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公开(公告)号:DE19743432A1
公开(公告)日:1999-04-08
申请号:DE19743432
申请日:1997-10-01
Applicant: BASF AG
Inventor: HUFF JUERGEN DR , LUX JUERGEN ALFRED DR , SCHUERMANN GREGOR DR
IPC: C08F26/06 , C08F226/06
Abstract: The invention relates to a method for producing anionically modified polymerizates of alkyl-1-vinyl-imidazoles by radically polymerizing alkyl-1-vinyl-imidazoles with anionic monoethylenically unsaturated monomers and optionally, other copolymerisable monomers, in an aqueous solvent, without using polymerisation regulators.
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公开(公告)号:DE19621983A1
公开(公告)日:1997-12-04
申请号:DE19621983
申请日:1996-06-03
Applicant: BASF AG
Inventor: HUFF JUERGEN DR , JAEGER HANS-ULRICH DR , KAHMEN MARTIN AUS DEM DR , KRONER MATTHIAS DR , LUX JUERGEN ALFRED DR , OETTER GUENTER DR
IPC: C08F210/00 , C11D3/37 , C08F212/08 , C08F218/04 , C08F220/04 , C08F220/10 , C08F220/20 , C08F222/10
Abstract: The invention concerns the use of copolymers obtainable by the radical polymerisation of (a) 10 to 90 wt% hydrophobic monomers and (b) 90 to 10 wt% hydrophilic monomers as an additive to particulate detergent formulations to increase their rate of dissolution in water, in quantities of 0.1 to 10 wt% in relation to the detergent formulations.
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公开(公告)号:DE19646437A1
公开(公告)日:1998-05-14
申请号:DE19646437
申请日:1996-11-11
Applicant: BASF AG
Inventor: BOECKH DIETER DR , JAEGER HANS-ULRICH DR , LUX JUERGEN ALFRED DR , STEIN STEFAN DR , DETERING JUERGEN DR , SCHADE CHRISTIAN DR
IPC: C08F226/06 , C11D3/00 , C11D3/37 , D06P1/52 , D06P5/08 , D06M15/356
Abstract: The use of polymerizates, containing at least 5 mol % quaternized 1-vinyl-imidazol units of formula (I) wherein R = C1-C25 alkyl, C5-C10 cycloalkyl or benzyl, R , R , R are the same or different, mean H, CH3 and C2H5 and X is an anion, as a colour fixing and colour transfer inhibiting additive to detergent post-treatment agents and detergents.
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公开(公告)号:DE19643281A1
公开(公告)日:1998-04-23
申请号:DE19643281
申请日:1996-10-21
Applicant: BASF AG
Inventor: BOECKH DIETER DR , JAEGER HANS-ULRICH DR , LUX JUERGEN ALFRED DR
Abstract: The use of polycationic condensation products which can be obtained by condensing (a) piperazine, 1-alkyl piperazines with 1-25 C atoms in the alkyl group, 1,4 dialkyl piperazines with 1-25 C atoms in the alkyl group, 1,4-bis -(3-aminopropyl) -piperazine, 1-(2-aminoethyl)piperazine, 1-(2-hydroxyalkyl)piperazines with 2-25 C atoms in the alkyl group, imidazole, C1-C25 - alkyl imidazoles or mixtures of cited compounds with (b) alkyl dihalogenides, epihalogenohydrines and/or bis-epoxides in a molar ratio 1 : 0.8 - 1 : 1.1 and possibly quaternization of condensation products with C4-C25 alkylation agents or by heating triethanolamine or triisopropanolamine in the presence of acid catalysts and quaternization of condensation products with C4-C25 alkylation agents as colour fixing agents for detergents and detergent after-treatment agents. Also disclosed are detergents containing i) at least 1-50 wt % of a non ionic tenside ii) 0 - 4.0 wt % of an ionic tenside and iii) 0.05 - 2.5 wt % of polycationic condensation products in the form of an additive inhibiting the running of colours and reducing colour loss, and detergent after-treatment agents containing a fabric softener, a non ionic tenside and O.1 - 2.5 wt % of cited polycationic condensation products.
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公开(公告)号:DE19740112A1
公开(公告)日:1999-03-18
申请号:DE19740112
申请日:1997-09-12
Applicant: BASF AG
Inventor: PAPKALLA THOMAS DR , LUX JUERGEN ALFRED DR , EBEL KLAUS DR
Abstract: In the production of polycarboxylic acids (I), crosslinked polysaccharides (II) are used for oxidation with gaseous nitrogen dioxide/dinitrogen tetroxide in a fluidized bed at 30-150 deg C, in which at least some of the hydroxyl groups of (II) are converted to carboxyl groups and then optionally (partly) neutralized.
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公开(公告)号:DE19643133A1
公开(公告)日:1998-04-23
申请号:DE19643133
申请日:1996-10-18
Applicant: BASF AG
Inventor: MEIXNER HUBERT DR , STEUERLE ULRICH DR , DECKER JUERGEN DR , PAULUS WOLFGANG DR , BOECKH DIETER DR , LUX JUERGEN ALFRED DR , EHLE BEATE DR
Abstract: The invention concerns the use of water-soluble or water-dispersible cross-linked nitrogenated compounds obtained by crosslinking (a) compounds containing at least three NH groups with (b) at least bifunctional crosslinking agents which react with NH groups, in washing and cleaning agents, in particular as soil-release agents. Preferably, the compounds (a) are selected from the group comprising oligo- and polyamines, polyalkylene polyamines, polyamidoamines, polyamidoamines grafted with (poly)ethyleneimine and mixtures thereof.
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公开(公告)号:DE19649150A1
公开(公告)日:1998-05-28
申请号:DE19649150
申请日:1996-11-27
Applicant: BASF AG
Inventor: KAHMEN MARTIN AUS DEM DR , HUFF JUERGEN DR , LUX JUERGEN ALFRED DR , JAEGER HANS-ULRICH DR
Abstract: Additives for increasing the solubility of washing powder formulations in water, added in amounts of 0.1-10 wt.%, comprise crosslinked alkoxylated alcohols prepared either by alkoxylating an alcohol with ethylene oxide (EO) and optionally propylene oxide (PO) and/or butylene oxide (BO) and then cross-linking the alkoxylated alcohol with an at least bifunctional crosslinking agent. Preferably reaction products of polyalkylene glycols with 2-6C alkylene glycol bisglycidyl ethers, or reaction products of polyethylene glycols having a weight average molecular weight of 100-2500 with a butane-1,4-diol glycidyl ether are used. The alkoxylation reaction products are addition reaction products of 1-100 moles EO, 0-30 moles PO and 0-10 moles BO with 1 mole of 1-22C alcohol. The amount of additive added is 0.5-5 wt.%. The washing powders have bulk weights of 550-1000 (at least 700) g/l.
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公开(公告)号:DE19648504A1
公开(公告)日:1998-05-28
申请号:DE19648504
申请日:1996-11-22
Applicant: BASF AG
Inventor: KAHMEN MARTIN AUS DEM DR , JAEGER HANS-ULRICH DR , LUX JUERGEN ALFRED DR , HUFF JUERGEN DR
IPC: C08G65/26 , C08G65/28 , C08G65/332 , C11D3/37 , C08G65/32
Abstract: Additives for increasing the solubility of washing powder formulations in water, added in amounts of 0.1-10 wt.%, comprise hydrophobic alkoxylated alcohols with a functionality of at least 3. The alcohols are prepared either by (i) alkoxylating an at least trivalent alcohol with ethylene oxide (EO) and/or propylene oxide (PO) and then rendering the alkoxylated alcohol hydrophobic by reacting it with a 4-32C epoxide and/or styrene oxide, 1-20C alkylating agent or 1-5C fatty acid, or (ii) reacting the alcohol with a 4-32C epoxide or styrene oxide and then alkoxylating the reaction product with EO and/or PO.
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公开(公告)号:DE19611977A1
公开(公告)日:1997-10-02
申请号:DE19611977
申请日:1996-03-26
Applicant: BASF AG
Inventor: HUFF JUERGEN DR , STEUERLE ULRICH DR , MEIXNER HUBERT DR , EHLE BEATE DR , PAULUS WOLFGANG DR , LUX JUERGEN ALFRED DR , HAEUSLING LUKAS DR
Abstract: The use of an amine with an average pKs of 1 to 14 as a washing power enhancer, preferably in textile detergents, especially for washing coloureds, and detergent formulations containing said amines.
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公开(公告)号:DE19805232A1
公开(公告)日:1999-08-12
申请号:DE19805232
申请日:1998-02-10
Applicant: BASF AG
Inventor: HUFF JUERGEN DR , BLANKENBURG RAINER DR , LEHMANN STEPHAN DR , EHLE BEATE DR , BERTLEFF WERNER DR , LUX JUERGEN ALFRED DR
Abstract: The invention relates to the use of copolymers consisting of (a) between 10 and 95 weight % of at least one non-ionic monomer which has a N-vinyl group and at 25 DEG C has a water solubility of at least 60 g/l, (b) between 5 and 90 weight % of at least one hydrophobic monoethylenically unsaturated monomer which at 25 DEG C has a water solubility of less than 60 g/l, and possibly (c) between 0 and 15 weight % of at least one monoethylenically unsaturated monomer having an ionic or ionisable group and (d) between 0 and 10 weight % of at least one monomer which has at least 2 ethylenically unsaturated groups. Said copolymers are used in detergents, in amounts of between 0.1 and 5 weight % in relation to said detergents, as additive which inhibits greying and promotes dirt removal during washing and as a secondary treatment agent for laundry.
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