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公开(公告)号:DE19739686A1
公开(公告)日:1999-03-11
申请号:DE19739686
申请日:1997-09-10
Applicant: BASF AG
Inventor: WEBER MARTIN DR , MUELHAUPT ROLF PROF DR
Abstract: Thermoplastic molding compositions contain (A) 1-97 wt.% thermoplastic polyester, (B) 1-97 wt.% polycarbonate, (C) 1-40 wt.% elastomer containing oxazoline groups, then a glass transition temperature (Tg) ≤ 0 degrees C, (D) 0.05-5 wt.% bisoxazoline and (E) 0-70 wt.% other additives and processing aids.
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公开(公告)号:DE19757669A1
公开(公告)日:1999-01-07
申请号:DE19757669
申请日:1997-12-23
Applicant: BASF AG
Inventor: RUPANER ROBERT DR , HORN FRANK M , RICHTERING WALTER DR , MUELHAUPT ROLF PROF DR
IPC: C08F2/24 , C08F210/02 , C08F212/08 , C08F214/06 , C08F214/08 , C08F218/04 , C08F220/18 , C08F220/42 , C08F236/06
Abstract: Production of dispersions of mono-disperse copolymer particles with an average particle size (d50) of 0.2-20 mu m and a heterogeneity of
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公开(公告)号:DE59501763D1
公开(公告)日:1998-05-07
申请号:DE59501763
申请日:1995-09-09
Applicant: BASF AG
Inventor: FISCHER DAVID DR , LANGHAUSER FRANZ DR , KERTH JUERGEN DR , SCHWEIER GUENTHER DR , MUELHAUPT ROLF PROF DR , SCHNEIDER MARTIN
Abstract: Oligomers (IA) and polymers (IB) are obtd. from 0.001-100 mole-% amino-alkene(s) of formula (II) and 0-99.999 mole-% alkene(s) (III). In (II): x = 0-25; and R -R = H, 1-10C alkyl, 5-7-membered cycloalkyl, opt. with 1-6C alkyl substits., or 6-15C aryl. When (III) is propene is x does not = 1.
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公开(公告)号:AT189898T
公开(公告)日:2000-03-15
申请号:AT96111813
申请日:1996-07-23
Applicant: BASF AG
Inventor: ROESCH JOACHIM DR , MUELLER HANS-JOACHIM DR , HOEHN ARTHUR DR , MUELHAUPT ROLF PROF DR , WOERNER CHRISTOF
IPC: C08F8/14 , C08F8/30 , C08F8/32 , C08F8/50 , C08F10/00 , C08F110/00 , C08F110/06 , C08G73/00 , C08G81/00 , C08G81/02
Abstract: Polymers and oligomers of formula (I), based on unsatd. 2-10C hydrocarbons and with one or two 2-oxazolinyl terminal gps., in which A = polymer or oligomer residue derived from the unsatd. hydrocarbon (A'), and R = H, 1-10C alkyl, 6-10C aryl or 3-6C cycloalkyl. Also claimed are (i) comb polymers (II) obtd. by cationic ring-opening homo- or co-polymerisation of (I); (ii) comb polymers (III) obtd. by reacting (I) with base polymers contg. reactive gps.; (iii) thermoplastic moulding materials or thermosets contg. (I), (II) or (III) or mixts. thereof; (iv) a process for the prodn. of (I) by polymerisation or oligomerisation of (A'), modification with one or two terminal ester gps., and Lewis acid-catalysed ring closure with 2-amino-1- alcohols; (v) processes for the prodn. of (II) and (III) under the above conditions; (vi) films, fibres and mouldings obtd. from the materials claimed in (iii).
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公开(公告)号:DE19802335A1
公开(公告)日:1999-07-29
申请号:DE19802335
申请日:1998-01-23
Applicant: BASF AG
Inventor: MUELHAUPT ROLF PROF DR , BAUMERT MARTIN , GEPRAEGS MICHAEL DR
IPC: C07D263/10 , C08F4/04 , C08F271/02 , C08F293/00 , C07D233/06 , C07D247/02 , C07D263/28 , C07D269/02 , C07D277/10 , C07D283/02 , C08F226/06 , C08F297/00
Abstract: Azo compounds functionalized with heterocycles are useful for radical polymerisation of olefinically unsaturated compounds to give (co)polymers with heterocyclic terminal groups. Azo compounds functionalized with heterocycles are of formula (I). Y = 1-20C alkyl, 6-14C aryl, 6-14C aryl substituted with functional groups based on non-metallic elements of Groups IVA, VA, VIA or VIIA, 3-10C cycloalkyl, aralkyl with 1-10C in the alkyl portion and 6-14C in the aryl portion, 1-20C alkyl substituted with functional groups based on non-metallic elements of Groups IVA, VA, VIA or VIIA, or a group of formula (II); Ra, Ra' = H, 1-20C alkyl, 6-14C aryl, aralkyl with 1-10C in the alkyl portion and 6-14C in the aryl portion, 3-10C cycloalkyl, or (not simultaneously) functional groups based on non-metallic elements of Groups IVA, VA, VIA or VIIA; Z' = -O-, -S- or -N(R')-; X = -(C(Rb)(Rb'))l or (=N)-(C(Rb)(Rb'))m-A-(C(Rb)(Rb'))n-(E)p; Rb, Rb' = as for Ra and Ra'; A = -C(O)O-, -O-, -S-, -C(O)N(R)-, -N(R)-, -C(O)- or -C(R)=N-; E = optionally substituted 6-14C arylene; R', R = H, alkyl, aryl or aralkyl; k = 2 or 3; l = a whole number 1-24; m, n = whole numbers 0-12, and m+n \- 1; and p = 0, 1, 2 or 3, and n + p \- 1. An Independent claim is also included for the preparation of compounds (I) comprising reacting a compound of formula (IIIa) with a halogenating agent in a polar aprotic solvent at -20 to 100 deg C to form the corresponding compound (IIIb: B = Cl, Br or I), and reacting the isolated compound (IIIb) with a base in a polar protic solvent at 0-50 deg C. Y = 1-20C alkyl, 6-14C aryl, 6-14C aryl substituted with functional groups based on nonmetallic elements of Groups IVA, VA, VIA or VIIA, 3-10C cycloalkyl, aralkyl with 1-10C in the alkyl part and 6-14C in the aryl part, 1-20C alkyl substituted with functional groups based on nonmetallic elements of Groups IVA, VA, VIA or VIIA, or a residue of formula (IV); Ra, Ra' = H, 1-10C alkyl, 6-14C aryl, aralkyl with 1-10C in the alkyl part and 6-14C in the aryl part, 3-10C cycloalkyl or (not both simultaneously) functional groups based on nonmetallic elements of Groups IVA, VA, VIA or VIIA; Z' = -O-, -S- or -N(R')-; X = -(C(Rb)(Rb'))l or -(C(Rb)(Rb'))m-A-(C(Rb)(Rb'))n(E)p-; Rb, Rb' = as for Ra and Ra'; A = -C(O)O-, -O-, -S-, -C(O)N(R)-, -N(R)-, -C(O)- or -C(R)=N-; E = optionally substituted 6-14C arylene; R', R = H, alkyl, aryl or aralkyl; k = 2 or 3; l = a whole number 1-24; m, n = whole numbers 0-12, and m + n at least 1; p = 0, 1, 2 or 3, and n + p at least 1; and B = OH, mesyl, trifluoromethylsulphonyl, tosyl or brosyl.
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公开(公告)号:ES2114256T3
公开(公告)日:1998-05-16
申请号:ES95114172
申请日:1995-09-09
Applicant: BASF AG
Inventor: FISCHER DAVID DR , LANGHAUSER FRANZ DR , KERTH JURGEN DR , SCHWEIER GUNTHER DR , MUELHAUPT ROLF PROF DR , SCHNEIDER MARTIN
Abstract: Oligomers (IA) and polymers (IB) are obtd. from 0.001-100 mole-% amino-alkene(s) of formula (II) and 0-99.999 mole-% alkene(s) (III). In (II): x = 0-25; and R -R = H, 1-10C alkyl, 5-7-membered cycloalkyl, opt. with 1-6C alkyl substits., or 6-15C aryl. When (III) is propene is x does not = 1.
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公开(公告)号:DE4433481A1
公开(公告)日:1996-03-21
申请号:DE4433481
申请日:1994-09-20
Applicant: BASF AG
Inventor: FISCHER DAVID DR , LANGHAUSER FRANZ DR , KERTH JUERGEN DR , SCHWEIER GUENTHER DR , MUELHAUPT ROLF PROF DR , SCHNEIDER MARTIN
Abstract: Oligomers (IA) and polymers (IB) are obtd. from 0.001-100 mole-% amino-alkene(s) of formula (II) and 0-99.999 mole-% alkene(s) (III). In (II): x = 0-25; and R -R = H, 1-10C alkyl, 5-7-membered cycloalkyl, opt. with 1-6C alkyl substits., or 6-15C aryl. When (III) is propene is x does not = 1.
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公开(公告)号:DE19750371A1
公开(公告)日:1999-05-20
申请号:DE19750371
申请日:1997-11-14
Applicant: BASF AG
Inventor: ROESCH JOACHIM DR , MUELHAUPT ROLF PROF DR , BAUER THORSTEN
IPC: C08J5/18 , C08K5/00 , C08K5/34 , C08J3/00 , C08F6/00 , C08J5/00 , C08K5/3462 , C08K5/3492 , C08L23/10 , D01F6/04
Abstract: A partially crystalline polymer (I) contains at least one hydrogen-bonded adduct (II) consisting of two chemically different compounds and having a melting point higher than that of the single compounds. Independent claims are also included for the following: (1) nucleation process of crystallizable polymers using the hydrogen-bonded adduct (II) as nucleating agent; (2) a barbituric acid derivative (III) of formula (1); (3) a triamino pyrimidine derivative (IV) of formula (2); (4) an adduct of barbituric acid derivative (III), and triamino pyrimidine derivative (IV); and (5) film, fiber or molded articles prepared from (I). R - R = 6-18C aryl or 6-18C aryl-1-10C alkyl; the aryl groups being optionally substituted with up to 3 1-10C alkyl groups and including fused cyclopentadienyl groups; R = (additionally) H.
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公开(公告)号:DE4203753A1
公开(公告)日:1993-08-12
申请号:DE4203753
申请日:1992-02-10
Applicant: BASF AG
Inventor: LANGHAUSER FRANZ DR , LUX MARTIN DR , MUELHAUPT ROLF PROF DR , FISCHER DAVID
IPC: C08F4/645 , C07F5/06 , C08F4/60 , C08F4/623 , C08F4/639 , C08F4/6392 , C08F4/642 , C08F4/646 , C08F4/6592 , C08F4/68 , C08F10/00 , C08F110/06
Abstract: Catalyst systems for polymerising C2 to C10 alkenes, containing as active components metallocene complexes of metals of sub-groups IV and V of the periodic system, an oligomeric aluminium oxide compound and a cyclic boron compound of general formula (IV) in which R to R are C1 to C10 alkyl groups which may be substituted singly to triply by halogen atoms, C6 to C15 aryl groups or C1 to C10 alkoxy groups; C4 to C7 cycloalkyl groups which may be substituted singly to triply by halogen atoms, C1 to C10 alkyl groups or C1 to C10 alkoxy groups; C1 to C10 alkoxy groups which may be substituted singly to triply by halogen atoms, C1 to C10 alkyl groups or C6 to C15 aryl groups; or C6 to C15 aryl groups which may be substituted singly to fivefold by halogen atoms, C1 to C10 alkyl groups or C1 to C10 alkoxy groups.
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