-
公开(公告)号:DE19514146A1
公开(公告)日:1996-10-17
申请号:DE19514146
申请日:1995-04-15
Applicant: BASF AG
Inventor: DINGERDISSEN UWE DR , LAUTH GUENTER DR , STEUERLE ULRICH DR
IPC: B01J23/02 , B01J23/10 , B01J27/18 , B01J31/04 , C07D203/08 , B01J27/182 , C07D203/10 , C07D203/12
Abstract: A cup catalyst consisting of a glass substrate, the pores of which have a diameter of at least 10 nm and on which there is a catalytically active layer containing compounds of elements from the alkaline metal, alkali metal earth and/or lanthanide group of the periodic system and process for producing aziridines, preferably ethylene imine, by the intramolecular catalytic dehydration of alkanol amines, preferably ethanol amine, in the gas phase at temperatures of at least 250 DEG C on the above-described cup catalysts and isolation of the aziridines from the reaction mixture.
-
公开(公告)号:DE19505037A1
公开(公告)日:1996-08-22
申请号:DE19505037
申请日:1995-02-15
Applicant: BASF AG
Inventor: BURKHART BERND DR , LAUTH GUENTER DR , OFTRING ALFRED DR
IPC: A61K8/19 , A61K8/26 , A61K8/39 , A61Q19/00 , B01J23/00 , B01J27/232 , B01J27/28 , C07B41/02 , C07B41/04 , C07C41/03 , C07C43/13
Abstract: An alkoxylation process comprises reacting cpds. contg. active H atoms with 2-4C alkylene oxides in the presence of an additive-modified mixed metal hydroxide catalyst; diluting the reaction mixt. with 1-50 wt.% water; and filtering off the agglomerated catalyst. The hydroxide is of formula (M1-xM'x(OH)2)Ax/n.mL (I) or (LiAl2(OH)6)a1/n.mL (II), where M = divalent metal ion(s), M' = trivalent metal ion(s), A = n-valent inorganic ion(s), L = water or organic solvent, x = 0.1-0.6, and m = 0-10.
-
公开(公告)号:DE4431093A1
公开(公告)日:1996-03-07
申请号:DE4431093
申请日:1994-09-01
Applicant: BASF AG
Inventor: DINGERDISSEN UWE DR , LAUTH GUENTER DR , HENNE ANDREAS DR , STOPS PETER , ELLER KARSTEN DR , GEHRER EUGEN DR
IPC: B01J27/18 , B01J27/182 , B01J27/185 , B01J27/188 , C07B61/00 , C07C209/60 , C07C211/03 , C07C211/05 , C07C211/06 , C07C211/07 , C07C211/08 , C07C211/35 , B01J21/08 , B01J21/12
Abstract: Preparation of amines of formula (I) comprises reaction of olefins of formula (II) with ammonia or prim. or sec. amines of formula (III) in the presence of a microporous, X-ray amorphous catalyst of formula (IV) having a specific BET surface area of 200-1000 sq.m/g, at 200-400 degrees C and 1-700 bar pressure. Catalyst has the compsn. aMO2.bQ2O3.cP2O5 (IV). R1-R5 = H, 1-20C alkyl or cycloalkyl, 4-20C alkyl-cycloalkyl, 4-20C cycloalkyl-alkyl, aryl, 7-20C alkylaryl, 7-20C aralkyl or heterocyclic; Q = Al, B, Cr, Fe or Ga; M = Si, Ti or Ge; a, b = 0.5:1 to 1,000-1; and c = 0 to 2:1.
-
公开(公告)号:DE4409310A1
公开(公告)日:1995-09-21
申请号:DE4409310
申请日:1994-03-18
Applicant: BASF AG
Inventor: DINGERDISSEN UWE DR , LAUTH GUENTER DR , HARTH KLAUS DR , STEUERLE ULRICH DR
IPC: C07D203/08 , B01J23/02 , B01J23/10 , B01J27/18 , B01J35/04 , B01J37/02 , B01J37/34 , C07D203/02 , C07D203/10 , C07D203/12 , C23C14/06 , C23C14/34
Abstract: The invention concerns a shell-type catalyst comprising a metallic carrier material and a catalytically active layer which adheres firmly thereto, which contains elements of the alkali, alkaline earth and/or lanthanide group of the periodic system of elements and which can be obtained by physical or chemical vapour deposition on the carrier material. The invention further concerns the use of shell-type catalysts and a process for preparing aziridines by the catalytic intramolecular splitting off of water in the gaseous phase from compounds of formula (I), in which R , R , R , R and R , independently of one another, signify H or C1 - C4 alkyl and R additionally stands for cyclohexyl, phenyl, benzyl, C1 - C8 hydroxyalkyl or C1 - C8 aminoalkyl.
-
公开(公告)号:DE4325237A1
公开(公告)日:1995-02-02
申请号:DE4325237
申请日:1993-07-28
Applicant: BASF AG
Inventor: WOLF GERHARD DR , BURKHART BERND DR , LAUTH GUENTER DR , TRAPP HORST DR , OFTRING ALFRED DR
IPC: C01B13/14 , B01J27/232 , C01F7/00 , C01F7/04 , C01F7/16 , C01F7/76 , C01G9/00 , C07B61/00 , C07C41/02 , C07C41/03 , C07C43/11 , B01J31/26 , C01G1/00 , C07B41/04
Abstract: PCT No. PCT/EP94/02195 Sec. 371 Date Jan. 29, 1996 Sec. 102(e) Date Jan. 29, 1996 PCT Filed Jul. 5, 1994 PCT Pub. No. WO95/04024 PCT Pub. Date Feb. 9, 1995Alkoxylation products are prepared by reacting compounds having active hydrogen atoms with C2-C4-alkylene oxides in the presence of a mixed hydroxide built up of polycations and modified with additives and having the general formula I or II[M(II)1-xM(III)x(OH)2]Ax/nxm L(I)[LiAl2(OH)6]A1/nxm L(II)where M(II) is at least one divalent metal ion, M(III) is at least one trivalent metal ion, A is at least one inorganic anion and L is an organic solvent or water, n is the valence of the inorganic anion A or in the case of a plurality of anions A is their mean valence and x can assume a value of from 0.1 to 0.5 and m can assume a value of from 0 to 10, as alkoxylation catalyst, wherein the mixed hydroxide contains additives.
-
公开(公告)号:DE4207745A1
公开(公告)日:1993-09-16
申请号:DE4207745
申请日:1992-03-11
Applicant: BASF AG
Inventor: LAUTH GUENTER DR , HOELDERICH WOLFGANG DR , WAGENBLAST GERHARD DR , ALBERT BERNHARD DR , LAMM GUNTHER DR , REICHELT HELMUT DR , GRUND CLEMENS DR , GRUETTNER-MERTEN SABINE DR
IPC: C01B25/36 , C01B25/45 , C01B33/26 , C01B37/04 , C01B37/06 , C01B37/08 , C01B39/00 , C01B39/02 , C09B63/00 , C09D7/00
Abstract: Crystalline molecular sieves containing one or more chromophores of the mono or polyazo dye class having no acid groups, and their use as colorants.
-
公开(公告)号:DE59201967D1
公开(公告)日:1995-05-24
申请号:DE59201967
申请日:1992-09-04
Applicant: BASF AG
Inventor: MUELLER ULRICH DR , HOELDERICH WOLFGANG DR , LAUTH GUENTER DR
Abstract: Process for the preparation of alumino- and silicoaluminophosphates having AEL structure under hydrothermal crystallisation conditions, characterised in that 1,2-bis(4-pyridyl)ethane is used for crystallisation.
-
公开(公告)号:DE4221011A1
公开(公告)日:1994-01-05
申请号:DE4221011
申请日:1992-06-26
Applicant: BASF AG
Inventor: LAUTH GUENTER DR , HOELDERICH WOLFGANG PROF DR , HARTH KLAUS DR , HIBST HARTMUT DR
IPC: B01J23/38 , B01J23/42 , B01J23/44 , B01J23/70 , B01J23/72 , B01J25/00 , B01J37/02 , B01J37/34 , B01J35/10
Abstract: Shell-coated catalyst, prepared by deposition of an alloy by means of physical vapour deposition and/or by chemical vapour deposition on a shaped body, at least one alloy component being a metal of the group comprising aluminium, gallium, silicon, germanium, tin, lead, bismuth, yttrium, titanium, zirconium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, iron, cobalt, ruthenium, rhodium, palladium, osmium, iridium, platinum, copper, silver, gold and zinc.
-
公开(公告)号:DE4207339A1
公开(公告)日:1993-09-16
申请号:DE4207339
申请日:1992-03-09
Applicant: BASF AG
Abstract: Crystalline molecular sieves containing one or more chromophores of the indigoid class and their use as colorants.
-
公开(公告)号:DE4423975A1
公开(公告)日:1996-01-11
申请号:DE4423975
申请日:1994-07-07
Applicant: BASF AG
Inventor: HAGEMEYER ALFRED DR , LAUTH GUENTER DR , LAUTENSACK THOMAS , DEIMLING AXEL DR
IPC: B01J23/18 , B01J23/92 , C07B61/00 , C07C5/42 , C07C11/02 , C07C15/40 , C07C15/46 , B01J23/22 , B01J23/10 , C07B35/04 , C07C11/00
Abstract: Process for the catalytically oxidative dehydrogenation of alkyl aromatics or paraffin hydrocarbons to the corresponding alkenyl aromatics or olefins by means of a redox catalyst (oxygen vehicle) in which in a first reaction stage the alkyl aromatic or paraffin hydrocarbon (educt) is dehydrogenated on a titanium dioxide carrier in the absence of molecular oxygen with a catalyst of a reducible metal oxide selected from the oxides of Bi, V, Ce, Fe, In, Ag, Cu, Co, Mn, Pb, Sn, Mo, Sb, As, W or their mixtures, whereby the catalyst is reduced, and in a second reaction stage the reduced catalyst is reoxidised by an oxidising agent.
-
-
-
-
-
-
-
-
-