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    CATALYTIC PATTERNS CONTAINING METAL COMPLEXES WITH AN ADAMANTANE-LIKE STRUCTURE
    3.
    发明申请
    CATALYTIC PATTERNS CONTAINING METAL COMPLEXES WITH AN ADAMANTANE-LIKE STRUCTURE 审中-公开
    催化剂体系包含金属配合物的ADAMANTANÄHNLICHER结构

    公开(公告)号：WO9816564A2

    公开(公告)日：1998-04-23

    申请号：PCT/EP9705201

    申请日：1997-09-23

    Applicant: BASF AG ,  GEPRAEGS MICHAEL ,  STUERMER RAINER ,  WEISS HORST ,  STEIGER SUSANNE

    Inventor： GEPRAEGS MICHAEL ,  STUERMER RAINER ,  WEISS HORST ,  STEIGER SUSANNE

    IPC: B01J31/22 ,  C08F4/602 ,  C08F4/642 ,  C08F4/645 ,  C08F10/00 ,  C08F12/00 ,  C08F12/04 ,  C08F210/02

    CPC classification number: C08F10/00 ,  C08F12/08 ,  C08F210/02 ,  C08F4/64072 ,  C08F212/08

    Abstract: The present invention relates to catalytic patterns, the active components of which are A) metal complexes of general formula (I), in which the substituents have the following notation: M is a metal of the subgroup III, IV, V or VI in the periodic table of the elements or a metal of the lanthanide series; Y is a negative nucleofuge atom or a negative leaving group; X and X are neutral atoms or negatively loaded atoms from the main group IV, V or VI in the periodic table of the elements; Z is hydrogen, C1- to C10-alkyl, C3- to C10-cycloalkyl, C1- to C10-alkoxy, C1- to C10-alkylthiolat or dialkylamide with, in each case, 1 to 4 C-atoms in the alkyl residues; R to R are hydrogen, organocarbon or organosilicon residues, n is 0, 1 or 2, the valence of M is (2+n), and B) a metallocenium-ionizing compound.

    Abstract translation: 包含作为活性成分A）（I）通式的金属配合物，其中取代基具有以下含义的催化剂体系：M是金属，V或III的VI，IV ... 元素或镧系的金属的周期表的子组; Y是负离去原子或负离去基团; X和X <1>为IV的带负电荷的或中性原子。，V。和VI。 元素的周期表主族; Z是氢，C1-C10烷基，C3至C10环烷基，C1至C10烷氧基，C1至C10烷基硫醇或烷基，R <1>至R <1至4个碳原子的二烷基酰胺具有 11>氢，碳 - 有机或有机硅基团，n为0，1或2，M（2 + n）和B）形成茂金属离子的化合物的化合价。

    METHOD FOR THE EMULSION POLYMERIZATION OF OLEFINS
    6.
    发明专利
    METHOD FOR THE EMULSION POLYMERIZATION OF OLEFINS 未知

    公开(公告)号：AU2003250070A1

    公开(公告)日：2004-02-23

    申请号：AU2003250070

    申请日：2003-07-16

    Applicant: BASF AG

    Inventor： BAUERS FLORIAN M ,  CHOWDHRY MUBARIK MAHMOOD ,  SCHMID MARKUS ,  PREISHUBER-PFLUGL PETER ,  SAVA XAVIER ,  WEISS HORST ,  MECKING STEFAN

    IPC: C08F2/22 ,  C08F2/24 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08F10/00

    Abstract: A method for the emulsion polymerization of one or more olefins by reacting a ligand of general formulae Ia and Ib or a mixture of at least two ligands Ia or Ib, wherein R respectively represents one or several of the following radicals; hydrogen, halogen, nitrile, C1-C12-alkyl groups, C1-C12-alkoxy groups, C7-C13-aralkyl groups, C6-C14-aryl groups, and wherein identical or different compounds of general formulae Ia and Ib can, optionally, be concatenated by one or several bridges, with a phosphine compound PR3′ and a metal compound of general formula M(L2)2 or M(L2)2 (L1)z, wherein the variables are defined as follows: M is a transition metal of groups 7-10 in the periodic system of the elements; L1 represents phosphanes (R5)xPH3-x or amines (R5)xNH3-x with identical or different radicals R5, ether (R5)2O, H2O, alkohols (R5)OH, pyridine, pyridine derivatives of formula C5H5-x(R5)xN, CO, C1-C12-alkylnitriles, C6-C14-arylnitriles or ethylenically unsaturated double bond systems, wherein x is a whole number ranging from 0-3, L2 represents halogenide ions R6xNH3-x, wherein x is a whole number ranging from 0 3 and R6 represents C1-C12-alkyl, and C1-C6-alkylane ions, allylane ions, benzylane ions or arylane ions, wherein L1 and L2 can be concatenated with each other by one or several covalent bonds, z is a number ranging from 0 4. The invention also relates to the immediate use of the reaction product in the polymerization or copolymerization of olefins in water or in a solvent mixture containing at least 50 vol. % water in the presence of an emulsifier and, optionally, in the presence of an activator.

    7.
    发明专利
    未知

    公开(公告)号：DE59704476D1

    公开(公告)日：2001-10-04

    申请号：DE59704476

    申请日：1997-10-21

    Applicant: BASF AG

    Inventor： JUENGLING STEPHAN ,  GAUSEPOHL HERMANN ,  WEISS HORST ,  BAUMGAERTEL MICHAEL

    IPC: C08F4/46 ,  C08F4/48 ,  C08F4/50

    Abstract: Initiator systems for anionic polymerization of vinyl monomers with polar groups, containing A) a1) at least one starter having general formula R -M or R -M -RC, wherein R , R or R independently stand for branched or straight-chain alkyl radicals of 1-6 carbon atoms, aryl radicals of 6-20 carbon atoms or alkyl radicals with 1-6 carbon atoms carrying at least one phenyl radical and M stands for a metal selected from the group of alkaline metals, and M stands for a metal selected from the group of alkaline earth metals, or a2) as a starter "living" polymer chains, whose chain ends are possibly stabilized by sterically demanding and/or aromatic radicals and B) at least one alkaline (I) or alkaline earth metal alcoholate (II) or at least one alkaline (I) and at least one alkaline earth metal alcoholate (II) which have at least one amino or one phosphino substituent or at least one amino and one phosphino substituent.

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