公开(公告)号：DE2624631A1

公开(公告)日：1977-12-22

申请号：DE2624631

申请日：1976-06-02

Applicant: BASF AG

Inventor： POHLEMANN HEINZ DIPL CHEM DR ,  MAARMANN HERBERT DIPL CHEM DR ,  SEEBACH DIETER PROF DR

IPC: C08C19/20 ,  C08F2/00 ,  C08F4/00 ,  C08F4/42 ,  C08F8/34 ,  C08F10/00

Abstract: A process for the manufacture of reactive polymers of vinyl monomers by reacting the latter, or the polymers formed therefrom, with compounds which form free radicals.

公开(公告)号：DE19611101A1

公开(公告)日：1997-09-25

申请号：DE19611101

申请日：1996-03-21

Applicant: BASF AG

Inventor： MEYER FRANK DR ,  SIEMENSMEYER KARL DR ,  KUBALL HANS-GEORG PROF DR ,  WEIS BERNHARD ,  SEEBACH DIETER PROF DR

IPC: C07D317/22 ,  C07D317/24 ,  C09B67/00 ,  C09B67/20 ,  C09D5/36 ,  C09D7/12 ,  C09D11/02 ,  C09K19/00 ,  C09K19/38 ,  C09K19/58 ,  G02F1/13 ,  C07D405/06 ,  C07D405/12 ,  C07D417/06 ,  C07D417/12 ,  C07D413/06 ,  C07D413/12 ,  C07D409/06 ,  C07D409/12 ,  C09D157/10

Abstract: The invention concerns chiral compounds of the general formula (I), in which the variables are defined as follows: R , R , R , and R are hydrogen or aromatic, aliphatic or araliphatic groups with 1 to 40 C-atoms; R , R , R , and R are aromatic or aliphatic groups with 1 to 20 C-atoms, with the exception that at least one of the groups R to R includes a polymerizable group. The compounds described are suitable for use as doping agents in liquid crystals, in coating-material formulations and in the manufacture of interference pigments for use in printing inks and paints.

公开(公告)号：DE2246564A1

公开(公告)日：1974-03-28

申请号：DE2246564

申请日：1972-09-22

Applicant: BASF AG

Inventor： SEEBACH DIETER PROF DR ,  ENDERS DIETER DIPL CHEM

IPC: C07D207/50 ,  C07D211/98 ,  C07D295/28 ,  C07C111/00

Abstract: Electrophilic substn. of nitrosamines on the C-atom in the alpha-position to the amino-N-atom, by preparing alpha-metallo derivs. of the nitrosamines and reacting the organo-metallic cpd. with an electrophile. The prods. are useful in studying biochemical processes, e.g. in cancer research. Pref. metals are alkali metals, especially Li, but, Na, and K and alkaline earths e.g. Mg. Zn, Cd may be used. Electrophiles include aldehydes, ketones, alkyl halides, alkyl sulphates, alkyl benzenesulphonates, acylating agents etc.

公开(公告)号：DE2423325A1

公开(公告)日：1975-12-04

申请号：DE2423325

申请日：1974-05-14

Applicant: BASF AG

Inventor： SEEBACH DIETER PROF DR ,  EHRIG VOLKER DIPL CHEM

IPC: C07D317/54 ,  C07D317/60 ,  C07D317/64 ,  C07C79/36 ,  C07C79/44

Abstract: Nitrocyclohexanones of formula: (I) where r1 is H, or an aliphatic or aromatic residue, R2 is H or a carbalkoxy gp., and R3 and R4 are H or an aliphatic residue, are prepd. by (a) reacting R1-CH=C-R4 (II) with 2 Li circle positive R2-circle negative CH-CO-circle negative-CH-CO-R3 (III) and (B) reacting the reaction mixt. with acid in presence of water at 30 degrees C. (I) are obtd. in high yield and purity by a simple method. Side reactions, e.g. polymerisation and isomerisation, do not occur.

公开(公告)号：DE2423317A1

公开(公告)日：1975-12-04

申请号：DE2423317

申请日：1974-05-14

Applicant: BASF AG

Inventor： SEEBACH DIETER PROF DR ,  EHRIG VOLKER DIPL CHEM

IPC: C07C201/12 ,  C07C205/04 ,  C07C205/45 ,  C07C205/53 ,  C07C233/00 ,  C07D317/52 ,  C07D317/54 ,  C07D317/56 ,  C07D317/60 ,  C07D339/08 ,  C07C79/36 ,  C07C103/30

Abstract: Cpds. of formula (I) where R5 is H, an aliphatic residue or where R10 is H or alkoxy or the 2 R10 gps. may together form -O-CH2-O-, R6 is an aliphatic residue, alkylthio, -NO-N-R, -CONH-R11, -CO-CH2- COOR11, or -CO-CH2-COR11 where R11 is an aliphatic residue, or R6 may also be -CON(R11)2 if R5 is H, an aliphatic residue or or R9 is halogen, R7 is h or alkylthio, R6 and R7 may form a dithiane ring, a cyclohexanone ring or a camphor ring with the adjacent C atom, R8 is H, a cycloaliphatic or aromatic residue, a GHO gp., a carbalkoxy, or alkylthio, and R9 is H or an aliphatic gp., and if R7, R8 and R9 are H and R5 is C6H5 or 1-3C alkyl, then if R6 is an aliphatic residue this is 4C, are prepd. by reacting HC = C - R9 (II) with.

公开(公告)号：DE2400429A1

公开(公告)日：1975-07-17

申请号：DE2400429

申请日：1974-01-05

Applicant: BASF AG

Inventor： SEEBACH DIETER PROF DR ,  MEYER HARTMUT DR

IPC: C07D309/32 ,  C07D339/08

Abstract: Tetrahydro-pyrone-2,4-diones of formula (I): (where R1 is H or lower alkyl; R2 is H or lower alkyl; R3 is 1-10C alkyl or alkenyl opt. substd. by phenyl, carbonyl and/or carbonyl protected against nucleophilic attack, or phenyl, and R4 is H, lower alkyl or phenyl, or R3 and R4 are linked so as to form a 5-8C cycloaliphatic ring), e.g., 4-keto-6-(2-n-butyl-1,3-dithia-2-yl)-tetrahydro-alpha-pyrone, are prepd. by reacting the dianion of an alpha-R1-gamma-R2-acetoacetic acid ester (II) with a carbonyl cpd. of formula: R3R4CO (III) at below-30 degrees C, pouring the reaction mixt. into water, and isolating (I) in a conventional manner. (I) are inters, for natural prodts. such as kawain and pestalotin. High yields are obtd.

公开(公告)号：DE2327545A1

公开(公告)日：1974-12-19

申请号：DE2327545

申请日：1973-05-30

Applicant: BASF AG

Inventor： SEEBACH DIETER PROF DR ,  DACH ROLF ,  ENDERS DIETER DIPL CHEM ,  RENGER BERND DIPL CHEM

IPC: C07D257/08 ,  C07D471/14 ,  C07D55/58

Abstract: Cpds. of formula (I) (where R1 and R2 are 2-5C alkyl or 4-7C cycloalkyl, and R3 and R4 are H or lower alkyl, or R1 + R3 and R2+R4 are -(CH2)n- (n = 3, 4, 5 or 6) or -(CH2)2-X-CH2- (X = O or NR5, R5 being lower alkyl)) have biological activity; for example, in experimental animals they display activity on the central nervous system. (I) are prepd. by redn. of N-oxides of formula (II) (obtainable by reaction of 2 molecules of alpha-metallated nitrosamines) to the oxygen-free cpds. e.g. by treating with excess tiralkyl phosphite.

公开(公告)号：DE2218366A1

公开(公告)日：1973-11-08

申请号：DE2218366

申请日：1972-04-15

Applicant: BASF AG

Inventor： SEEBACH DIETER PROF DR ,  ENDERS DIETER DIPL CHEM

IPC: C07D207/50 ,  C07D211/98 ,  C07D295/28 ,  C07C111/00

Abstract: Substn. is on the C atom alpha-to the amine N, using a nitrosamine of a sec. amine having >=1 H atom alpha to the amine N. Process is used for chemical synthetics (e.g., by reducing prods. to assymetrically substd. hydrazines or denitrosylation to amino cpds.) and for studying biochemical processes, esp., in cancer research. Metallisation is e.g., with alkali(ne earth) metal, Zn, Cd or Cu, and electrophilic is pref. a carbonyl cpd.