公开(公告)号：US3926943A

公开(公告)日：1975-12-16

申请号：US40805773

申请日：1973-10-19

Applicant: BASF AG

Inventor： DIMROTH PETER ,  GAENG MANFRED ,  RUIDER GUENTHER

IPC: C09D7/00 ,  C09B29/20 ,  C09B43/32 ,  C09D7/12 ,  C09D11/00 ,  C09D11/02 ,  C09B29/36 ,  C09B43/12

CPC classification number: C09B43/32 ,  C09B29/20

Abstract: Azo pigments of the Beta -hydroxynaphthoic acid series containing an o-phenylenediamine and a trimellitic acid imide moiety. These pigments are best illustrated by the formula

The pigments are suitable for example for coloring resins, surface coatings and printing inks and give brilliant hues of very good fastness properties.

Abstract translation: 包含邻苯二胺和偏苯三酸酰亚胺部分的β-羟基萘甲酸系的偶氮颜料。 这些颜料最好用配方说明。颜料适合用于着色树脂，表面涂料和印刷油墨，并提供非常好的牢度性能的辉煌色彩。

公开(公告)号：JP2001294562A

公开(公告)日：2001-10-23

申请号：JP2001067448

申请日：2001-03-09

Applicant: BASF AG

Inventor： RUIDER GUENTHER ,  ROSS KARL-HEINZ DR ,  MELDER JOHANN-PETER DR ,  SCHULZ GERHARD ,  GUTSCHOVEN FRANK ,  BUSKENS PHILIPP DR

IPC: C07C213/10 ,  C07C215/08 ,  C07C215/12 ,  C07C215/14

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing an alkanolamine diminished in discoloration determined by e.g. APHA color number and improved in color stability over a long storage period. SOLUTION: This method for producing an alkanolamine comprises the following steps: step (a): the original alkanolamine is treated with an effective amount of phosphorous acid, hypophosphorous acid or a compound thereof at an elevated temperature for 5 min or longer, and subsequently, step b: the resultant alkanolamine is distilled in the presence of an effective amount of one of the above phosphorus compounds.

公开(公告)号：JP2001097934A

公开(公告)日：2001-04-10

申请号：JP2000265450

申请日：2000-09-01

Applicant: BASF AG

Inventor： RUIDER GUENTHER ,  ROSS KARL-HEINZ DR ,  BREITSCHEIDEL BORIS DR ,  MAIER HEIKE ,  SCHULZ GERHARD ,  HUBER SYLVIA

IPC: B01J35/02 ,  C07B61/00 ,  C07C213/10 ,  C07C215/08 ,  C07C215/10 ,  C07C215/12 ,  C07C215/14

Abstract: PROBLEM TO BE SOLVED: To find out an economical, selective and efficient method for producing an alkanolamine having improved color quality as opposed to a conventional method. SOLUTION: This method for producing the alkanolamine having the improved color quality and good in color stability comprises using a supported heterogeneous catalyst comprising a noble metal of Re, Ru, Rh, Pd, Os, Ir, Pt and/or Ag and a carrier material selected from the group of active carbon, α-aluminum oxide, zirconium dioxide and titanium dioxide as a hydrogenating catalyst in which the catalyst has a prescribed hardness of at least 10 N cutting hardness and prescribed strengths of at least 30 N laterial pressure strength and at least 25 N stamping strength in the case of active carbon as the carrier material in the method for producing the alkanolamine having the improved color quality by treating an alkanolamine using hydrogen at a high temperature in the presence of the hydrogenating catalyst. Thereby, the alkanolamine is economically produced.

公开(公告)号：WO2005035481A3

公开(公告)日：2005-06-02

申请号：PCT/EP2004011022

申请日：2004-10-02

Applicant: BASF AG ,  REIF WOLFGANG ,  HAMMER HANS ,  RUIDER GUENTHER ,  MEIER ANTON ,  BUSKENS PHILIPP ,  FRAUENKRON MATTHIAS

Inventor： REIF WOLFGANG ,  HAMMER HANS ,  RUIDER GUENTHER ,  MEIER ANTON ,  BUSKENS PHILIPP ,  FRAUENKRON MATTHIAS

IPC: C07C213/10 ,  C07C215/12

CPC classification number: C07C213/10 ,  C07C215/12

Abstract: The invention relates to a method for distillative separation of triethanolamin from a substance mixture consisting of mono- di-, and triethanolamin, ethanolamin-ether and water obtainable by an ammonia and ethylene oxide reaction in a liquid phase at a high pressure and temperature consisting in distilling the substance mixture in two stages. In the first stage, a low-boiling fraction and a high-boiling fraction are withdrawn and discharged, and in the second stage, a medium-boiling fractions is distilled at a triethanolamin content >99.4 % by weight and a diethanolamin content

Abstract translation: 一种用于三乙醇胺的从图像在压力下，并在一，二和三乙醇胺的升高的温度下混合，以及乙醇胺醚和水，通过氨与环氧乙烷在液相中反应而获得的连续蒸馏分离工艺，其中在两个阶段中蒸馏该混合物 是。 在第一阶段中的低沸点馏分和高沸点馏分被取出和排出并在第二阶段中，中间沸点馏分蒸馏具有<0.2重量％的> 99.4重量％三乙醇胺的含量和二乙醇胺。 该混合物的蒸馏在第一列中优选进行和相互连接该第二塔或间壁塔。

公开(公告)号：ID28966A

公开(公告)日：2001-07-19

申请号：ID20011360

申请日：1999-11-25

Applicant: BASF AG

Inventor： RUIDER GUENTHER ,  ROSS KARL-HEINZ

IPC: C07C213/04 ,  C07C213/10 ,  C07C215/08

Abstract: Method of purifying triethanolamine prepared by reacting aqueous ammonia with ethylene oxide in the liquid phase under pressure and at elevated temperature by removing excess ammonia, water and monoethanolamine from the reaction product, reacting the resulting crude product with ethylene oxide at temperatures of from 110 to 180° C., and then rectifying the mixture in the presence of phosphorous or hypophosphorous acid or compounds thereof.

公开(公告)号：DE502004004156D1

公开(公告)日：2007-08-02

申请号：DE502004004156

申请日：2004-10-02

Applicant: BASF AG

Inventor： REIF WOLFGANG ,  HAMMER HANS ,  RUIDER GUENTHER ,  MEIER ANTON ,  BUSKENS PHILIPP ,  FRAUENKRON MATTHIAS

IPC: C07C213/10 ,  C07C215/12

Abstract: Process for separating triethanolamine continuously by distillation from a mixture of monoethanolamine, diethanolamine and triethanolamine together with ethanolamine ethers and water obtained by reaction of ammonia with ethylene oxide in the liquid phase under superatmospheric pressure and at elevated temperature, in which the mixture is distilled in two stages. The low-boiling fraction and the high-boiling fraction are taken off and discharged in the first stage and the intermediate-boiling fraction comprising >99.4% by weight of triethanolamine and

公开(公告)号：DE10346779A1

公开(公告)日：2005-05-12

申请号：DE10346779

申请日：2003-10-08

Applicant: BASF AG

Inventor： REIF WOLFGANG ,  HAMMER HANS ,  RUIDER GUENTHER ,  MEIER ANTON ,  BUSKENS PHILIP ,  FRAUENKRON MATTHIAS

IPC: C07C213/10 ,  C07C215/12

Abstract: Process for separating triethanolamine continuously by distillation from a mixture of monoethanolamine, diethanolamine and triethanolamine together with ethanolamine ethers and water obtained by reaction of ammonia with ethylene oxide in the liquid phase under superatmospheric pressure and at elevated temperature, in which the mixture is distilled in two stages. The low-boiling fraction and the high-boiling fraction are taken off and discharged in the first stage and the intermediate-boiling fraction comprising >99.4% by weight of triethanolamine and

公开(公告)号：CA2540246C

公开(公告)日：2011-06-07

申请号：CA2540246

申请日：2004-10-02

Applicant: BASF AG

Inventor： REIF WOLFGANG ,  HAMMER HANS ,  RUIDER GUENTHER ,  MEIER ANTON ,  BUSKENS PHILIP ,  FRAUENKRON MATTHIAS

IPC: C07C213/10 ,  C07C215/12

Abstract: The invention relates to a method for distillative separation of triethanolamin from a substance mixture consisting of mono- di-, and triethanolamin, ethanolamin-ether and water obtainable by an ammonia and ethylene oxide reaction in a liquid phase at a high pressure and temperature consisting in distilling the substance mixture in two stages. In the first stage, a low-boiling fraction and a high-boiling fraction are withdrawn and discharged, and in the second stage, a medium-boiling fractions is distilled at a triethanolamin content >99.4 % by weight and a diethanolamin content

公开(公告)号：AT365153T

公开(公告)日：2007-07-15

申请号：AT04765773

申请日：2004-10-02

Applicant: BASF AG

Inventor： REIF WOLFGANG ,  HAMMER HANS ,  RUIDER GUENTHER ,  MEIER ANTON ,  BUSKENS PHILIPP ,  FRAUENKRON MATTHIAS

IPC: C07C213/10 ,  C07C215/12

Abstract: Process for separating triethanolamine continuously by distillation from a mixture of monoethanolamine, diethanolamine and triethanolamine together with ethanolamine ethers and water obtained by reaction of ammonia with ethylene oxide in the liquid phase under superatmospheric pressure and at elevated temperature, in which the mixture is distilled in two stages. The low-boiling fraction and the high-boiling fraction are taken off and discharged in the first stage and the intermediate-boiling fraction comprising >99.4% by weight of triethanolamine and

公开(公告)号：CA2540246A1

公开(公告)日：2005-04-21

申请号：CA2540246

申请日：2004-10-02

Applicant: BASF AG

Inventor： MEIER ANTON ,  RUIDER GUENTHER ,  BUSKENS PHILIP ,  HAMMER HANS ,  FRAUENKRON MATTHIAS ,  REIF WOLFGANG

IPC: C07C213/10 ,  C07C215/12

Abstract: Process for separating triethanolamine continuously by distillation from a mixture of monoethanolamine, diethanolamine and triethanolamine together with ethanolamine ethers and water obtained by reaction of ammonia with ethylene oxide in the liquid phase under superatmospheric pressure and at elevated temperature, in which the mixture is distilled in two stages. The low-boiling fraction and the high-boiling fraction are taken off and discharged in the first stage and the intermediate-boiling fraction comprising >99.4% by weight of triethanolamine and