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公开(公告)号：KR101305441B1
公开(公告)日：2013-09-09
申请号：KR1020110096585
申请日：2011-09-23
Applicant: 현대자동차주식회사 , 한국기술교육대학교 산학협력단
Abstract: 본 발명은 고무 Latex(Latex)에 물로부터 호화 시킨 전분 용액을 직접 블렌드(Blend) 하여 원료고무와 충전제를 화학적으로 블렌드 한 고무 조성물이다. 이 때에 고무 Latex와 전분 간의 커플링제(Coupling-agent)로써 레조시놀-포름알데히드(Resorcinol-formaldehyde)를 이용하며, 이를 이용하여 가황 고무 컴파운드(Compound)를 제조한다. 고무 Latex와 호화 전분 용액의 블렌드 시에 커플링제로 레조시놀-포름알데히드를 사용하면 고무와의 친화력이 떨어져 인장강도가 크게 저하되는 문제와 물에 잘 녹는 전분의 특성상 용액상태로 블렌드 시에 일어나는 전분의 손실을 해결할 수 있으며, 그 양의 첨가비에 따라 가황 고무 컴파운드의 물성을 변화시킬 수 있다.
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公开(公告)号：KR1020130032784A
公开(公告)日：2013-04-02
申请号：KR1020110096585
申请日：2011-09-23
Applicant: 현대자동차주식회사 , 한국기술교육대학교 산학협력단
Abstract: PURPOSE: A method for manufacturing a starch/rubber latex compound is provided to suppress the loss of starch and to control the physical property by controlling the content of a coupling agent. CONSTITUTION: A method for manufacturing a starch/rubber latex compound comprises 100.0 parts by weight of a rubber component, 20-100.0 parts by weight of starch filler, 1-10 parts by weight of a coupling agent, and 1-10 parts by weight of a solidifier. The rubber is latex. The starch filler is a gelatinized solution that a starch with a powder shape is gelatinized to distilled water. The coupling agent is a resorcinol-formaldehyde. A rubber-vulcanized composition comprises the rubber composition, a vulcanizer, a vulcanization accelerator, and an oxidizer.
Abstract translation: 目的：提供淀粉/橡胶胶乳化合物的制造方法，以抑制淀粉的损失并通过控制偶联剂的含量来控制物理性能。 构成：制造淀粉/橡胶胶乳化合物的方法包括100.0重量份的橡胶组分，20-100.0重量份淀粉填料，1-10重量份偶联剂和1-10重量份 的固化剂。 橡胶是乳胶。 淀粉填充剂是具有粉末形状的淀粉糊化成蒸馏水的糊化溶液。 偶联剂是间苯二酚 - 甲醛。 橡胶硫化组合物包括橡胶组合物，硫化剂，硫化促进剂和氧化剂。
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公开(公告)号：KR1020090112103A
公开(公告)日：2009-10-28
申请号：KR1020080037801
申请日：2008-04-23
Applicant: 주식회사 삼양제넥스 , 한국기술교육대학교 산학협력단
IPC: C08F220/06 , C08F246/00 , C08F301/00 , C08L3/02
CPC classification number: C08F220/18 , C08F2/22 , C08F2/44 , C08F220/06 , C08F220/14 , C08F246/00
Abstract: PURPOSE: A method for preparing starch-acryl copolymer using emulsifier-free emulsion polymerization is provided to minimize the amount of impurities included in the copolymer without the use of emulsifier. CONSTITUTION: A method for preparing starch-acryl copolymer using emulsifier-free emulsion polymerization comprises the following steps of: gelatinizing starch; mixing the gelatinized starch and monomers containing acrylic compounds at a ratio of 1:1 ~ 1:9 by weight; and emulsifying the mixture in the presence of initiator. The monomers contain up to 20 parts unsaturated carbon acid. The initiator is an organic peroxide compound, inorganic peroxide compound, persulfate compound, cerium ammonium, or redox initiator.
Abstract translation: 目的：提供使用无乳化剂的乳液聚合制备淀粉 - 丙烯酸共聚物的方法，以尽量减少包含在共聚物中的杂质的量，而不使用乳化剂。 构成：使用无乳化剂乳液聚合制备淀粉 - 丙烯酸共聚物的方法包括以下步骤：使淀粉糊化; 以1：1〜1：9的比例混合糊化淀粉和含有丙烯酸类化合物的单体; 并在引发剂存在下使混合物乳化。 单体含有多至20份不饱和碳酸。 引发剂是有机过氧化物，无机过氧化物，过硫酸盐化合物，铈铵或氧化还原引发剂。
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公开(公告)号：KR101821482B1
公开(公告)日：2018-01-24
申请号：KR1020160015445
申请日：2016-02-11
Applicant: 한국기술교육대학교 산학협력단
Abstract: 본발명은난연성및 내한성을갖는난연성탄성소재조성물, 상기난연성탄성소재조성물을포함하는케이블피복용조성물및 이들의제조방법에관한것입니다.
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公开(公告)号：KR101474738B1
公开(公告)日：2014-12-22
申请号：KR1020130010287
申请日：2013-01-30
Applicant: 한국기술교육대학교 산학협력단
Abstract: 본발명은천연고무에퍼옥시드계개시제및 산무수물을반응시켜산 무수물-그래프트된천연고무를제조하는단계및 산무수물-그래프트된천연고무를나일론과반응시키는단계를포함하는, 개질된고무컴파운드의제조방법, 및이로부터제조된개질된고무컴파운드에관한것이다. 본발명의개질된고무컴파운드제조방법에의할경우, 우수한기체차단성, 기계적물성및 마모특성을갖는개질된고무컴파운드를제공할수 있다.
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Patent Agency Ranking
公开(公告)号：KR1020120121214A
公开(公告)日：2012-11-05
申请号：KR1020110039055
申请日：2011-04-26
Applicant: 한국기술교육대학교 산학협력단
Abstract: PURPOSE: A manufacturing method of polyurethane is provided to provide polyurethane with excellent fatigue resistance and improved storage stability and mechanical properties. CONSTITUTION: A manufacturing method of polyurethane comprises: a step of obtaining two or more prepolymers by reacting two or more NCO group-containing diisocyanate having different reactivity with polyol with a molar ratio of 3-6:1 in a respective separate polymerization bath to obtain two or more prepolymers; a step of mixing the two or more prepolymers in one polymerization bath and adding one equivalent or more of polyol, a chain extender, an antifoaming agent and foaming agent based on separated NCO group of in the prepolymer. Diisocyanate with slow reactivity is dipenyl methane-4,4-diisocyanate and the other diisocyanate with quick reactivity is naphthalene-1,5-diisocyante.
Abstract translation: 目的：提供聚氨酯的制造方法，为聚氨酯提供优异的耐疲劳性能和改善的储存稳定性和机械性能。 构成：聚氨酯的制造方法包括：通过在各自的分离的聚合槽中使两种或更多种具有不同反应性的含有NCO基团的二异氰酸酯与摩尔比为3-6:1的多元醇反应获得两种或更多种预聚物，以获得 两种或更多种预聚物; 将两种或更多种预聚物在一个聚合浴中混合并加入基于预聚物中分离的NCO基团的一当量或多种多元醇，扩链剂，消泡剂和发泡剂的步骤。 具有缓慢反应性的二异氰酸酯是二烯基甲烷-4,4-二异氰酸酯，具有快速反应性的其它二异氰酸酯是萘-1,5-二异氰酸酯。
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公开(公告)号：KR1020140097786A
公开(公告)日：2014-08-07
申请号：KR1020130010287
申请日：2013-01-30
Applicant: 한국기술교육대학교 산학협력단
Abstract: The present invention relates to a manufacturing method for a modified rubber compound which comprises: a step of manufacturing an acid anhydride-grafted natural rubber by making a natural rubber react with a peroxide based initiator and an acid anhydride; and a step of making the acid anhydride-grafted natural rubber react with nylon, and to a modified rubber compound manufactured thereby. The manufacturing method for a modified rubber compound of the present invention is able to provide a modified rubber compound with excellent gas barrier properties, mechanical properties and wear properties.
Abstract translation: 本发明涉及一种改性橡胶化合物的制造方法，其特征在于，包括：通过使天然橡胶与过氧化物类引发剂和酸酐反应来制造酸酐接枝天然橡胶的工序; 以及使酸酐接枝的天然橡胶与尼龙反应的步骤和由其制备的改性橡胶混合物。 本发明的改性橡胶化合物的制造方法能够提供具有优异的阻气性，机械性能和耐磨性的改性橡胶化合物。
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公开(公告)号：KR1020130098066A
公开(公告)日：2013-09-04
申请号：KR1020120019884
申请日：2012-02-27
Applicant: 한국기술교육대학교 산학협력단
CPC classification number: C08F220/18 , C08F2/22 , C08F2220/1808 , C08F2220/325 , C08K3/013 , C08K3/04 , C08K5/0025 , C08K5/09 , C08K5/17 , C08K5/31 , C08L33/10
Abstract: PURPOSE: An acryl rubber and an acryl rubber composition have improved heat resistance, mechanical properties, durability, and moldability, and can be molded to a desired shape through a molding or an extrusion process. CONSTITUTION: An acryl rubber is 90-98 parts by weight of at least one monomer among ethyl acrylate, butyl acrylate, and methoxyethyl acrylate and 2-10 parts by weight of a glycidyl methacrylate are emulsification polymerized with regards to 100.0 parts by weight of an acryl rubber. An acryl rubber composition includes 20-40 parts by weight of a filler, 1-10 parts by weight of a crosslinking agent, and 3-15 parts by weight of a crosslinking accelerator to 100.0 parts by weight of the acryl rubber.
Abstract translation: 目的：丙烯酸橡胶和丙烯酸橡胶组合物具有改善的耐热性，机械性能，耐久性和成型性，并且可以通过模制或挤出方法模制成所需形状。 构成：丙烯酸橡胶是丙烯酸乙酯，丙烯酸丁酯和丙烯酸甲氧基乙酯中的至少一种单体为90-98重量份，甲基丙烯酸缩水甘油酯为2-10重量份，相对于100.0重量份的 丙烯橡胶。 丙烯酸橡胶组合物包含20-40重量份的填料，1-10重量份的交联剂和3-15重量份的交联促进剂与100.0重量份的丙烯酸橡胶。
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公开(公告)号：KR101288295B1
公开(公告)日：2013-07-26
申请号：KR1020110039055
申请日：2011-04-26
Applicant: 한국기술교육대학교 산학협력단
Abstract: 본 발명은 반응성이 상이한 둘 이상의 NCO기 함유 디이소시아네이트를 각각 별도로 폴리올과 반응시켜서 프리폴리머를 합성한 후 이들을 혼합함으로써 피로저항성이 우수하고 저장안정성 및 기계적 특성이 개선된 폴리우레탄을 제조하는 방법및 그에 의해 얻어진 폴리우레탄을 제공한다.
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公开(公告)号：KR101281865B1
公开(公告)日：2013-07-05
申请号：KR1020120015947
申请日：2012-02-16
Applicant: 한국기술교육대학교 산학협력단
IPC: D06M15/05 , D06M15/564 , D06M13/02
CPC classification number: D06M15/05 , D06M13/02 , D06M15/564 , Y02P70/637
Abstract: PURPOSE: A coating composition for leather is provided to be cost effective by replacing an expensive coating composition with an inexpensive coating composition. CONSTITUTION: A coating composition for leather with brush stability, volatility and stability in dilution comprises 80-90 parts by weight % of nitrocellulose dope composition and 10-20 parts by weight % of polyurethane resin. The nitrocellulose dope composition is mixed with 25-45 parts by weight of alkyd resin, 4-8 parts by weight of nitro cellulose, 4-10 parts by weight of butylpropionate and 10-30 parts by weight of ketone. The polyurethane resin is polymerized by diisocyanate, 1,4- butanediol or ethylene glycol which is chosen from a group made of ether type polyol, N-methylpyrolidone (NMP) solvent, methylene diphenyl diisocyanate, toluene diisocyanate and hexamethylene diisocyanate. The nitrocellulose dope composition comprises 70 parts by weight of ethyl acetate for 100 parts by weight of nitrocellulose dope composition.
Abstract translation: 目的：提供一种用于皮革的涂料组合物，通过用廉价的涂料组合物代替昂贵的涂料组合物而具有成本效益。 构成：用于具有刷稳定性，挥发性和稀释稳定性的皮革用涂料组合物包含80-90重量％的硝化纤维素涂料组合物和10-20重量％的聚氨酯树脂。 硝酸纤维素涂料组合物与25-45重量份醇酸树脂，4-8重量份硝基纤维素，4-10重量份丙酸丁酯和10-30重量份酮混合。 聚氨酯树脂由选自由醚型多元醇，N-甲基吡咯烷酮（NMP）溶剂，亚甲基二苯基二异氰酸酯，甲苯二异氰酸酯和六亚甲基二异氰酸酯组成的组中的二异氰酸酯，1,4-丁二醇或乙二醇聚合。 硝酸纤维素涂料组合物包含70重量份的乙酸乙酯，用于100重量份硝化纤维素涂料组合物。
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