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公开(公告)号:JPH10174874A
公开(公告)日:1998-06-30
申请号:JP29677597
申请日:1997-10-29
Applicant: BASF AG
Inventor: WULFF-DOERING JOACHIM , MELDER JOHANN-PETER , SCHULZ GERHARD , VOIT GUIDO , GUTSCHOVEN FRANK , HARDER WOLFGANG
IPC: B01J23/89 , C07B61/00 , C07C209/02 , C07C209/14 , C07C209/16 , C07C209/26 , C07C211/10 , C07C211/13 , C07C213/02 , C07C215/14
Abstract: PROBLEM TO BE SOLVED: To provide an amination catalyst small in the content of nickel and/or cobalt and having high selectivity and high stability about ethylene diamine obtained by aminating monoethanol amine with ammonia. SOLUTION: The catalyst is carried on a porous metal oxide carrier. And the catalyst contains 0.1-6wt.% cobalt, nickel or the mixture, 0.001-25wt.% ruthenium, 0-10wt.% copper and 0-5wt.% accelerator selected from iron, rhodium, palladium, platina, iridium, osmium, silver, gold, chromium, molybdenum, tungsten, rhenium, zinc, cadmium, lead, manganese, tin lithium, sodium, potassium, rubidium, cesium, phosphorus, arsenic, antimony, bismuth, tellurium, thallium and the mixture per total weight of the catalyst.
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公开(公告)号:JPH08325245A
公开(公告)日:1996-12-10
申请号:JP6671596
申请日:1996-03-22
Applicant: BASF AG
Inventor: GUTSCHOVEN FRANK , BECKER RAINER , MELDER JOHANN-PETER , BRANDE ETIENNE VAN DEN , KRADER THOMAS
IPC: B01J31/24 , C07B61/00 , C07D251/34
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公开(公告)号:JP2001294562A
公开(公告)日:2001-10-23
申请号:JP2001067448
申请日:2001-03-09
Applicant: BASF AG
Inventor: RUIDER GUENTHER , ROSS KARL-HEINZ DR , MELDER JOHANN-PETER DR , SCHULZ GERHARD , GUTSCHOVEN FRANK , BUSKENS PHILIPP DR
IPC: C07C213/10 , C07C215/08 , C07C215/12 , C07C215/14
Abstract: PROBLEM TO BE SOLVED: To provide a method for producing an alkanolamine diminished in discoloration determined by e.g. APHA color number and improved in color stability over a long storage period. SOLUTION: This method for producing an alkanolamine comprises the following steps: step (a): the original alkanolamine is treated with an effective amount of phosphorous acid, hypophosphorous acid or a compound thereof at an elevated temperature for 5 min or longer, and subsequently, step b: the resultant alkanolamine is distilled in the presence of an effective amount of one of the above phosphorus compounds.
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公开(公告)号:JP2001199939A
公开(公告)日:2001-07-24
申请号:JP2000371847
申请日:2000-12-06
Applicant: BASF AG
Inventor: NOUWEN JAN , KAESHAMMER STEFAN , HOEHN ARTHUR , FUNKE FRANK DR , MELDER JOHANN-PETER DR , GUTSCHOVEN FRANK , BUSKENS PHILIPP DR
IPC: B01J35/02 , B01J23/755 , C07B61/00 , C07C209/26 , C07C211/06
Abstract: PROBLEM TO BE SOLVED: To provide a method of producing monoisopropylamine(MIPA), capable of overcoming disadvantages of conventional methods and therefore capable of economically improving the methods, when the MIPA is produced by aminating acetone with ammonia and simultaneously hydrogenating with hydrogen. SOLUTION: This method of producing the MIPA comprises reacting the acetone with the ammonia and the hydrogen in the presence of a catalyst at a high temperature under an increased pressure, wherein the catalyst has a main body for catalytic activity which contains aluminum dioxide (Al2O3), zirconium dioxide (ZrO2), titanium dioxide (TiO2) and/or silicon dioxide (SiO2) in an amount of 20-90 wt.%, an oxygen-containing copper compound in an amount of 1-70 wt.% (calculated as CuO), an oxygen-containing nickel compound in an amount of 1-70 wt.% (calculated as NiO) and an oxygen-containing cobalt compound in an amount of 1-70 wt.% (calculated as CoO), when measured at a time after the catalyst is produced but before the catalyst is subjected to hydrogenation treatment.
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公开(公告)号:JPH10174875A
公开(公告)日:1998-06-30
申请号:JP29688697
申请日:1997-10-29
Applicant: BASF AG
Inventor: WULFF-DOERING JOACHIM DR , MELDER JOHANN-PETER DR , SCHULZ GERHARD DR , VOIT GUIDO DR , GUTSCHOVEN FRANK , HARDER WOLFGANG DR
IPC: B01J23/89 , B01J37/18 , C07B61/00 , C07C209/16 , C07C211/00 , C07C211/10
Abstract: PROBLEM TO BE SOLVED: To provide an amination catalyst small in the content of nickel and/or cobalt and having high selectivity and high stability about ethylene diamine obtained by aminating monoethanol amine with ammonia. SOLUTION: The catalyst is obtained by carrying 6-50wt.% cobalt, nickel or the mixture, 0.001-25wt.% ruthenium, 0-10wt.% copper and 0-5wt.% accelerator per total weight of the catalyst on a porous metal oxide carrier. In such a case, the catalyst is produced by (a) impregnating the carrier with the metal and the accelerator or the compound, (b) drying and calcining and (c) reducing with hydrogen flow, where without impregnating the carrier with a halogen compound.
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公开(公告)号:ES2158423T3
公开(公告)日:2001-09-01
申请号:ES97118631
申请日:1997-10-27
Applicant: BASF AG
Inventor: WULFF-DOERING JOACHIM , MELDER JOHANN-PETER , SCHULZ GERHARD , VOIT GUIDO , GUTSCHOVEN FRANK , HARDER WOLFGANG
IPC: B01J23/89 , C07B61/00 , C07C209/02 , C07C209/14 , C07C209/16 , C07C209/26 , C07C211/10 , C07C211/13 , C07C213/02 , C07C215/14
Abstract: Catalysts contain, on a porous metal oxide support, 0.1-6 wt% cobalt, nickel or a mixture, 0.001-25 wt% ruthenium, 0-10 wt% copper and 0-5 wt% promoter(s) of iron, rhodium, palladium, platinum, iridium, osmium, silver, gold, chromium, molybdenum, tungsten, rhenium zinc, cadmium, lead, manganese, tin, lithium, sodium, potassium, rubidium, caesium, phosphorus, arsenic, antimony, bismuth, tellurium or thallium. Also claimed are: (i) a process for the production of catalysts, by impregnating the support with the metals and promoters or their compounds, drying and calcining, and reducing the calcined catalyst in a stream of hydrogen, and (ii) a process for the production of amination products by reacting alkylene oxides, alcohol, aldehyde or ketones with ammonia or prim. or sec. amines in presence of free hydrogen and catalyst.
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公开(公告)号:BR0005746A
公开(公告)日:2001-07-17
申请号:BR0005746
申请日:2000-12-06
Applicant: BASF AG
Inventor: NOUWEN JAN , KOSHAMMER STEFAN , HOEHN ARTHUR , FUNKE FRANK , MELDER JOHANN-PETER , GUTSCHOVEN FRANK , BUSKENS PHILIP
IPC: B01J35/02 , B01J23/755 , C07B61/00 , C07C209/26 , C07C211/06
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公开(公告)号:DE19507007A1
公开(公告)日:1996-08-29
申请号:DE19507007
申请日:1995-02-28
Applicant: BASF AG
Inventor: MELDER JOHANN-PETER DR , WULFF-DOERING JOACHIM DR , GUTSCHOVEN FRANK , WITZEL TOM DR , HARDER WOLFGANG DR
IPC: C07D295/02 , B01J23/38 , B01J23/46 , B01J23/54 , B01J23/56 , B01J23/89 , C07B61/00 , C07C209/14 , C07C209/16 , C07C209/24 , C07C209/26 , C07C211/03 , C07C211/10 , C07C213/02 , C07C215/14 , B01J23/48 , B01J27/057 , B01J27/185 , C07C209/60 , C07C211/14 , C07C211/16 , C07C213/00 , C07C215/08 , C07D295/023
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公开(公告)号:ES2203558T3
公开(公告)日:2004-04-16
申请号:ES01104959
申请日:2001-03-01
Applicant: BASF AG
Inventor: RUIDER GUNTHER DR , ROSS KARL-HEINZ DR , MELDER JOHANN-PETER DR , SCHULZ GERHARD DR , GUTSCHOVEN FRANK , BUSKENS PHILIP DR
IPC: C07C213/10 , C07C215/08 , C07C215/12 , C07C215/14
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公开(公告)号:AT244696T
公开(公告)日:2003-07-15
申请号:AT01104959
申请日:2001-03-01
Applicant: BASF AG
Inventor: RUIDER GUENTHER DR , ROSS KARL-HEINZ DR , MELDER JOHANN-PETER DR , SCHULZ GERHARD DR , GUTSCHOVEN FRANK , BUSKENS PHILIP DR
IPC: C07C213/10 , C07C215/08 , C07C215/12 , C07C215/14
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