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公开(公告)号:AT454387T
公开(公告)日:2010-01-15
申请号:AT07787520
申请日:2007-07-13
Applicant: BASF SE
Inventor: SCHUBERT MARKUS , OEZKIRIM FARUK , KIENER CHRISTOPH , MUELLER ULRICH , TONIGOLD MARKUS
IPC: C07F1/00
Abstract: The present invention relates to a process for preparing a porous metal organic framework comprising a first and at least one second at least bidentate organic compound coordinated to at least one copper ion, which comprises the steps (a) reaction of a reaction mixture in the liquid phase comprising at least one copper compound and the first at least bidentate organic compound to form an intermediate complex comprising the at least one copper ion and the first at least bidentate organic compound, with the first at least bidentate organic compound being derived from a dicarboxylic acid and having a skeleton which is a hydrocarbon, and (b) reaction of the intermediate complex with the at least second at least bidentate organic compound, with the at least second at least bidentate organic compound being an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons have been replaced by heteroatoms selected from the group consisting of N, O and S, wherein the reaction mixture in step (a) comprises less than a 3-fold excess of formic acid based on the copper of the copper compound used.
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公开(公告)号:ZA200806381B
公开(公告)日:2009-12-30
申请号:ZA200806381
申请日:2008-07-23
Applicant: DOW CHEMICAL CO , BASF SE
Inventor: GOEBBEL HANS-GEORG , BASSLER PETER , TELES JOAQUIM HENRIQUE , RUDOLF PETER , MUELLER ULRICH , FORLIN ANNA , SCHULZ MALTE , WEIDENBACH MEINOLF
IPC: C07C20100101 , C07D20100101
Abstract: The present invention provides a process for the epoxidation of propene which comprises reacting propene with hydrogen peroxide in the presence of methanol as solvent and a titanium zeolite catalyst, the process further comprising separating propylene oxide from the reaction mixture to obtain a mixture comprising methanol, water, at least one carboxylic acid and at least one carbonyl compound, wherein the at least one carboxylic acid is at least partially neutralized, said process optionally comprising a hydrogenation stage.
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公开(公告)号:AT449054T
公开(公告)日:2009-12-15
申请号:AT04740513
申请日:2004-07-01
Applicant: BASF SE
Inventor: MUELLER ULRICH , SCHUBERT OLGA , HESSE MICHAEL , STOESSER MICHAEL , HAAS PETER , YAGHI OMAR
Abstract: The present invention relates to a process for the alkoxylation of a monool with at least one alkoxylating agent to an alkoxylated alcohol wherein a catalyst is employed which comprises a metallo-organic framework material of metal ions and at least bidentate coordinately bound organic ligands.
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公开(公告)号:AT447632T
公开(公告)日:2009-11-15
申请号:AT07729006
申请日:2007-05-11
Applicant: BASF SE
Inventor: PUETTER HERMANN , SCHUBERT MARKUS , RICHTER INGO , MUELLER ULRICH , TRUKHAN NATALIA
IPC: C25B3/13
Abstract: The present invention relates to a process for preparing a porous metal organic framework comprising at least two organic compounds coordinated to at least one metal ion, which comprises the steps (a) oxidation of at least one anode comprising the metal corresponding to at least one metal ion in a reaction medium in the presence of at least one first organic compound which is an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons have been replaced by heteroatoms selected from the group consisting of N, O and S to form a reaction intermediate comprising the at least one metal ion and the first organic compound; and (b) reaction of the reaction intermediate at a prescribed temperature with at least one second organic compound which coordinates to the at least one metal ion, with the second organic compound being derived from a dicarboxylic, tricarboxylic or tetracarboxylic acid.
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公开(公告)号:DE502006003244D1
公开(公告)日:2009-05-07
申请号:DE502006003244
申请日:2006-11-08
Applicant: BASF SE
Inventor: SCHUBERT MARKUS , MUELLER ULRICH , RUETZ ROGER , HATSCHER STEPHAN
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公开(公告)号:MX2008013969A
公开(公告)日:2009-02-10
申请号:MX2008013969
申请日:2007-04-26
Applicant: BASF SE
Inventor: HESSE MICHAEL , MUELLER ULRICH , SCHUBERT MARKUS , SCHIERLE-ARNDT KERSTIN , OERTEL KAI , FAYE IAN , ALLGEIER THORSTEN , GRAEHN JAN-MICHAEL
IPC: F17C11/00
Abstract: La invención se refiere a un recipiente de gas presurizado con un volumen mínimo de 1 m3 y una presión máxima de llenado para llenar, almacenar y surtir un combustible que se encuentra en estado gaseoso en las condiciones de almacenamiento, cuya combustión puede ser utilizada para impulsar un vehículo, que se caracteriza porque el recipiente de gas presurizado tiene un filtro a través del cual el combustible puede fluir por lo menos en la etapa de llenado y surtido, el filtro es adecuado para remover posibles contaminantes en el combustible provenientes del flujo, dichos contaminantes pueden reducir la capacidad de almacenamiento con relación al gas combustible de un adsorbente utilizado para almacenamiento del gas combustible. La invención se refiere además al uso de un recipiente de gas presurizado de este tipo para llenar un recipiente de gas presurizado adicional, el recipiente de gas presurizado adicional se coloca dentro o bien sobre un vehículo y contiene un adsorbente para el almacenamiento del gas combustible.
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公开(公告)号:MX2008013256A
公开(公告)日:2008-10-29
申请号:MX2008013256
申请日:2007-04-17
Applicant: BASF SE
Inventor: MUELLER ULRICH , SCHUBERT MARKUS , MARX STEFAN
Abstract: La invención se refiere a un material de estructura metálica-orgánica porosa que contiene por lo menos un compuesto orgánico de al menos bidentato que se une de manera coordinada a por lo menos un ión metálico, el por lo menos ión metálico siendo zirconio y el por lo menos un compuesto orgánico de al menos bidentato siendo derivado de un ácido di-, tri-o tetracarboxílico. La invención también se refiere a métodos para la producción de dichos materiales y al uso de los mismos.
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公开(公告)号:MX2008012765A
公开(公告)日:2008-10-14
申请号:MX2008012765
申请日:2007-04-12
Applicant: BASF SE
Inventor: SCHUBERT MARKUS , MUELLER ULRICH , TRUKHAN NATALIA
IPC: C01G1/02 , C01F5/02 , C01F7/02 , C01F7/30 , C01G23/053 , C01G25/02 , C04B35/04 , C04B35/053 , C04B35/10 , C04B35/111 , C04B35/48 , C04B35/486 , C04B38/00
Abstract: La invención se refiere a un método para producir un óxido metálico al calentar un material de estructura metálica-orgánica porosa, dicho material de estructura que contiene por lo menos un compuesto orgánico de al menos bidentato que se une de manera coordinada a por lo menos un ión metalico y el ión metálico siendo seleccionado a partir de los metales incluyendo el segundo a cuarto y treceavo grupo de la Tabla Periódica de los Elementos, vía la temperatura de descomposición completa del material de estructura. La invención también se refiere a óxidos metálicos que se pueden obtener por este método y al uso del mismo.
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公开(公告)号:DE60315453T2
公开(公告)日:2008-05-29
申请号:DE60315453
申请日:2003-05-27
Applicant: BASF SE , UNIV MICHIGAN
Inventor: MUELLER ULRICH , LOBREE LISA , HESSE MICHAEL , YAGHI OMAR M , EDDAOUDI MOHAMED
IPC: C07D301/10 , B01J31/16 , B01J31/22
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公开(公告)号:CA2650609A1
公开(公告)日:2007-11-22
申请号:CA2650609
申请日:2007-05-11
Applicant: BASF SE
Inventor: MUELLER ULRICH , RICHTER INGO , SCHUBERT MARKUS
IPC: C25B3/13 , C25B3/23 , C07D233/54 , C07D235/22
Abstract: Processes comprising: (i) providing an anode comprising zinc; and (ii) oxidizing the anode in a reaction medium in the presence of at least one organic compound to form a porous metal organic framework comprising the least one organic compound coordinated to at least one zinc ion; wherein the at least one organic compound comprises a ring system selected from the group consisting of compounds corresponding to the following structures wherein the ring system optionally bears one or more substituents selected independently from the group consisting of halogens, C1-6-alkyls, phenyl, NH2, NH(C1-6-alkyls), N(C1-6-alkyls)2, OH, O-phenyl and O-C1-6-alkyls, and wherein each C1-6-alkyl and phenyl substituent may independently and optionally bear one or more substituents selected independently from the group consisting of halogens, NH2, NH(C1-6-alkyls), N(C1-6-alkyls)2, OH, O-phenyl and O-C1-6-alkyls.
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