公开(公告)号：DE59704476D1

公开(公告)日：2001-10-04

申请号：DE59704476

申请日：1997-10-21

Applicant: BASF AG

Inventor： JUENGLING STEPHAN ,  GAUSEPOHL HERMANN ,  WEISS HORST ,  BAUMGAERTEL MICHAEL

IPC: C08F4/46 ,  C08F4/48 ,  C08F4/50

Abstract: Initiator systems for anionic polymerization of vinyl monomers with polar groups, containing A) a1) at least one starter having general formula R -M or R -M -RC, wherein R , R or R independently stand for branched or straight-chain alkyl radicals of 1-6 carbon atoms, aryl radicals of 6-20 carbon atoms or alkyl radicals with 1-6 carbon atoms carrying at least one phenyl radical and M stands for a metal selected from the group of alkaline metals, and M stands for a metal selected from the group of alkaline earth metals, or a2) as a starter "living" polymer chains, whose chain ends are possibly stabilized by sterically demanding and/or aromatic radicals and B) at least one alkaline (I) or alkaline earth metal alcoholate (II) or at least one alkaline (I) and at least one alkaline earth metal alcoholate (II) which have at least one amino or one phosphino substituent or at least one amino and one phosphino substituent.

公开(公告)号：DE59702297D1

公开(公告)日：2000-10-05

申请号：DE59702297

申请日：1997-10-28

Applicant: BASF AG

Inventor： BAUMGAERTEL MICHAEL ,  DEMBEK GERHARD ,  HAHN KLAUS ,  HOLOCH JAN ,  HUSEMANN WOLFRAM ,  KAEMPFER KNUT ,  LAY PETER ,  RUECK SWEN ,  SCHIESSL MICHAEL ,  WITT MICHAEL

IPC: C08F257/02 ,  C08J9/20

公开(公告)号：NO980736L

公开(公告)日：1998-02-20

申请号：NO980736

申请日：1998-02-20

Applicant: BASF AG

Inventor： LAY PETER NICOLAUS ,  RUECK SWEN ,  SCHIESSL MICHAEL ,  WITT MICHAEL ,  ZETTLER HANS DIETER ,  BAUMGAERTEL MICHAEL ,  DEMBEK GERHARD ,  HAHN KLAUS ,  HOLOCK JAN ,  HUSEMANN WOLFRAM ,  KAEMPFER KNUT

IPC: C08J9/16 ,  B01J13/14 ,  B01J19/18 ,  B01J19/24 ,  C08F2/02 ,  C08F2/18 ,  C08F12/08 ,  C08F ,  C08J

Abstract: PCT No. PCT/EP96/03633 Sec. 371 Date Jan. 29, 1998 Sec. 102(e) Date Jan. 29, 1998 PCT Filed Aug. 19, 1996 PCT Pub. No. WO97/08231 PCT Pub. Date Mar. 6, 1997A continuous process for preparing bead-form expandable styrene polymers in which the styrene is prepolymerized in bulk to a conversion of 10 to 80%, the prepolymer is dispersed in liquid form in an aqueous phase in the presence of suspension stabilizers, and the polymerization of the prepolymer is completed in an aqueous suspension to a residual styrene content of less than 2000 ppm.

公开(公告)号：DE19904058A1

公开(公告)日：2000-08-03

申请号：DE19904058

申请日：1999-02-02

Applicant: BASF AG

Inventor： FISCHER WOLFGANG ,  BAUMGAERTEL MICHAEL ,  HOFMANN JUERGEN

IPC: C08F2/00 ,  C08F36/06 ,  C08F236/00 ,  C08L9/00

Abstract: Solvent-free diene rubber solutions prepared continuously in a spray tower reactor with an inner wall by polymerization of monomers with insertion of an anionic initiator, and deposition of the diene rubber particles on the reactor inner wall without repulsion by this wall are new. An Independent claim is included for an apparatus for preparing the solvent free solutions comprising a spray tower reactor, a wall and a second wall (1b) with openings arranged so that an inner space is formed between the reactor inner wall and the second wall (1b).

公开(公告)号：NO980736D0

公开(公告)日：1998-02-20

申请号：NO980736

申请日：1998-02-20

Applicant: BASF AG

Inventor： LAY PETER NICOLAUS ,  RUECK SWEN ,  SCHIESSL MICHAEL ,  WITT MICHAEL ,  ZETTLER HANS DIETER ,  BAUMGAERTEL MICHAEL ,  DEMBEK GERHARD ,  HAHN KLAUS ,  HOLOCK JAN ,  HUSEMANN WOLFRAM ,  KAEMPFER KNUT

IPC: C08J9/16 ,  B01J13/14 ,  B01J19/18 ,  B01J19/24 ,  C08F2/02 ,  C08F2/18 ,  C08F12/08 ,  C08F ,  C08J

Abstract: PCT No. PCT/EP96/03633 Sec. 371 Date Jan. 29, 1998 Sec. 102(e) Date Jan. 29, 1998 PCT Filed Aug. 19, 1996 PCT Pub. No. WO97/08231 PCT Pub. Date Mar. 6, 1997A continuous process for preparing bead-form expandable styrene polymers in which the styrene is prepolymerized in bulk to a conversion of 10 to 80%, the prepolymer is dispersed in liquid form in an aqueous phase in the presence of suspension stabilizers, and the polymerization of the prepolymer is completed in an aqueous suspension to a residual styrene content of less than 2000 ppm.

公开(公告)号：PL325059A1

公开(公告)日：1998-07-06

申请号：PL32505996

申请日：1996-08-19

Applicant: BASF AG

Inventor： LAY PETER NIKOLAUS ,  RUECK SWEN ,  SCHIESSL MICHAEL ,  WITT MICHAEL ,  ZETTLER HANS DIETER ,  BAUMGAERTEL MICHAEL ,  DEMBEK GERHARD ,  HAHN KLAUS ,  HOLOCH JAN ,  HUSEMANN WOLFRAM ,  KAEMPFER KNUT

IPC: C08J9/16 ,  B01J13/14 ,  B01J19/18 ,  B01J19/24 ,  C08F2/02 ,  C08F2/18 ,  C08F12/08 ,  C08E112/08

Abstract: PCT No. PCT/EP96/03633 Sec. 371 Date Jan. 29, 1998 Sec. 102(e) Date Jan. 29, 1998 PCT Filed Aug. 19, 1996 PCT Pub. No. WO97/08231 PCT Pub. Date Mar. 6, 1997A continuous process for preparing bead-form expandable styrene polymers in which the styrene is prepolymerized in bulk to a conversion of 10 to 80%, the prepolymer is dispersed in liquid form in an aqueous phase in the presence of suspension stabilizers, and the polymerization of the prepolymer is completed in an aqueous suspension to a residual styrene content of less than 2000 ppm.

公开(公告)号：DE59602118D1

公开(公告)日：1999-07-08

申请号：DE59602118

申请日：1996-08-19

Applicant: BASF AG

Inventor： LAY PETER ,  RUECK SWEN ,  SCHIESSL MICHAEL ,  WITT MICHAEL ,  ZETTLER HANS ,  BAUMGAERTEL MICHAEL ,  DEMBEK GERHARD ,  HAHN KLAUS ,  HOLOCH JAN ,  HUSEMANN WOLFRAM ,  KAEMPFER KNUT

IPC: C08J9/16 ,  B01J13/14 ,  B01J19/18 ,  B01J19/24 ,  C08F2/02 ,  C08F2/18 ,  C08F12/08

Abstract: PCT No. PCT/EP96/03633 Sec. 371 Date Jan. 29, 1998 Sec. 102(e) Date Jan. 29, 1998 PCT Filed Aug. 19, 1996 PCT Pub. No. WO97/08231 PCT Pub. Date Mar. 6, 1997A continuous process for preparing bead-form expandable styrene polymers in which the styrene is prepolymerized in bulk to a conversion of 10 to 80%, the prepolymer is dispersed in liquid form in an aqueous phase in the presence of suspension stabilizers, and the polymerization of the prepolymer is completed in an aqueous suspension to a residual styrene content of less than 2000 ppm.

公开(公告)号：NO980736A

公开(公告)日：1998-02-20

申请号：NO980736

申请日：1998-02-20

Applicant: BASF AG

Inventor： LAY PETER NICOLAUS ,  RUECK SWEN ,  SCHIESSL MICHAEL ,  WITT MICHAEL ,  ZETTLER HANS DIETER ,  BAUMGAERTEL MICHAEL ,  DEMBEK GERHARD ,  HAHN KLAUS ,  HOLOCK JAN ,  HUSEMANN WOLFRAM ,  KAEMPFER KNUT

IPC: C08J9/16 ,  B01J13/14 ,  C08F2/02 ,  C08F2/18 ,  C08F12/08 ,  C08F ,  C08J

CPC classification number: C08F12/08

公开(公告)号：CA2227270A1

公开(公告)日：1997-03-06

申请号：CA2227270

申请日：1996-08-19

Applicant: BASF AG

Inventor： LAY PETER NIKOLAUS ,  BAUMGAERTEL MICHAEL ,  KAEMPFER KNUT ,  HAHN KLAUS ,  HOLOCH JAN ,  DEMBEK GERHARD ,  RUECK SWEN ,  WITT MICHAEL ,  HUSEMANN WOLFRAM ,  SCHIESSL MICHAEL ,  ZETTLER HANS DIETER

IPC: C08J9/16 ,  B01J13/14 ,  B01J19/18 ,  B01J19/24 ,  C08F2/02 ,  C08F2/18 ,  C08F12/08 ,  C08J9/20 ,  C08L25/04

Abstract: A process is disclosed for continuously producing expandable styrene polymers by polymerising styrene in the presence of expanding agents in three steps: (a) prepolymerising styrene in the mass; (b) dispersing the prepolymer in an aqueous phase; and (c) polymerising the prepolymer in an aqueous suspension.