PROPYLENE-BASED COPOLYMER COMPOSITON FOR PIPES
    1.
    发明申请
    PROPYLENE-BASED COPOLYMER COMPOSITON FOR PIPES 审中-公开
    用于管道的丙烯基共聚物复合物

    公开(公告)号:WO2016012199A1

    公开(公告)日:2016-01-28

    申请号:PCT/EP2015/064684

    申请日:2015-06-29

    Abstract: A polyolefin composition comprising: A) from 90.0 wt% to 99.0 wt%; of a copolymer of propylene with ethylene wherein: i) the content of ethylene derived units comprised between 1.0 wt% and 8.0 wt%; (ii) the melting temperature ranges from 135° C to 155° C; (iii) the melt flow rate (230°C/5 kg.. ISO 1133) ranging from 0.2 g/10min to 3.5 g/10min; (iv) the xylene solubles at 25°C ranges from 10.0 wt% to 4.0wt%; (v) the polydispersity, PI, ranges from 3.0 to 7.0; B) from 1.0 wt% to 10.0 wt%; of a propylene ethylene copolymer containing from 8.0 wt% to 20.0 wt% of ethylene; said copolymer having a MFR (measured at 190°C 2.16 kg of load) comprised between 0.5 g/10 min and 5.0 g/10 min wherein the resulting polyolefin composition has an melt flow rate (230°C/5 kg.. ISO 1133) ranging from 0.2 g/10min to 4.0 g/10min; the sum A+B being 100.

    Abstract translation: 一种聚烯烃组合物,其包含:A)90.0wt%至99.0wt%; 的丙烯与乙烯的共聚物,其中:i)乙烯衍生单元的含量为1.0重量%至8.0重量%; (ii)熔融温度范围为135℃至155℃; (iii)0.2g / 10min至3.5g / 10min范围内的熔体流动速率(230℃/ 5kg .. ISO 1133); (iv)二甲苯可溶物在25℃的范围为10.0重量%至4.0重量%; (v)多分散性PI的范围为3.0至7.0; B)为1.0重量%〜10.0重量% 的含有8.0重量%至20.0重量%乙烯的丙烯乙烯共聚物; 所述共聚物具有在0.5g / 10min至5.0g / 10min之间的MFR(在190℃2.16kg负荷下测量),其中所得聚烯烃组合物具有熔体流动速率(230℃/ 5kg .. ISO 1133 )为0.2g / 10min至4.0g / 10min; 总和A + B为100。

    PROPYLENE-BASED COPOLYMER COMPOSITION FOR PIPES
    2.
    发明申请
    PROPYLENE-BASED COPOLYMER COMPOSITION FOR PIPES 审中-公开
    用于管道的丙烯基共聚物组合物

    公开(公告)号:WO2015180918A1

    公开(公告)日:2015-12-03

    申请号:PCT/EP2015/059241

    申请日:2015-04-28

    Abstract: A polyolefin composition comprising: A) from 90.0 wt% to 99.0 wt%; of a copolymer of propylene with ethylene wherein: i) the content of ethylene derived units is comprised between 1.0 wt% and 8.0 wt%; (ii) the melting temperature ranges from 135° C to 155° C; (iii) the melt flow rate (230°C/5 kg.. ISO 1133) ranging from 0.2 g/10min to 3.5 g/10min; (iv) the xylene solubles at 25°C ranges from 20.0 wt% to 4.0wt%; (v) the polydispersity, PI, ranges from 3.0 to 7.0; B) from 1.0 wt% to 10.0 wt%; of a propylene, ethylene copolymer composition comprising: b1) from 12 wt% to 52 wt%; of a propylene homopolymer or a propylene/ethylene copolymer; b2) from 48 wt% to 88 wt% of a propylene ethylene copolymer having a content of ethylene derived units ranging from 15.0 wt% to 42.0 wt%.

    Abstract translation: 一种聚烯烃组合物,其包含:A)90.0wt%至99.0wt%; 的丙烯与乙烯的共聚物,其中:i)乙烯衍生单元的含量为1.0重量%至8.0重量%; (ii)熔融温度范围为135℃至155℃; (iii)0.2g / 10min至3.5g / 10min范围内的熔体流动速率(230℃/ 5kg .. ISO 1133); (iv)25℃的二甲苯可溶物的含量为20.0重量%〜4.0重量% (v)多分散性PI的范围为3.0至7.0; B)为1.0重量%〜10.0重量% 的丙烯,乙烯共聚物组合物,其包含:b1)12重量%至52重量%; 的丙烯均聚物或丙烯/乙烯共聚物; b2)为48重量%至88重量%的丙烯乙烯共聚物,其乙烯衍生单元的含量为15.0重量%至42.0重量%。

    NUCLEATED PROPYLENE-BASED POLYOLEFIN COMPOSITIONS
    3.
    发明申请
    NUCLEATED PROPYLENE-BASED POLYOLEFIN COMPOSITIONS 审中-公开
    基于丙烯的聚烯烃组合物

    公开(公告)号:WO2014170070A1

    公开(公告)日:2014-10-23

    申请号:PCT/EP2014/054869

    申请日:2014-03-12

    Abstract: A polyolefin composition, particularly fit for the production of extrusion blow molded articles, comprising (a) a propylene-ethylene copolymer having a content of units deriving from ethylene of 4.0 % by weight or higher, and (b) a nucleating agent and having a crystallization temperature (Tc) higher than 117°C can be obtained by copolymerizing propylene and ethylene in the presence of a catalyst system obtained by contacting a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 40 to 90% by mol with respect to the total amount of donors and selected from succinates and the other selected from 1,3 diethers, an aluminum hydrocarbyl compound, and optionally an external electron donor compound.

    Abstract translation: 一种聚烯烃组合物,特别适用于生产挤出吹塑制品,其包含(a)乙烯衍生物的含量为4.0重量%以上的丙烯 - 乙烯共聚物,和(b)成核剂并具有 在通过使包含卤化镁的固体催化剂组分,至少具有Ti-卤素键的钛化合物的固体催化剂组分和在至少含有Ti-卤素键的钛化合物的存在下,将丙烯和乙烯共聚合,可以获得高于117℃的结晶温度(Tc) 至少两种电子给体化合物,其中一种以相对于供体总量为40至90摩尔%的量存在,并且选自琥珀酸盐,另一种选自1,3-二醚,铝烃基化合物和任选的 外电子给体化合物。

    POLYMER COMPOSITION
    4.
    发明申请
    POLYMER COMPOSITION 审中-公开
    聚合物组合物

    公开(公告)号:WO2010081753A1

    公开(公告)日:2010-07-22

    申请号:PCT/EP2010/050015

    申请日:2010-01-04

    Abstract: A polypropylene composition comprising: A) from 30% to 90% by weight of a propylene polymer composition comprising: a1) from 20% to 90% of a propylene homopolymer, or a copoloymer of propylene containing 3% or less of derived units of ethylene or C 4 -C 10 α-olefin(s) or of combinations thereof, said homopolymer or copolymer having a content of isotactic pentads (mmmm), measured by 13 C NMR on the fraction insoluble in xylene at 25 °C, higher than 96; a2) from 10% to 80%, of a copolymer of ethylene containing from 40% to 70% of derived units of propylene or C 4 -C 10 α-olefin(s) or of combinations thereof; B) from 10% to 70% by weight of a multimodal ethylene copolymer wherein the comonomer is selected from the derived units of alpha olefins of formula CH 2 =CHT wherein T is a C 3 -C 10 alkyl group; having the following properties: i) density (with ISO 1183) comprised in the range from 0.850 to 0.935 g/cm 3 ; ii) total comonomer content ranging from 6% to 30% by weight; iii) content of 1-butene derived units ranging from 0 to 2% by weight; iv) Mw/Mn comprised from 4 to 20; v) intrinsic viscosity (decalin at 135°C as determined according to EN IS0 1628-312003) comprised between 1.0 and 4.0 dL/g, and C) from 0 to 50 % by weight; preferably from 0 to 20% of a filler.

    Abstract translation: 一种聚丙烯组合物,其包含:A)30重量%至90重量%的丙烯聚合物组合物,其包含:a1)20重量%至90重量%的丙烯均聚物,或含有3%或更少的衍生的乙烯单元的丙烯共聚物 或C 4 -C 10α-烯烃或其组合,所述均聚物或共聚物的含量为全同立构五单元组(mmmm),通过13 C NMR测量在25℃下不溶于二甲苯的级分,高于96; a2)10%至80%的含有40%至70%的衍生单元的丙烯或C 4 -C 10α-烯烃的乙烯的共聚物或其组合; B)10重量%至70重量%的多峰乙烯共聚物,其中共聚单体选自式CH 2 = CHT的α-烯烃的衍生单元,其中T是C 3 -C 10烷基; 具有以下特性:i)密度(ISO 1183),范围为0.850-0.935g / cm3; ii)总共聚单体含量为6重量%至30重量%; iii)1-丁烯衍生单元的含量为0-2重量%; iv)Mw / Mn为4〜20; v)特性粘度(根据EN IS 1628-312003确定的135℃下的萘烷)为1.0-4.0dL / g,C)为0至50重量% 优选0至20%的填料。

    HETEROPHASIC POLYOLEFIN COMPOSITIONS HAVING IMPROVED TENSILE PROPERTIES
    7.
    发明申请
    HETEROPHASIC POLYOLEFIN COMPOSITIONS HAVING IMPROVED TENSILE PROPERTIES 审中-公开
    具有改善拉伸性能的异质聚烯烃组合物

    公开(公告)号:WO2009050025A1

    公开(公告)日:2009-04-23

    申请号:PCT/EP2008/062998

    申请日:2008-09-29

    CPC classification number: C08L23/0815 C08L23/10 C08L2205/02 C08L2666/06

    Abstract: Polyolefin composition comprising, in percent by weight: A) 50-75% of a blend of polymers (PP) and (EC I ), wherein (PP) is selected from the group consisting of: (i) propylene homopolymers; (ii) copolymers of propylene; (iii) combinations of said homopolymers (i) and copolymers (ii); (EC 1 ) is a copolymer of ethylene and propylene or CH 2 =CHR alpha-olefin(s), where R is a 2-8 carbon alkyl radical, or a copolymer of ethylene, propylene and the said CH 2 =CHR alpha-olefin(s), containing from 20 to 35%, of ethylene; and B) 25-50% of a copolymer (EC II ) of ethylene and propylene or CH 2 =CHR alpha-olefin(s), where R is a 2-8 carbon alkyl radical,or a copolymer of ethylene, propylene and the said CH 2 =CHR alpha-olefin(s), containing from 40 to 60% of ethylene; in which composition the copolymer component (EC I ) is present in amounts from 23 to 45% with respect to the total weight of (A),and the intrinsic viscosity [η tot ] of the fraction XS soluble in xylene at room temperature, referred to the total weight of (A) + (B), is of 3.5 dl/g or more.

    Abstract translation: 聚烯烃组合物,其以重量百分比计包含:A)50-75%的聚合物(PP)和(ECI)共混物,其中(PP)选自:(i)丙烯均聚物; (ii)丙烯的共聚物; (iii)所述均聚物(i)和共聚物(ii)的组合; (EC1)是乙烯和丙烯或CH 2 =CHRα-烯烃的共聚物,其中R是2-8个碳的烷基,或乙烯,丙烯和所述的CH 2 = CHR的α-烯烃的共聚物 ),含有20至35%的乙烯; 和B)乙烯和丙烯或CH 2 =CHRα-烯烃的共聚物(ECII)的25-50%,其中R是2-8个碳的烷基,或乙烯,丙烯和所述的CH2的共聚物 = CHRα-烯烃,含有40至60%的乙烯; 在该组合物中,相对于(A)的总重量,共聚物组分(ECI)的存在量为23-45%,室温下可溶于二甲苯的级分XS的特性粘度[ηtot] (A)+(B)的总重量为3.5dl / g以上。

    POLYMER COMPOSITION FOR BUMPERS AND INTERIORS AND POLYETHYLENE-BASED RESIN PRECURSOR
    9.
    发明申请
    POLYMER COMPOSITION FOR BUMPERS AND INTERIORS AND POLYETHYLENE-BASED RESIN PRECURSOR 审中-公开
    用于缓冲和内部聚合物和聚乙烯基树脂前体的聚合物组合物

    公开(公告)号:WO2013068273A1

    公开(公告)日:2013-05-16

    申请号:PCT/EP2012/071443

    申请日:2012-10-30

    Abstract: Polyolefin compositions suitable for injection moulded items e.g. for impact bumpers and car interiors comprising from 30% to 90% by weight of an heterophasic propylene polymer composition (A); and from 10% to 70% by weight of a multimodal ethylene/C6-C12 alpha olefin copolymer (B); having density from 0.850 to 0.920 g/cm 3 , total comonomer content from 6% to 30% by weight, Mw/Mn from 4 to 20; intrinsic viscosity in decalin at 135°C from 1.0 to 4.0 dL/g, and comprising an HDPE fraction (HDPE %wt) up to 30%wt; further comprising up to 50 % by weight of a filler (C) and optionally, in amount up to 10% by weight with respect to the overall composition, an impact modifier masterbatch component (D) consisting of a ultra-soft heterophasic copolymer component.

    Abstract translation: 适用于注射成型物品的聚烯烃组合物 用于冲击保险杠和汽车内饰,其包含按重量计30%至90%的异相丙烯聚合物组合物(A); 和10重量%至70重量%的多峰乙烯/ C 6 -C 12α-烯烃共聚物(B); 密度为0.850〜0.920g / cm3,总共聚单体含量为6〜30重量%,Mw / Mn为4〜20; 十氢萘在135℃下的特性粘度为1.0至4.0dL / g,并且包含高达30%wt的HDPE级分(HDPE%wt); 进一步包含至多50重量%的填料(C),并且任选地,相对于整个组合物,其量为至多10重量%,由超软多相共聚物组分组成的抗冲改性剂母料组分(D)。

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