公开(公告)号：DE10002089A1

公开(公告)日：2001-07-26

申请号：DE10002089

申请日：2000-01-19

Applicant: BASF AG

Inventor： SCHWALM REINHOLD ,  VOELLINGER FRANK ,  MENZEL KLAUS ,  REICH WOLFGANG ,  BECK ERICH ,  JAWOREK THOMAS

IPC: C08F2/46 ,  C08F2/50 ,  C08G18/08 ,  C08G18/32 ,  C08G18/67 ,  C08G18/79 ,  C09D175/16

Abstract: A water dispersible, radiation curable polyurethane comprises organic aliphatic or alicyclic polyisocyanates, cycloaliphatic diols and/or cycloaliphatic diamines, compounds having at least one isocyanate reactive group and at least one radically polymerizable unsaturated group and compounds having at least one isocyanate reactive group and at least one dispersion aiding group. A water dispersible, radiation curable polyurethane (I) comprises: (A) organic aliphatic or alicyclic polyisocyanates; (B) cycloaliphatic diols and/or cycloaliphatic diamines; (C) compounds having at least one isocyanate reactive group and at least one radically polymerizable unsaturated group; (D) compounds having at least one isocyanate reactive group and at least one dispersion aiding group; (E) optionally compounds having at least two isocyanate reactive groups having a mol. wt. of less than 1000 g/mol; (F) optionally compounds having at least one isocyanate reactive group that are different to (A)-(D). Independent claims are included for: (i) a polyurethane dispersion (II) comprising the polyurethane (I) and optionally 0-10 wt.% of a photochemical and/or thermal initiator and 0-10 wt.% of a UV absorber and a HALS compound; (ii) a process for the coating of substrates by application of the polyurethane dispersion (II), optionally containing conventional paint additives, onto a substrate and curing by means of electron irradiation or UV light under oxygen, or preferably under inert gas; (iii) the resulting coated substrate.

公开(公告)号：DE59606624D1

公开(公告)日：2001-04-26

申请号：DE59606624

申请日：1996-11-20

Applicant: BASF AG

Inventor： HAEUSSLING LUKAS ,  BERNHARD LUDWIG ,  REICH WOLFGANG ,  SCHWALM REINHOLD ,  BECK ERICH ,  HARTMANN GABRIELE

IPC: C08F2/46 ,  C08F2/54 ,  C08F10/14 ,  C08F20/10 ,  C08F210/14 ,  C08F290/00 ,  C08F290/06 ,  C09D4/02

Abstract: A radiation-hardenable compsn. based on radiation-hardenable radically-polymerisable cpds. contains alpha -olefins with more than 8 C.

公开(公告)号：DE19947054A1

公开(公告)日：2001-04-05

申请号：DE19947054

申请日：1999-09-30

Applicant: BASF AG

Inventor： SCHWALM REINHOLD ,  PAULUS WOLFGANG ,  MEISENBURG UWE ,  BECK ERICH ,  BRUCHMANN BERND ,  SCHROF WOLFGANG

IPC: C08G18/08 ,  C08G18/78 ,  C08G18/80 ,  C09D175/16 ,  C08G18/67 ,  C09D175/14

Abstract: UV- and heat-curable aqueous polyurethane dispersion based on aliphatic polyisocyanates and low-mol. wt. aliphatic compounds with at least 2 hydroxyl, mercapto or amino groups also contains compounds with NCO-reactive groups and UV-polymerizable double bonds, carboxylic or sulfonic acids with NCO-reactive groups and an isocyanate blocking agent. UV- and heat-curable aqueous polyurethane dispersions (PD), essentially comprising: (a) aliphatic polyisocyanates with an NCO functionality of 2-4.5, (b) compounds with isocyanate-reactive group(s) and C=C double bond(s) which can be polymerized with UV in presence of a photoinitiator, (c) aliphatic compounds with a mol. wt. of less than 500 and at least 2 isocyanate-reactive hydroxyl, mercapto or prim. and/or sec. amino groups, (d) compounds with isocyanate-reactive group(s) and carboxylic or sulfonic acid group(s), (e) a basic compound for at least partial neutralization of the acid groups in (d), (f) an isocyanate blocking agent (f1) with a deblocking temperature of 70-160 deg C or an added low-mol. wt. compound (f2) with blocked isocyanate groups, and (g) optionally compounds other than (b-f) with only one isocyanate-reactive group. Dispersions (PD) are obtained by reacting (a) with (b) and (c) using a stoichiometric excess of NCO groups over OH groups and with sufficient (d) and (e) for good dispersibility in aqueous media, and then introducing blocked isocyanate groups by reaction with (f1) or by addition of (f2) containing (b) as additive.

公开(公告)号：AT199243T

公开(公告)日：2001-03-15

申请号：AT96118091

申请日：1996-11-12

Applicant: BASF AG

Inventor： HAEUSSLING LUKAS ,  BERNHARD LUDWIG ,  REICH WOLFGANG ,  SCHWALM REINHOLD ,  BECK ERICH

IPC: C07C67/08 ,  C07C67/62 ,  C07C69/54 ,  C08G65/332 ,  C09D4/02

Abstract: A process for the production of (meth)acrylate esters (I) by esterification of (meth)acrylic acid (II) with mono- or poly- hydric alcohols (III) is claimed. The reaction mixture, still containing (II) in amounts equivalent to an acid number of at least 5 mg KOH/g, is treated with amino compound(s) (IV) containing at least one prim., sec. or tert. amino group. Also claimed are: (1) esters (I) obtained by this process; and (2) radiation-curable materials (RCM) containing (I).

公开(公告)号：DE19940313A1

公开(公告)日：2001-03-01

申请号：DE19940313

申请日：1999-08-25

Applicant: BASF AG

Inventor： JAWOREK THOMAS ,  SCHWALM REINHOLD

IPC: B05D3/04 ,  B05D3/06 ,  C08F2/46 ,  C08F2/48 ,  C09D4/00 ,  C09D4/06 ,  C09D175/16 ,  B05D7/26 ,  B05D7/16 ,  B05D5/00

Abstract: The invention relates to a method for producing scratch resistant coatings. A UV hardenable coating agent contains at least one aliphatic urethane(meth)acrylate prepolymer PU with at least two double bonds per molecule or a mixture of at least one urethane(meth)acrylate prepolymer PU and at least one reactive diluent, said contents being the photochemically cross-linkable component. At least one of said coating agents is applied to the substrate to be coated. The humid coating thus obtained is hardened in an inert gas atmosphere under the influence of ultraviolet radiation.

公开(公告)号：DE19860049A1

公开(公告)日：2000-06-29

申请号：DE19860049

申请日：1998-12-23

Applicant: BASF AG

Inventor： SCHWALM REINHOLD ,  BRUCHMANN BERND ,  BECK ERICH

IPC: B05D7/24 ,  C08F290/06 ,  C08G18/67 ,  C08G18/75 ,  C08G18/79 ,  C08G18/81 ,  C08K5/103 ,  C09D4/00 ,  C09D5/00 ,  C09D175/04 ,  C09D175/14 ,  C09D175/16 ,  C08G18/10 ,  C08G18/78 ,  C08G18/32 ,  C08L75/16

Abstract: The invention relates to a hardenable preparation containing a prepolymer and the following incorporated by polymerisation: (a) an isocyanate which is at least bifunctional on average and is based on a compound of formula (I), wherein R and R , independently of each other, represent C1-12-alkylene; (b) an ethylenically unsaturated compound containing isocyanate reactive groups and (c) optionally, a saturated compound containing isocyanate reactive groups.

公开(公告)号：DE19851139A1

公开(公告)日：2000-05-11

申请号：DE19851139

申请日：1998-11-05

Applicant: BASF AG

Inventor： SCHROF WOLFGANG ,  SCHWALM REINHOLD ,  BECK ERICH ,  MEISENBURG UWE

IPC: B05B5/025 ,  B05C9/14 ,  B05D3/06 ,  B05D5/06 ,  B05D7/24 ,  C08F2/48 ,  B05D3/00

Abstract: A crosslinking reaction is initiated in a reactive paint formulation. This is coated-onto a surface at least locally, before reaction is completed. Independent claims are included for equipment carrying out the process, and for the coating so produced. The equipment employs a sprayer and/or electrostatic applicator with bell housing. Preferred features: Initiation of reaction preferably employs UV illumination (1), in conjunction with at least one photoinitiator in the formulation. Kinetics of the reaction are controlled by temperature variation, and/or by use of a sufficiently slowly-running reaction, especially a cationic polymerization, and/or by spatial separation of photoinitiator(s) from the formulation components and/or by minimizing reactivity of the photoinitiator(s). Spatial separation cited, is by nano-structuring of the paint formulation. Further stages include mixing a UV protection agent and/or pigment into the formulation before coating. A hand spray gun (6) applies the paint. In the equipment, optical fibers (3, 4) transmit UV light to the paint formulation.

公开(公告)号：AT190328T

公开(公告)日：2000-03-15

申请号：AT95114706

申请日：1995-09-19

Applicant: BASF AG

Inventor： HAEUSSLING LUKAS ,  JAEGER ULRICH ,  REICH WOLFGANG ,  BECK ERICH ,  LEBKUECHER WERNER ,  SCHWALM REINHOLD

IPC: C08G18/66 ,  C08G18/08 ,  C08G18/12 ,  C08G18/42 ,  C08G18/65 ,  C08G18/67 ,  C09D175/16

公开(公告)号：DE59701008D1

公开(公告)日：2000-02-17

申请号：DE59701008

申请日：1997-04-04

Applicant: BASF AG

Inventor： REICH WOLFGANG ,  SCHWALM REINHOLD ,  HAEUSSLING LUKAS ,  NUYKEN OSKAR ,  RAETHER ROMAN-BENEDIKT

IPC: G03F7/039 ,  C08G65/06 ,  C08G65/16 ,  C08G65/22 ,  C09D5/25 ,  G03C9/08 ,  G03F7/004 ,  G03F7/027

Abstract: PCT No. PCT/EP97/01689 Sec. 371 Date Jul. 13, 1998 Sec. 102(e) Date Jul. 13, 1998 PCT Filed Apr. 4, 1997 PCT Pub. No. WO97/39047 PCT Pub. Date Oct. 23, 1997Polymers are obtainable by polymerising or copolymerising 2,7-dioxabicyclo[3.2.1]octane derivatives of the formula in which X, X', Y, Y', Z and Z' each independently are a C1-C2 hydrocarbon radical or hydrogen.

公开(公告)号：DE59603969D1

公开(公告)日：2000-01-27

申请号：DE59603969

申请日：1996-09-16

Applicant: BASF AG

Inventor： SCHWALM REINHOLD ,  REICH WOLFGANG ,  HAEUSSLING LUKAS ,  BECK ERICH

IPC: C08F2/48 ,  C08F2/44 ,  C08F2/46 ,  C08F2/50 ,  C08F8/30 ,  C08F8/32 ,  C08F20/10 ,  C08F290/06 ,  C08G73/00 ,  C09D4/00 ,  C09D4/02

Abstract: Radiation-curable compsns. (I), contg. (a) radiation-curable, radically-polymerisable cpds. and (b) capped amino cpds. which are surface-active in cpds. (a) and which release amino cpds. with free prim. and/or sec. amino gps. when irradiated with high-energy light, the total no. of H atoms contained in amino gps. being at least 2. Also claimed is (i) a process for the prodn. of (I) by adding cpds. (b) to cpds. (a); (ii) a process for the prodn. of coatings or mouldings by irradiating (I) with high-energy light; (iii) moulded prods. or coatings obtd. by this process.