9.
    发明专利
    未知

    公开(公告)号:DE3776624D1

    公开(公告)日:1992-03-19

    申请号:DE3776624

    申请日:1987-10-30

    Applicant: BASF AG

    Abstract: Prodn. of 2,2-disubstd. 3-chloropropionate esters of formula (I) is effected by (a) converting a 2,2-disubstd. 3-hydroxypropanal of formula (II) into an ester diol of formula (III); (b) reacting (III) with an alcohol of formula (IV) in the presence of a transesterification catalyst; and (c) reacting the resulting 2,2-disubstd. 3-hydroxypropionate ester (V) with at least the stoichiometric amt. of SOCl2: R1 and R2 = 1-6C alkyl, 2-6C oxaalkyl, alkenyl, oxaalkenyl, aryl or 7-12C aralkyl, or CR1R2 is a 5- to 7-membered ring; R3 is as defined for R1 and R2 but not aryl.

    10.
    发明专利
    未知

    公开(公告)号:DE3844048A1

    公开(公告)日:1990-07-05

    申请号:DE3844048

    申请日:1988-12-28

    Applicant: BASF AG

    Abstract: The process involves reacting a) organic and/or modified organic polyisocyanates with b) relatively high-molecular-weight compounds containing at least two reactive hydrogen atoms and c) optionally low-molecular-weight chain extenders, in the presence of d) catalysts, e) blowing agents, f) flameproofing agents and optionally g) assistants and/or additives, where the following are used: starting component (b) is a mixture having a mean functionality of from 2 to 4 and a mean molecular weight of from 2,200 to 8,000, and preferably containing: bi) from 40 to 94 parts by weight of at least one polyoxyalkylene polyol having a functionality of from 2 to 4 and a mean molecular weight of from 250 to 8,000, bii) from 3 to 25 parts by weight of at least one polymer-modified polyoxyalkylene polyol having a mean functionality of from 2 to 4 and a mean molecular weight of from 1,200 to 8,000, selected from the group comprising graft polyoxyalkylene polyols, and polyurethane-polyalkylene polyols containing bonded polyurea, polyhydrazide and/or tert.-amino groups, and biii) from 3 to 35 parts by weight of at least one polyoxyalkylene-polyamine having a functionality of from 2 to 4 and a mean molecular weight of from 1,800 to 8,000, and the flameproofing agent (f) is melamine or a mixture of melamine and other flameproofing agents.

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