公开(公告)号：JPH1045826A

公开(公告)日：1998-02-17

申请号：JP10026797

申请日：1997-04-17

Applicant: BASF AG

Inventor： EBEL KLAUS DR ,  HAEHNLE HANS-JOACHIM DR

IPC: C07C233/03 ,  C08F8/00 ,  C08F8/12 ,  C08F20/42

Abstract: PROBLEM TO BE SOLVED: To obtain a polymer capable of industrially, simply and inexpensively producing a polyamide and a polyamine by carrying out catalytic reaction of a nitrile-containing polymer. SOLUTION: A nitrile containing polymer (preferably acrylonitrile homopolymer or copolymer) is subjected to catalytic reaction in the presence of hydrogen, carbon monoxide and/or carbon monoxidereleasing compound (preferably formic acid or its derivative). Furthermore, a group I metal or group IV to X metal or metal compound in the periodic table, e.g. iron pentacarbonyl is preferably used as the catalyst and a molar ratio of hydrogen to carbon monoxide is preferably (4:1) to (0.25:1) and a molar ratio of carbon monoxide to nitrile group is preferably (1:1) to (1,000:1) and a molar ratio of hydrogen to nitrile group is preferably (2:1) to (1,000:1).

公开(公告)号：JP2002194128A

公开(公告)日：2002-07-10

申请号：JP2001331002

申请日：2001-10-29

Applicant: BASF AG

Inventor： DIETZEN FRANZ-JOSEF ,  HAEHNLE HANS-JOACHIM DR ,  EVSIOUKOV SERGUEI ,  SCHORNICK GUNNAR ,  EHRMANN GERD ,  FUNK RUDIGER

IPC: C08J9/12 ,  A61F13/15 ,  A61L15/42 ,  B29C47/00 ,  B29K23/00 ,  B29K67/00 ,  B29K105/04 ,  C08J9/14 ,  C08J9/36

Abstract: PROBLEM TO BE SOLVED: To develop a flexible open cell foam useful for a liquid absorbing sanitary product, which can be manufactured by a simple process. SOLUTION: The fine pore flexible foam having an open cell is based on an olefin polymer or a thermoplastic polyester. The foam has an open cell content of 40%, preferably higher than 50%, a density of 300 g/L (liter), preferably in the range of 20-200 g/L, and an average cell diameter of less than 0.1 mm, preferably less than 0.08 mm.

公开(公告)号：EP0802205A3

公开(公告)日：1998-11-11

申请号：EP97106077

申请日：1997-04-14

Applicant: BASF AG

Inventor： EBEL KLAUS DR ,  HAEHNLE HANS-JOACHIM DR

IPC: C07C233/03 ,  C08F8/00 ,  C08F8/12 ,  C08F20/42

CPC classification number: C08F8/04 ,  C08F120/44 ,  C08F8/44 ,  C08F8/12

Abstract: Polymere, die N-substituierte Formamidstruktureinheiten enthalten, erhältlich durch katalytische Umsetzung von nitrilgruppenhaltigen Polymeren in Gegenwart von Wasserstoff, Kohlenmonoxid und/oder kohlenmonoxidfreisetzenden Verbindungen.

Abstract translation: 含有N-取代的甲酰胺结构单元的聚合物，可通过含氢聚合物在氢气，一氧化碳和/或一氧化碳释放化合物存在下的催化反应获得。

公开(公告)号：DE19642761A1

公开(公告)日：1998-04-23

申请号：DE19642761

申请日：1996-10-16

Applicant: BASF AG

Inventor： KRONER MATTHIAS DR ,  HAEHNLE HANS-JOACHIM DR ,  RUEBENACKER MARTIN DR

IPC: C08J3/075 ,  C08J5/14 ,  C08K3/00 ,  C08K3/01 ,  C09D17/00 ,  C08L101/14 ,  C08J5/00 ,  C08K3/22 ,  C08K5/09 ,  C08K13/02 ,  C08L1/08 ,  C08L3/04 ,  C08L89/00 ,  C09K3/14 ,  C10M107/28

Abstract: The present invention relates to composite materials made of inorganic minerals and polymer gels and the application thereof.

公开(公告)号：DE19615485A1

公开(公告)日：1997-10-23

申请号：DE19615485

申请日：1996-04-19

Applicant: BASF AG

Inventor： EBEL KLAUS DR ,  HAEHNLE HANS-JOACHIM DR

IPC: C07C233/03 ,  C08F8/00 ,  C08F8/12 ,  C08F20/42

Abstract: Production of polymers comprise N-substituted formamide structural units comprises catalytic reaction of nitrile group-containing polymers in the presence of hydrogen, carbon monoxide and/or carbon monoxide releasing compounds. Also claimed is a process for the production of polyamines by hydrolysis of the above polymers.

公开(公告)号：DE19540951A1

公开(公告)日：1997-05-07

申请号：DE19540951

申请日：1995-11-03

Applicant: BASF AG

Inventor： HAEHNLE HANS-JOACHIM DR ,  WALTER MANFRED DR ,  TROPSCH JUERGEN DR ,  SCHORNICK GUNNAR DR ,  ANSTOCK THOMAS DR

IPC: A61L15/00 ,  A61L15/42 ,  A61L15/60 ,  C08F2/16 ,  C08F220/06 ,  C08J9/30 ,  C08L33/02 ,  C08F265/02 ,  A61L15/24 ,  B01J20/26 ,  C08F265/10 ,  C08F267/02 ,  C08F273/00 ,  C08L35/00 ,  C09K3/10 ,  C09K3/32

Abstract: The invention concerns water-absorbent cellular crosslinked-polymer materials produced by (I) foaming a polymerizable aqueous mixture containing: (a) acid-group-containing monoethylenically unsaturated monomers which have been neutralized to at least 50 mol %; (b) optionally, other monoethylenically unsaturated monomers; (c) crosslinking agents; (d) initiators; (e) 0.1 to 20 % by wt. of at least one surfactant; (f) optionally, at least one solubilizer and (g) optionally, thickeners, foam stabilizers, polymerization-control agents, fillers and/or cell-nucleation agents, the foaming being carried out by dispersing throughout the mixture fine bubbles of a gas which is inert to radicals, and (II) polymerizing the foamed mixture to form a cellular hydrogel and adjusting the water content of the cellular hydrogel to 1 to 45 % by wt. The invention also concerns methods of producing such polymer materials and their use in personal-hygiene articles used to absorb body fluids and in bandage material used to cover injuries.

公开(公告)号：AT142374T

公开(公告)日：1996-09-15

申请号：AT92107609

申请日：1992-05-06

Applicant: BASF AG

Inventor： SCHREPP WOLFGANG DR ,  HAEHNLE HANS-JOACHIM DR ,  GRUNZE MICHAEL PROF DR

IPC: C01G1/00 ,  C01G3/00 ,  C04B41/83 ,  C08G73/10 ,  H01B3/30 ,  H01B12/02 ,  H01B13/00 ,  H01L39/24

Abstract: In a method of making thin polyimide protection layers on ceramic superconductors or high-temperature superconductors, the polyimide acids or their precursors on which the polyimide is based are applied to the superconductor or high-temperature superconductor surface and imidised. Drying or imidisation is carried out in an oxidising atmosphere.

公开(公告)号：DE4115872A1

公开(公告)日：1992-11-19

申请号：DE4115872

申请日：1991-05-15

Applicant: BASF AG

Inventor： SCHREPP WOLFGANG DR ,  HAEHNLE HANS-JOACHIM DR ,  GRUNZE MICHAEL PROF DR

IPC: C01G1/00 ,  C01G3/00 ,  C04B41/83 ,  C08G73/10 ,  H01B3/30 ,  H01B12/02 ,  H01B13/00 ,  H01L39/24

Abstract: In a method of making thin polyimide protection layers on ceramic superconductors or high-temperature superconductors, the polyimide acids or their precursors on which the polyimide is based are applied to the superconductor or high-temperature superconductor surface and imidised. Drying or imidisation is carried out in an oxidising atmosphere.

公开(公告)号：DE59600721D1

公开(公告)日：1998-12-03

申请号：DE59600721

申请日：1996-01-23

Applicant: BASF AG

Inventor： HAEHNLE HANS-JOACHIM DR ,  NEUFELD ECKHARD ,  SCHORNICK GUNNAR DR ,  MINGES ROLAND DR ,  ANSTOCK THOMAS DR ,  TROPSCH JUERGEN DR ,  KRAUSS HANS-JUERGEN

IPC: B01D21/01 ,  B01J19/00 ,  B01J19/24 ,  C02F1/56 ,  C08F2/00 ,  C08F2/10 ,  C08F2/16 ,  C08F4/04 ,  C08F20/00

Abstract: Prodn. of high mol. polymers involves: (a) polymerising water-soluble, mono-ethylenically unsatd. monomers and opt. crosslinkers contg. non-conjugated ethylenically unsatd. double bonds. in the molecule and opt. water-insol. monoethylenically unsatd. monomers in aq. soln. in the presence of polymerisation initiators in a tubular reactor; and (b) forcing the gelatinous reaction mixt. from the reactor with an inert gas. The reactor has: (i) a conical taper at one end, so the ratio of the dia. (D1) of the reactor to the dia. (D2) at the end of the cone is (2-25); and (ii) the angle between D1 at the beginning of the cone and the inner wall of the cone of more than 45 and less than 90 degrees .

公开(公告)号：DE19607529A1

公开(公告)日：1997-09-04

申请号：DE19607529

申请日：1996-02-28

Applicant: BASF AG

Inventor： HAEHNLE HANS-JOACHIM DR ,  WALTER MANFRED DR ,  TROPSCH JUERGEN DR ,  KREMESKOETTER JENS DR ,  SCHORNICK GUNNAR DR ,  ANSTOCK THOMAS DR

IPC: A61F13/53 ,  A61F5/44 ,  A61F13/15 ,  A61F13/49 ,  A61L15/42 ,  A61L15/60 ,  B32B5/18 ,  C08F220/06 ,  A61L15/24 ,  C08J9/02 ,  C08L23/00

Abstract: The invention concerns absorber elements consisting of at least one composite with absorbent elements on a carrier, the invention being characterized in that on at least one carrier a plurality of elements of a superabsorbent foam are arranged in a grid-like manner at spacings such that the peripheries of the elements touch in the swollen state.