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公开(公告)号:DE1936790A1
公开(公告)日:1971-02-18
申请号:DE1936790
申请日:1969-07-19
Applicant: BASF AG
Inventor: PRIEBE EDMUND DR , BURGER HEINZ DR , WEBER HEINZ DR , HIRSCH GUENTER DR , SCHULLER HELMUT DR , TRIESCHMANN HANS-GEORG PROF DR , WILLERSINN HERBERT DR
Abstract: (Co)polymerisation of styrene or mixtures thereof with 50% or less of comonomer(s) is carried out in suspension, in presence of a foaming agent and a suspension agent and 0.01 to 0.3%, with respect to weight of monomer(s) of a polysiloxane. The (co)polymer obtained may be coated with an emulsifier. Addition of the polysiloxane results in production of a finely divided polymer having excellent flow characteristics without tendency to agglomeration of the particles. Esp. suitable for prodn. of thin-walled foamed mouldings having homogeneous structure and good mechanical strength.
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公开(公告)号:DE1769475A1
公开(公告)日:1971-09-16
申请号:DE1769475
申请日:1968-05-29
Applicant: BASF AG
Inventor: STAHNECKER ERHARD DR , BURGER HEINZ DR , GROHMANN JOHANNES DR
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公开(公告)号:DE1769096A1
公开(公告)日:1971-09-23
申请号:DE1769096
申请日:1968-04-03
Applicant: BASF AG
Inventor: STAHNECKER ERHARD DR , BURGER HEINZ DR , GROHMANN JOHANNES DR
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4.
公开(公告)号:DE2133531A1
公开(公告)日:1973-01-25
申请号:DE2133531
申请日:1971-07-06
Applicant: BASF AG
Inventor: ZUERN LUDWIG DR , STAHNECKER ERHARD DR , BURGER HEINZ DR , RAPPOLD KURT DR
Abstract: The polymers consist of polystyrene, polymeric mixts. of styrene (K value 54-72 pref. 63-70) plus propane (0.05-3 pref. 0.1-0.6 wt.%) as propellant and 7-15C (pref. 7-10C) (cyclo) aliphatic hydrocarbons (0.1-7.0 pref. 0.3-6.0 wt.%) e.g. isooctane. The polymeric mixt. pref. consists of alpha-methyl styrene, (meth) acrylonitrile, 1-8C alcoholic esters of (meth) acrylic or fumaric acids N-vinyl cpds. or e.g. divinyl benzene (0.001-1.0 pref. 0.01-0.1 wt.%). The polymers are frothed by steam or heated gases deposited for 24 hrs. at room temp. compressed in a perforated form and refrothed by superheated steam through the perforations. The prod. (particle diam. 0.1-6 pref. 0.4-5mm) is used in pearl, granular etc. form, in the mfre. of polystyrene foaming plastics with reduced contraction (=1%).
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公开(公告)号:DE1669746A1
公开(公告)日:1971-07-01
申请号:DE1669746
申请日:1967-11-29
Applicant: BASF AG
Inventor: MOELLER ROLF DR , BURGER HEINZ DR , POHLEMANN HEINZ DR , STANGER BERND DR , DISTLER HARRY DR
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