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    81.
    发明专利
    未知

    公开(公告)号：DE59503268D1

    公开(公告)日：1998-09-24

    申请号：DE59503268

    申请日：1995-03-06

    Applicant: BASF AG

    Inventor： KNEUPER HEINZ-JOSEF ,  ARON MAIK ,  KORGITZSCH FRANK-MICHAEL ,  NILLES MICHAEL ,  HARDER WOLFGANG ,  ROEPER MICHAEL ,  PACIELLO ROCCO

    IPC: B01J31/40 ,  C07B61/00 ,  C07C27/22 ,  C07C29/141 ,  B01J23/46 ,  C07C29/16 ,  C07C31/02 ,  C07C45/50 ,  C07C45/80 ,  C07C47/02 ,  C07C51/235 ,  C07C209/00

    Abstract: PCT No. PCT/EP95/00825 Sec. 371 Date Sep. 13, 1996 Sec. 102(e) Date Sep. 13, 1996 PCT Filed Mar. 6, 1995 PCT Pub. No. WO95/25080 PCT Pub. Date Sep. 21, 1995An industrial preparation of aldehydes and/or alcohols from olefins of more than 3 carbon atoms by a catalytic hydroformylation of the olefin reactant at a pressure of from 50 to 1000 bar and a temperature of from 50 to 180 DEG C. in the presence of an uncomplexed rhodium catalyst homogeneously dissolved in the reaction medium. The catalytic activity of the rhodium is maintained, first by extracting it from the initially discharged reaction mixture by means of an aqueous solution of a nitrogen-containing complexing agent such as sulfonated or carboxylated pyridines, quinolines or the like. In a recycle of the complexed rhodium to be reused in the hydroformylation reaction, the aqueous rhodium-containing extract is fed to a precarbonylation stage where it subjected to a required precarbonylation in the presence of an essentially water-insoluble organic liquid and in the presence of carbon monoxide, synthesis gas or another gas mixture containing carbon monoxide at from 50 to 1000 bar and from 50 to 180 DEG C. The mixture discharged from this precarbonylation stage is then separated into an organic phase containing the main part of the rhodium and an aqueous phase containing the complexing agent. The resulting rhodium-containing organic phase with the regenerated catalyst is then fed into the hydroformylation stage to complete its recycle.

    MANUFACTURING PROCESS FOR 6-AMINOCAPRONITRILE
    83.
    发明专利
    MANUFACTURING PROCESS FOR 6-AMINOCAPRONITRILE 未知

    公开(公告)号：CA2259941A1

    公开(公告)日：1998-02-12

    申请号：CA2259941

    申请日：1997-07-23

    Applicant: BASF AG

    Inventor： SCHNURR WERNER ,  PACIELLO ROCCO ,  R PER MICHAEL ,  FISCHER ROLF

    IPC: C07C253/30 ,  C07C255/24

    Abstract: Manufacture of 6-aminocapronitrile or 6-aminocapronitrile/hexamethylene diamine mixtures, involving a) the reaction of at least one pentennitrile, selected from the group consisting of 2,3 and 4-pentennitrile with carbon monoxide and hydrogen in the presence of catalysts, which contain at least one element of the eighth subgroup as active components, obtaining a hydrogenation formylating discharge (I), b) the optional separation of carbon monoxide, hydrogen and the catalyst from the hydrogenation formylating discharge (I), obtaining a hydrogenation formylating discharge (II), c) the separation of 5formyl valeronitrile from the hydrogenation formylating discharge (I) or (II), d) the reaction of separated 5-formyl valeronitrile with ammonia and hydrogen in the presence of hydrogenating catalysts, selected from the group consisting of rhenium, copper and its compounds as well as metals and metallic compounds of the eighth group, obtaining a hydrogenation discharge, and e) obtaining 6aminocapronitrile and if necessary hexamethylene diamine.

    84.
    发明专利
    未知

    公开(公告)号：BR9508689A

    公开(公告)日：1997-12-30

    申请号：BR9508689

    申请日：1995-08-24

    Applicant: BASF AG

    Inventor： KANAND JUERGEN ,  ROEPER MICHAEL ,  PACIELLO ROCCO ,  THOME ALFRED

    IPC: C07C27/00 ,  C07B61/00 ,  C07C29/00 ,  C07C29/09 ,  C07C29/17 ,  C07C31/12 ,  C07C45/51 ,  C07C45/56 ,  C07C47/02 ,  C07D295/023

    Abstract: PCT No. PCT/EP95/03358 Sec. 371 Date Jul. 23, 1997 Sec. 102(e) Date Jul. 23, 1997 PCT Filed Aug. 24, 1995 PCT Pub. No. WO96/07630 PCT Pub. Date Mar. 14, 1996A process for the preparation of n-butyraldehyde and/or n-butanol, in which a) 1,3-butadiene is caused to react with an amine of the formula I R1R2NH, I in which R1 and R2 independently denote hydrogen, optionally substituted aliphatic or cycloaliphatic radicals, or aryl or aralkyl radicals or are linked to form a bridging member which can contain hetero atoms, at elevated temperature and under superatmospheric pressure in the presence of a compound of a Group VIIIb element and in the presence of an alkali metal amide or a basic metal oxide to form a mixture of the adducts of the formulas II II and III III b) the adduct III is isomerized to the adduct II, c) the adduct II is isomerized in the presence of a homogeneous or heterogeneous transition metal element catalyst in the liquid phase or in the presence of a heterogeneous catalyst containing a transition metal element in the gaseous phase to form the enamine of the formula IV IV and d) n-butyraldehyde and/or n-butanol is/are produced from this enamine.

    85.
    发明专利
    未知

    公开(公告)号：DE4431528A1

    公开(公告)日：1996-03-07

    申请号：DE4431528

    申请日：1994-09-03

    Applicant: BASF AG

    Inventor： KANAND JUERGEN ,  ROEPER MICHAEL ,  PACIELLO ROCCO ,  THOME ALFRED

    IPC: C07C27/00 ,  C07B61/00 ,  C07C29/00 ,  C07C29/09 ,  C07C29/17 ,  C07C31/12 ,  C07C45/51 ,  C07C45/56 ,  C07C47/02 ,  C07D295/023 ,  C07C45/00 ,  C07D295/03

    Abstract: The proposed process for producing n-butyraldehyde and/or n-butanol involves the following steps: (a) 1,3-butadiene is allowed to react with an amine of formula (I) R R NH, in which the groups independently of one another represent hydrogen, optionally substituted aliphatic or cyclo-aliphatic groups, or aryl or aralkyl groups, or are connected to a bridging unit which can contain heteroatoms, at high temperature and pressure and in the presence of a compound of a group VIIIb element, in the presence of an alkali metal amide, or in the presence of a basic metal oxide, to form a mixture of addition compounds of formula (II) and (III); (b) addition compound (III) is isomerised to addition compound (II); (c) addition compound (II) is isomerised in the presence of a homogeneous or heterogeneous transition metal catalyst in liquid phase or in the presence of a heterogeneous catalyst containing transition metal in the gas phase to produce enamine of formula (IV); and (d) the enamine (IV) is converted, by reaction with hydrogen and water, or water, in the presence of a homogeneous or heterogeneous transition metal catalyst in liquid phase, in the presence of a heterogenous catalyst containing transition metal in the gas phase, in the presence of an acid or in the presence of one of the above mentioned catalysts and of an acid, to n-butyraldehyde and/or n-butanol, the amine (I) being released and the released amine (I) being led back into sub-reaction (a).

    PROCESS FOR PRODUCING N- BUTYRALDEHYDE AND / OR N- BUTANOL
    87.
    发明专利
    PROCESS FOR PRODUCING N- BUTYRALDEHYDE AND / OR N- BUTANOL 未知

    公开(公告)号：MY123728A

    公开(公告)日：2006-05-31

    申请号：MYPI9600134

    申请日：1996-01-13

    Applicant: BASF AG

    Inventor： THOME ALFRED ,  KANAND JURGEN ,  ROPER MICHAEL ,  PACIELLO ROCCO

    IPC: C07C29/00

    Abstract: A PROCESS FOR PREPARATION OF N-BUTYRALDEHYDE AND/OR N-BUTANOL, IN WHICH A) 1,3-BUTADIENE IS CAUSED TO REACT WITH AN AMINE OF THE FORMULA &Igr;, IN WHICH R¹ AND R² INDEPENDENTLY DENOTE HYDROGEN, OPTIONALLY SUBSTITUTED ALIPHATIC OR CYCLOALIPHATIC RADICALS, OR ARYL OR ARALKYL RADICALS OR ARE LINKED TO FORM A BRIDGING MEMBER CONTAINING THE HETERO ATOM, AT ELEVATED TEMPERATURE AND UNDER SUPERATMOSPHERIC PRESSURE IN THE PRESENCE OF A COMPOUND OF A GROUP V&Igr;&Igr;&Igr;B ELEMENT AND IN THE PRESENCE OF AN ALKALI METAL AMIDE OR A BASIC METAL OXIDE TO FORM A MIXTURE OF THE ADDUCTS OF THE FORMULA &Igr;&Igr; (FORMULA &Igr;&Igr;, &Igr;&Igr;&Igr;)B) THE ADDUCT &Igr;&Igr;&Igr; IS ISOMERIZED TO THE ADDUCT &Igr;&Igr;,C) THE ADDUCT &Igr;&Igr; IS ISOMERIZED IN THE PRESENCE OF A HOMOGENEOUS OR HETEROGENEOUS TRANSITION METAL ELEMENT CATALYST IN THE LIQUID PHASE OR IN THE PRESENCE OF A HETEROGENEOUS CATALYST CONTAINING A TRANSITION METAL ELEMENT IN THE GASEOUS PHASE TO FORM THE ENAMINE OF THE FORMULA &Igr;V(FORMULA &Igr;V)AND D) N-BUTYRALDEHYDE AND/OR N-BUTANOL IS/ARE PRODUCED FROM THIS ENAMINE &Igr;V BY THE REACTION THEREOF WITH HYDROGEN AND WATER ONLY IN THE PRESENCE OF A HOMOGENEOUS OR HETEROGENEOUS TRANSITION METAL ELEMENT CATALYST IN THE LIQUID PHASE OR IN THE PRESENCE OF A HETEROGENOUS TRANSITION METAL ELEMENT CATALYST IN THE GASEOUS PHASE AND IN THE PRESENCE OF AN ACID OR IN PRESENCE OF ONE OF SAID CATALYST AND AN ACID, AND THE AMINE &Igr; IS LIBERATED, AND THE LIBERATED AMINE &Igr; IS RECYCLED TO THE STAGE DEFINED ABOVE AS PARTIAL REACTION A).

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