from 1.5 wt% to 6.0 wt% B) from 50 wt% to 81 wt% of a propylene ethylene 1-butene terpolymer having an ethylene derived units content ranging from 1.5 wt% and 6.0 wt% and 1-butene derived units content of between 4.8 wt% and 12.4 wt%; the sum of the amount of component A) and B) being 100; the composition being characterized by the following features: molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than 4.0; the creep and recovery curve measured on the polymer fuse at 200°C measured according to the procedure reported in the characterizing section shows a maximum value between 600 and 1200 seconds lower than 53x10 -5 1/Pa.
Abstract translation: 一种聚烯烃组合物，其包含：A）19重量％至50重量％的乙烯衍生单元含量范围为1.5重量％至6.0重量％的丙烯乙烯共聚物B）50重量％至81重量％的丙烯乙烯1 乙烯衍生单元含量为1.5重量％至6.0重量％，1-丁烯衍生单元含量为4.8重量％至12.4重量％的丁烯三元共聚物; 组分A）和B）的量的总和为100; 该组合物的特征在于以下特征：以Mw / Mn表示的分子量分布（MWD）大于4.0; 在根据表征部分中报道的程序测量的在200℃下聚合物保险丝上测量的蠕变和恢复曲线显示比53×10-51 / Pa低600至1200秒的最大值。
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公开(公告)号：WO2016142377A1
公开(公告)日：2016-09-15
申请号：PCT/EP2016/054903
申请日：2016-03-08
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： CHEVALIER, Reynald , MIGNOGNA, Alessandro , MORINI, Giampiero
CPC classification number: C08F110/06 , C07F7/28 , C08F2500/12 , C08F2500/15 , C08F4/651
Abstract: A solid catalyst component which exhibits high activity and stereo specificity polymerization of olefins comprising Mg, Ti and an electron donor of formula (I) where R and R 1 are selected from C 1 -C 20 hydrocarbon groups C 6 -C 14 aryl or alkylaryl groups hydrocarbon groups, optionally containing a heteroatom selected from halogen, P, S, N,O; R 2 to R 11 groups, equal to or different from each other, are hydrogen, halogen or C 1 -C 15 hydrocarbon groups which can be optionally fused together to form one or more cycles with the proviso that R 6 and R 11 cannot join together to form a phenyl ring.
Abstract translation: 显示出具有式（I）的Mg，Ti和电子给体的烯烃的高活性和立体特异性聚合的固体催化剂组分，其中R和R 1选自C 1 -C 20烃基C 6 -C 14芳基或烷基芳基烃基，任选地 含有选自卤素，P，S，N，O的杂原子; R 2至R 11基团彼此相同或不同，为氢，卤素或C 1 -C 15烃基，其可以任选地稠合在一起形成一个或多个循环，条件是R 6和R 11不能连接在一起形成苯环 。
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公开(公告)号：WO2016142334A1
公开(公告)日：2016-09-15
申请号：PCT/EP2016/054772
申请日：2016-03-07
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： MIGNOGNA, Alessandro , MORINI, Giampiero , CHEVALIER, Reynald
CPC classification number: C08F110/06 , C08F4/6455 , C08F4/6457 , C08F4/649 , C08F4/6495 , C08F4/6498 , C08F2410/01 , C08F4/651 , C08F2500/12 , C08F2500/15 , C08F4/6543
Abstract: A solid catalyst component for the polymerization of olefins comprising Mg, Ti, halogen and an electron donor of formula (I) or (II). When activated with an aluminum alkyl and optionally an external electron donor is capable to give high activity and stereospecificity in the polymerization of olefins.
Abstract translation: 包含Mg，Ti，卤素和式（I）或（II）的电子给体的烯烃聚合的固体催化剂组分。 当用烷基铝和任选的外部电子给体活化时，能够在烯烃聚合中产生高活性和立体定向性。
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公开(公告)号：WO2016050662A1
公开(公告)日：2016-04-07
申请号：PCT/EP2015/072200
申请日：2015-09-28
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： GUIDOTTI, Simona , LIGUORI, Dario , MORINI, Giampiero
CPC classification number: C08F10/06 , C08F110/06 , C08F4/025 , C08F4/6574 , C08F2500/15
Abstract: A catalyst component comprising Ti, Mg, CI, and an electron donor compound having porosity of at least 0.2 cm 3 /g and characterized by the fact that it further comprises Cu oxide, with the proviso that when the electron donor compound is selected from esters of phthalic acids, the porosity is of at least 0.45 cm 3 /g.
Abstract translation: 包含Ti，Mg，Cl和具有至少0.2cm 3 / g的孔隙率的电子给体化合物的催化剂组分，其特征在于它还包含Cu氧化物，条件是当电子给体化合物选自 邻苯二甲酸，孔隙率至少为0.45cm 3 / g。
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Patent Agency Ranking86.发明申请
公开(公告)号：WO2015169831A1
公开(公告)日：2015-11-12
申请号：PCT/EP2015/059919
申请日：2015-05-06
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： PIEMONTESI, Fabrizio , CATHELIN, Caroline , GUIDOTTI, Simona , LIGUORI, Dario , MORINI, Giampiero , TARTARI, Davide , VITALE, Gianni
IPC: C08F110/06 , C08F210/06 , C08F4/657
CPC classification number: C08F210/06 , C08F210/16 , C08F2500/04 , C08F2500/12 , C08F2500/26 , C08F4/6574
Abstract: Propylene-ethylene copolymers showing an ethylene content of between 0.1 and 10% by weight, a molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than 3.0 and a content of xylene soluble fraction (XS) and ethylene content (C2) such that the point defined by said values falls below the line given by the equation XS= 1.0296 . e 0.435C2 show high transparency and low melting temperature.
Abstract translation: 丙烯 - 乙烯共聚物，其乙烯含量为0.1〜10重量％，分子量分布（MWD）以Mw / Mn表示，大于3.0，二甲苯可溶成分（XS）含量和乙烯含量（ C2），使得由所述值定义的点落在由等式XS = 1.0296.e0.435C2给出的线下方显示高透明度和低熔融温度。
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公开(公告)号：WO2015144668A1
公开(公告)日：2015-10-01
申请号：PCT/EP2015/056198
申请日：2015-03-24
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： MIGNOGNA, Alessandro , MORINI, Giampiero
CPC classification number: C08F4/6425 , C07C271/44 , C08F4/022 , C08F4/65912 , C08F10/14 , C08F110/06 , C08F2500/15 , C08L57/00 , C08L2207/10 , C08L2314/02 , C08F4/651 , C08F2500/12
Abstract: A solid catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of formula (I), where each Q is a group –COOR 1 in which R 1 is selected from C 1 -C 15 hydrocarbon groups, optionally containing a heteroatom selected from halogen, P, S, N,O; or a group –CON(R 2 ) 2 in which R 2 groups, equal to or different from each other, are hydrogen or R 1 groups which can be fused together to form one or more cycles, and A is a bivalent bridging group with the proviso that Q groups cannot be simultaneously a group – COOR 1 or –CON(R 2 ) 2 .
Abstract translation: 用于烯烃聚合的固体催化剂组分，包括Mg，Ti和式（I）的电子给体，其中每个Q是-COOR 1基团，其中R 1选自C 1 -C 15烃基，任选地含有选自卤素 ，P，S，N，O; 或其中R2基彼此相同或不同的基团-CON（R 2）2是氢或可以稠合在一起形成一个或多个循环的R 1基团，A是二价桥连基团，条件是 Q组不能同时为COOR1或-CON（R2）2。
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公开(公告)号：WO2015135903A1
公开(公告)日：2015-09-17
申请号：PCT/EP2015/054900
申请日：2015-03-10
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： GUIDOTTI, Simona , DALL'OCCO, Tiziano , LIGUORI, Dario , MORINI, Giampiero , PIEMONTESI, Fabrizio , VITALE, Gianni
IPC: C08F110/02 , C08F110/06 , C08F210/06 , C08F4/657 , C08F4/02 , C08F4/651
CPC classification number: C08F4/64 , C08F4/12 , C08F10/02 , C08F10/06 , C08F4/6545 , C08F4/6465 , C08F4/6574 , C08F110/06 , C08F2500/04 , C08F210/06 , C08F210/16 , C08F2500/12 , C08F4/022 , C08F4/651 , C08F110/02
Abstract: A solid catalyst component for the (co)polymerization of olefins CH 2 =CHR, in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising Ti, Mg, and Cl, and optionally an electron donor compound selected from the group consisting of ethers, amines, silanes, carbamates ketones, esters of aliphatic acids, alkyl and aryl esters of optionally substituted aromatic polycarboxylic acids, diol derivatives chosen among monoesters monocarbamates and monoesters monocarbonates or mixtures thereof characterized by the fact that it contains from 0.1 to 50%wt of Bi with respect to the total weight of said solid catalyst component.
Abstract translation: 用于烯烃CH 2 = CHR（其中R是氢或具有1-12个碳原子的烃基）的（共）聚合的固体催化剂组分，包含Ti，Mg和Cl，以及任选的电子给体化合物，其选自 由醚，胺，硅烷，氨基甲酸酯酮，脂肪酸的酯，任选取代的芳族多元羧酸的烷基和芳基酯，选自单酯单乳酸单酯和单酯单碳酸酯的二醇衍生物或其混合物，其特征在于其含有0.1至50 Bi的％wt相对于所述固体催化剂组分的总重量。
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公开(公告)号：WO2014184171A1
公开(公告)日：2014-11-20
申请号：PCT/EP2014/059717
申请日：2014-05-13
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： MIGNOGNA, Alessandro , CHEVALIER, Reynald , GUIDOTTI, Simona , LIGUORI, Dario , MORINI, Giampiero , SCHNEIDER, Martin
CPC classification number: C08F110/06 , C07C271/44 , C07C2601/14 , C07C2602/08 , C08F4/6545 , C08F4/6543 , C08F4/651 , C08F2500/12 , C08F2500/15
Abstract: A solid catalyst component for the polymerization of olefins comprising Mg, Ti, Cl and at least an electron donor compound which is the reaction product obtained by bringing into contact a Mg compound and a Ti compound having at least a Ti-halogen bond with an electron donor selected from specific diphenol derivatives.
Abstract translation: 一种用于烯烃聚合的固体催化剂组分，包括Mg，Ti，Cl和至少一种电子给体化合物，它是通过与Mg化合物和至少具有Ti-卤素键的电子与电子接触而获得的反应产物 供体选自具体的二酚衍生物。
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公开(公告)号：WO2014161905A1
公开(公告)日：2014-10-09
申请号：PCT/EP2014/056625
申请日：2014-04-02
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor： GUIDOTTI, Simona , LIGUORI, Dario , MORINI, Giampiero , PIEMONTESI, Fabrizio
CPC classification number: C08F10/06 , C08F4/6421 , C08F4/6574 , C08F110/06 , C08F2410/01 , C08F2500/15
Abstract: A solid catalyst component for the (co)polymerization of olefins CH 2 =CHR, in which R is a hydrocarbyl radical with 1-12 carbon atoms, optionally in mixture with ethylene, comprising Ti, Mg, Cu, CI, and an electron donor compound characterized by the fact that the Cu/Ti weight ratio is lower than 0.5.
Abstract translation: 用于烯烃CH 2 = CHR（其中R是具有1-12个碳原子的烃基，任选与乙烯混合）的固体催化剂组分，其包含Ti，Mg，Cu，Cl和电子给体化合物 其特征在于Cu / Ti重量比低于0.5。
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