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    PRODUCTION OF N-SUBSTITUTED CYCLIC AMINE
    1.
    发明专利
    PRODUCTION OF N-SUBSTITUTED CYCLIC AMINE 失效

    公开(公告)号：JPH1072454A

    公开(公告)日：1998-03-17

    申请号：JP15828297

    申请日：1997-06-16

    Applicant: BASF AG

    Inventor： SIMON JOACHIM DR ,  DOSTALEK ROMAN DR ,  LINGK HEINZ ,  BECKER RAINER DR ,  HENNE ANDREAS DR ,  ROLF REEPUKYUUHIYAA ,  FREIRE ERDBRUEGGER CRISTINA DR ,  HESSE MICHAEL DR ,  KRATZ DETLEF DR

    IPC: C07D295/02 ,  B01J23/72 ,  B01J37/02 ,  C07B61/00 ,  C07D295/03

    Abstract: PROBLEM TO BE SOLVED: To enable to industrially simply and profitably obtain the subject compound from a primary amine and a diol by using a specific copper- containing hydrogenation/dehydrogenation catalyst. SOLUTION: This method for producing an N-substituted cyclic amine of formula I comprises reacting (C) a compound of the formula: R -NH2 [R is an (alkoxy)alkyl, an aryl, etc.,] with (D) a compound of the formula: HO-A-OH A is an alkylene (substituted by a group of the formula: R (R is R ), a group of the formula: (CH2 )n -[O-(CH )m ]r , [(m), (n) are each 2-8; (r) is 1-3]} in the presence of a coppercontaining catalyst. The copper-containing catalyst is obtained by impregnating an inactive carrier (e.g. silicon dioxide, a silicate or zeolite) with (A) hydrogen and (B) the aqueous ammine complex solution of an easily pyrolytic copper compound (e.g. copper carbonate, copper oxalate or copper formate)(preferably an ammoniacal copper carbonate solution), drying the impregnated carrier, and subsequently calcining the dried product, and contains the copper in an amount of 5-50wt.% converted into CuO on the basis of the whole amount of the calcined catalyst.

    PRODUCTION OF ANHYDROUS 2-AMINO-1-METHOXYPROPANE
    2.
    发明专利
    PRODUCTION OF ANHYDROUS 2-AMINO-1-METHOXYPROPANE 失效

    公开(公告)号：JPH1149733A

    公开(公告)日：1999-02-23

    申请号：JP14725298

    申请日：1998-05-28

    Applicant: BASF AG

    Inventor： SIMON JOACHIM ,  HENNE ANDREAS ,  LINGK HEINZ

    IPC: C07C213/02 ,  C07C213/10 ,  C07C217/08

    Abstract: PROBLEM TO BE SOLVED: To provide a method for producing anhydrous 2-amino-1- methoxypropane, capable of obtaining a desired product in high yield. SOLUTION: (a) Two phases comprising a reaction mixture and sodium hydroxide solution, obtained by reaction of 1-methoxy-2-propanol with ammonia on a catalyst are formed and (b) 2-amino-1-methoxypropane-containing phase is separated from water phase and (c) 2-amino-1-methoxypropane-containing phase is subjected to azeotropic distillation to produce an azeotropic mixture at first and the azeotropic mixture is returned to a process (a) or (b), and then, anhydrous 2-amino-1-methoxypropane is produced.

    4.
    发明专利
    未知

    公开(公告)号：ES2136225T3

    公开(公告)日：1999-11-16

    申请号：ES95109869

    申请日：1995-06-24

    Applicant: BASF AG

    Inventor： REIF WOLFGANG DR ,  HESSE MICHAEL DR ,  ZIMMERMANN HORST DR ,  LINGK HEINZ

    IPC: B01J23/72 ,  B01J23/76 ,  C07C209/48 ,  C07C209/60 ,  C07C211/09

    Abstract: A catalyst (C) consisting of 85-100 wt.% copper oxide and zirconium oxide and 15-0 wt.% metal oxides of groups Ib to VIIb and VIII of the Periodic Table is new. Also claimed is the prepn. of amines by reaction of nitrile with ammonia, or prim. or sec. amine at 80-250 degrees C and 1-400 bar with hydrogen and a catalyst (C). Pref. prepn. of NR1R2-CH2R3 (I) comprises reaction of R3CN with NHR1R2. R1, R2 = H, 1-20C alkyl, 3-12C cycloalkyl, aryl, 7-20C aralkyl, 7-20C alkylaryl; R3 = 1-200C alkyl, 3-12C cycloalkyl, 1-20C alkyl (substd. with NH2, NHMe, NMe2 and/or OH), 2-30C alkoxyalkyl, (CH2-CHR5-O)nR4, aryl, 7-20C aralkyl or 7-20C alkylaryl; n = 2-30; R4 = H, 1-4C alkyl; R5 = H or Me.

    5.
    发明专利
    未知

    公开(公告)号：DE19722700A1

    公开(公告)日：1998-12-03

    申请号：DE19722700

    申请日：1997-05-30

    Applicant: BASF AG

    Inventor： SIMON JOACHIM ,  HENNE ANDREAS ,  LINGK HEINZ

    IPC: C07C213/02 ,  C07C213/10 ,  C07C217/08 ,  B01J23/885

    Abstract: Production of anhydrous 2-amino-1-methoxypropane (I) comprises (a) treating an aqueous reaction mixture (II) containing (I), obtained by reacting 1-methoxy-2-propanol with ammonia (NH3) on a catalyst, with aqueous sodium hydroxide (NaOH) solution to form an aqueous phase containing aqueous NaOH solution and a phase containing (I); (b) separating the phase (III) containing (I) from the aqueous phase; and (c) distilling (III) to separate an azeotrope of water and (I), which is recycled to step (a) or (b), and then anhydrous (I). Also claimed is a method of separating water from (II) in this way.

    7.
    发明专利
    未知

    公开(公告)号：ES2150805T3

    公开(公告)日：2000-12-01

    申请号：ES98109538

    申请日：1998-05-26

    Applicant: BASF AG

    Inventor： SIMON JOACHIM ,  HENNE ANDREAS ,  LINGK HEINZ

    IPC: C07C213/02 ,  C07C213/10 ,  C07C217/08

    Abstract: Production of anhydrous 2-amino-1-methoxypropane (I) comprises (a) treating an aqueous reaction mixture (II) containing (I), obtained by reacting 1-methoxy-2-propanol with ammonia (NH3) on a catalyst, with aqueous sodium hydroxide (NaOH) solution to form an aqueous phase containing aqueous NaOH solution and a phase containing (I); (b) separating the phase (III) containing (I) from the aqueous phase; and (c) distilling (III) to separate an azeotrope of water and (I), which is recycled to step (a) or (b), and then anhydrous (I). Also claimed is a method of separating water from (II) in this way.

    8.
    发明专利
    未知

    公开(公告)号：DE59800237D1

    公开(公告)日：2000-09-21

    申请号：DE59800237

    申请日：1998-05-26

    Applicant: BASF AG

    Inventor： SIMON JOACHIM ,  HENNE ANDREAS ,  LINGK HEINZ

    IPC: C07C213/02 ,  C07C213/10 ,  C07C217/08

    Abstract: Production of anhydrous 2-amino-1-methoxypropane (I) comprises (a) treating an aqueous reaction mixture (II) containing (I), obtained by reacting 1-methoxy-2-propanol with ammonia (NH3) on a catalyst, with aqueous sodium hydroxide (NaOH) solution to form an aqueous phase containing aqueous NaOH solution and a phase containing (I); (b) separating the phase (III) containing (I) from the aqueous phase; and (c) distilling (III) to separate an azeotrope of water and (I), which is recycled to step (a) or (b), and then anhydrous (I). Also claimed is a method of separating water from (II) in this way.

    9.
    发明专利
    未知

    公开(公告)号：DE59506673D1

    公开(公告)日：1999-09-30

    申请号：DE59506673

    申请日：1995-06-24

    Applicant: BASF AG

    Inventor： REIF WOLFGANG ,  HESSE MICHAEL ,  ZIMMERMANN HORST ,  LINGK HEINZ

    IPC: B01J23/72 ,  B01J23/76 ,  C07C209/48 ,  C07C209/60 ,  C07C211/09

    Abstract: A catalyst (C) consisting of 85-100 wt.% copper oxide and zirconium oxide and 15-0 wt.% metal oxides of groups Ib to VIIb and VIII of the Periodic Table is new. Also claimed is the prepn. of amines by reaction of nitrile with ammonia, or prim. or sec. amine at 80-250 degrees C and 1-400 bar with hydrogen and a catalyst (C). Pref. prepn. of NR1R2-CH2R3 (I) comprises reaction of R3CN with NHR1R2. R1, R2 = H, 1-20C alkyl, 3-12C cycloalkyl, aryl, 7-20C aralkyl, 7-20C alkylaryl; R3 = 1-200C alkyl, 3-12C cycloalkyl, 1-20C alkyl (substd. with NH2, NHMe, NMe2 and/or OH), 2-30C alkoxyalkyl, (CH2-CHR5-O)nR4, aryl, 7-20C aralkyl or 7-20C alkylaryl; n = 2-30; R4 = H, 1-4C alkyl; R5 = H or Me.

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