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公开(公告)号:DE69516446T2
公开(公告)日:2000-12-14
申请号:DE69516446
申请日:1995-02-28
Applicant: AGENCY IND SCIENCE TECHN
Inventor: TAGUCHI YOICHI , OISHI AKIHIRO , SHIBUYA ISAO , TSUCHIYA TOHRU
IPC: A01N43/90 , C07D491/04 , C07D491/048 , A61K31/395
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公开(公告)号:DE69516446D1
公开(公告)日:2000-05-31
申请号:DE69516446
申请日:1995-02-28
Applicant: AGENCY IND SCIENCE TECHN
Inventor: TAGUCHI YOICHI , OISHI AKIHIRO , SHIBUYA ISAO , TSUCHIYA TOHRU
IPC: A01N43/90 , C07D491/04 , C07D491/048 , A61K31/395
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公开(公告)号:AU779638B2
公开(公告)日:2005-02-03
申请号:AU2522100
申请日:2000-03-31
Applicant: AGENCY IND SCIENCE TECHN
Inventor: OISHI AKIHIRO , TAGUCHI YOICHI , FUJITA KENICHI , IKEDA YOSHIKAZU , MASUDA TAKASHI , ISHIGAMI YUTAKA , NAKAYAMA KAZUO , KINUGASA SHINICHI , NAKAHARA HISAE
IPC: C08G63/08 , C08G63/78 , C08G63/82 , C08L101/16
Abstract: A process of producing a polyester or copolyester, wherein at least one cyclic lactone of the following formula (I): wherein n is an integer of 1-4 provided that n is not 2 when only one cyclic lactone is used, is polymerized under a pressure of at least 200 MPa in the absence of any catalyst or in the presence of a metal-free polyesterification catalyst.
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公开(公告)号:GB2360779A
公开(公告)日:2001-10-03
申请号:GB0007928
申请日:2000-03-31
Applicant: AGENCY IND SCIENCE TECHN
Inventor: TAGUCHI YOICHI , OISHI AKIHIRO , IKEDA YOSHIKAZU , FUJITA KEN-ICHI , MASUDA TAKASHI
Abstract: An aliphatic copolyester having a plurality of first ester units of the formula : - CO - [R 1 ] t - CO - O - R 2 - O - wherein R 1 represents a divalent aliphatic group, R 2 represents a divalent aliphatic and t is an integer of 0 or 1, and a plurality of second ester units of the formula: wherein R 1 and t are as defined above and R 3 represents an aliphatic group. The molar ratio of the first ester unit to the second ester unit is 90:10 to 99.9:0.1. The copolyester is produced by reacting an aliphatic diester e.g. dimethyl succinate with an aliphatic glycol e.g. 1,4 butanediol and with a monoacylated glycerin and with a monoacylated glycerin e.g. glyceryl a -monolaurate under ester exchanging conditions.
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公开(公告)号:DE10009769A1
公开(公告)日:2000-09-28
申请号:DE10009769
申请日:2000-03-01
Applicant: AGENCY IND SCIENCE TECHN
Inventor: TAGUCHI YOICHI , OISHI AKIHIRO , IKEDA YOSHIKAZU , FUJITA KEN-ICHI , MASUDA TAKASHI
Abstract: The aliphatic polyester expressed by a general formula (I), is new. - The aliphatic polyester is expressed by a general formula (I): (-CO-[R1]t-CO-O-R2-O-)p (I) t = molar fraction of ester portion within range of 0 or 1; r is molar fraction of ester portion which is in the range of 0.001-0.10; The R1 =(CH2)2; and R2 = (CH2)4. An independent claim is also included for aliphatic polyester manufacturing method.
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公开(公告)号:GB2360779B
公开(公告)日:2004-03-24
申请号:GB0007928
申请日:2000-03-31
Applicant: AGENCY IND SCIENCE TECHN
Inventor: TAGUCHI YOICHI , OISHI AKIHIRO , IKEDA YOSHIKAZU , FUJITA KEN-ICHI , MASUDA TAKASHI
Abstract: The aliphatic polyester expressed by a general formula (I), is new. - The aliphatic polyester is expressed by a general formula (I): (-CO-[R1]t-CO-O-R2-O-)p (I) t = molar fraction of ester portion within range of 0 or 1; r is molar fraction of ester portion which is in the range of 0.001-0.10; The R1 =(CH2)2; and R2 = (CH2)4. An independent claim is also included for aliphatic polyester manufacturing method.
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公开(公告)号:FR2790761B1
公开(公告)日:2003-03-28
申请号:FR0002450
申请日:2000-02-28
Applicant: AGENCY IND SCIENCE TECHN
Inventor: TAGUCHI YOICHI , OISHI AKIHIRO , IKEDA YOSHIKAZU , FUJITA KEN ICHI , MASUDA TAKASHI
Abstract: The aliphatic polyester expressed by a general formula (I), is new. - The aliphatic polyester is expressed by a general formula (I): (-CO-[R1]t-CO-O-R2-O-)p (I) t = molar fraction of ester portion within range of 0 or 1; r is molar fraction of ester portion which is in the range of 0.001-0.10; The R1 =(CH2)2; and R2 = (CH2)4. An independent claim is also included for aliphatic polyester manufacturing method.
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公开(公告)号:FR2790761A1
公开(公告)日:2000-09-15
申请号:FR0002450
申请日:2000-02-28
Applicant: AGENCY IND SCIENCE TECHN
Inventor: TAGUCHI YOICHI , OISHI AKIHIRO , IKEDA YOSHIKAZU , FUJITA KEN ICHI , MASUDA TAKASHI
Abstract: The aliphatic polyester expressed by a general formula (I), is new. The aliphatic polyester is expressed by a general formula (I): (-CO- R t-CO-O-R -O-)p (I) t = molar fraction of ester portion within range of 0 or 1; r is molar fraction of ester portion which is in the range of 0.001-0.10; The R =(CH2)2; and R = (CH2)4. An Independent claim is also included for aliphatic polyester manufacturing method.
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公开(公告)号:JPH0892203A
公开(公告)日:1996-04-09
申请号:JP23284694
申请日:1994-09-28
Applicant: AGENCY IND SCIENCE TECHN
Inventor: TSUCHIYA TORU , SHIBUYA ISAO , TAGUCHI YOICHI , OISHI AKIHIRO , HONDA KAZUMASA
IPC: C07D223/08 , C07C327/42 , C07C327/44 , C07D223/02 , C07D223/06 , C07D225/02
Abstract: PURPOSE: To provide a new β-ketothioamide derivative useful as a chelating reagent or an intermediate for organic synthesis and easily producible by a new reaction of an N,N-disubstituted amide with a bis(trialkylsilyl)thioketene. CONSTITUTION: This β-ketothioamide derivative is expressed by formula I (R and R are each a hydrocarbon group; R is H or a hydrocarbon group; R may be bonded with R or R to form a ring structure), e.g. N,N-dimethyl-3- oxothiobutyramide of formula II. The compound of formula I can be produced by reacting an N,N-disubstituted amide of formula III with a bis(trialkylsilyl) thioketene and treating the reaction product with an alcohol. The β- ketothioamide derivative can be produced by this production process with a simple procedure under mild reaction condition in high yield using an inexpensive raw material.
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公开(公告)号:JPH03109382A
公开(公告)日:1991-05-09
申请号:JP24860289
申请日:1989-09-25
Applicant: AGENCY IND SCIENCE TECHN
Inventor: TAGUCHI YOICHI , SHIBUYA ISAO
IPC: C07D251/34
Abstract: PURPOSE:To efficiently obtain the title compound useful as an improver for resins in high yield by reacting an isocyanic ester in the presence of a base under high pressure. CONSTITUTION:An isocyanic ester (e.g. phenyl isocyanate) shown by the formula NCO (R is alkyl or aryl) is reacted in the presence of a base (e.g. triethylamine) under high pressure (preferably 500-4,000kg/cm ) preferably at room temperature to 10 deg.C for 5-50 hours to give the objective compound shown by the formula.
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