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    1.
    发明专利
    未知

    公开(公告)号：AT366280T

    公开(公告)日：2007-07-15

    申请号：AT05701330

    申请日：2005-02-03

    Applicant: BASF AG

    Inventor： STORK MARTIN ,  WEBER MARTIN ,  GOTTSCHALK AXEL ,  RIECHERS SVEN ,  GUENTHERBERG NORBERT ,  FISCHER WOLFGANG ,  LEBER LUDGER ,  ITTEMANN PETER ,  JUENGLING STEPHAN ,  DUIJZINGS WIL

    IPC: C08L51/04 ,  C08F279/02 ,  C08F279/04 ,  C08F285/00 ,  C08L55/02

    Abstract: The invention relates to thermoplastic moulding materials containing a mixture of (A) between 30 and 69 wt. %, in relation to the sum of the constituents (A), (B) and (C), of a methylmethacrylate polymer, (B) between 30 and 69 wt. %, in relation to the sum of the constituents (A), (B) and (C), of a copolymer that can be obtained by the polymerisation of a vinylaromatic monomer and a vinylcyanide, and (C) between 1 and 40 wt. %, in relation to the sum of the constituents (A), (B) and (C), of a graft copolymer that can be obtained from (C1) between 60 and 90 wt. %, in relation to (C), of a core, (C2) between 5 and 20 wt. %, in relation to (C), of a first graft envelope consisting of a vinylaromatic monomer, an alkylmethacrylate and optionally a cross-linking monomer, and (C3) between 5 and 20 wt. %, in relation to (C), of a second graft envelope consisting of an alkyl(meth)acrylate polymer, on the proviso that the quantitative ratio of (C2) to (C3) is between 2:1 and 1:2. The invention is characterised in that the average particle size D50 of the core (C1) is between 50 and 250 nm, the average particle size D90 of the core (C1) is between 60 and 1000 nm, the average particle size D90 of the core (C1) being larger than the average particle size D50 of the core (C1), by a factor between 1.15 and 20, and the core (C1) can be obtained by the polymerisation of a monomer mixture comprising (C11) between 65 and 89 wt. %, in relation to (C1), of a 1,3-diene, (C12) between 10 and 34.9 wt. %, in relation to (C1), of a vinylaromatic monomer, and (C13) between 0.1 and 5 wt. %, in relation to (C1), of an agglomeration polymer. The invention also relates to a method for producing said moulding masses, to the use thereof, and to the moulded bodies obtained therefrom.

    MASAS DE MOLDEO TERMOPLASTICAS CON RESISTENCIA MEJORADA FRENTE A LOS PRODUCTOS QUIMICOS.
    5.
    发明专利
    MASAS DE MOLDEO TERMOPLASTICAS CON RESISTENCIA MEJORADA FRENTE A LOS PRODUCTOS QUIMICOS. 未知

    公开(公告)号：ES2284084T3

    公开(公告)日：2007-11-01

    申请号：ES04820435

    申请日：2004-12-14

    Applicant: BASF AG

    Inventor： STORK MARTIN ,  WEBER MARTIN ,  GOTTSCHALK AXEL ,  RIECHERS SVEN ,  GUNTHERBERG NORBERT ,  FISCHER WOLFGANG

    IPC: C08L33/12 ,  C08F257/02 ,  C08F279/02 ,  C08F285/00 ,  C08L25/12 ,  C08L35/06 ,  C08L51/00 ,  C08L51/04 ,  C08L55/02

    Abstract: Masas de moldeo termoplásticas, que contienen una mezcla formada por (A) desde 30 hasta 69 % en peso, referido a la suma de los componentes (A), (B) y (C), de un polímero de metacrilato de metilo, que puede obtenerse mediante polimerización de una mezcla, constituida por (A1) desde 90 hasta 100 % en peso, referido a (A), de metacrilato de metilo, y (A2) desde 0 hasta 10 % en peso, referido a (A), de un éster de alquilo con 1 hasta 8 átomos de carbono del ácido acrílico, y (B) desde 30 hasta 69 % en peso, referido a la suma de los componentes (A), (B) y (C), de un copolímero, obtenible mediante polimerización de una mezcla, constituida por (B1) desde 75 hasta 88 % en peso, referido a (B), de un monómero vinilaromático y (B2) desde 12 hasta 25 % en peso, referido a (B), de un cianuro de vinilo y (C) desde 1 hasta 40 % en peso, referido a la suma de los componentes (A), (B) y (C), de un copolímero de injerto, obtenible a partir de (C1) desde 60 hasta 90 % en peso, referido a (C), de un núcleo,obtenible mediante polimerización de una mezcla de monómeros, constituida por (C11) desde 65 hasta 90 % en peso, referido a (C1), de un 1, 3-dieno y (C12) desde 10 hasta 35 % en peso, referido a (C1), de un monómero vinilaromático y (C2) desde 5 hasta 20 % en peso, referido a (C), de un primer revestimiento de injerto, y (C3) desde 5 hasta 20 % en peso, referido a (C), de un segundo revestimiento de injerto, obtenible mediante polimerización de una mezcla de monómeros, constituida por (C31) desde 70 hasta 98 % en peso, referido a (C3), de un éster de alquilo con 1 hasta 8 átomos de carbono del ácido metacrílico y (C32) desde 2 hasta 30 % en peso, referido a (C3), de un éster de alquilo con 1 hasta 8 átomos de carbono del ácido acrílico, y (D) en caso dado aditivos usuales en cantidades de hasta un 20 % en peso, referido a la suma de los componentes (A), (B) y (C), con la condición de que la relación en peso entre (C2) y (C3) se encuentre en el intervalo desde 2:1 hasta 1:2, caracterizadasporque el primer revestimiento de injerto (C2) puede obtenerse mediante polimerización de una mezcla de monómeros, constituida por (C21) desde 30 hasta 39 % en peso, referido a (C2), de un monómero vinilaromático (C22) desde 61 hasta 70 % en peso, referido a (C2), de un éster de alquilo con 1 hasta 8 átomos de carbono del ácido metacrílico y (C23) desde 0 hasta 3 % en peso, referido a (C2), de otro monómero reticulable.

    6.
    发明专利
    未知

    公开(公告)号：DE502005000978D1

    公开(公告)日：2007-08-16

    申请号：DE502005000978

    申请日：2005-02-03

    Applicant: BASF AG

    Inventor： STORK MARTIN ,  WEBER MARTIN ,  GOTTSCHALK AXEL ,  RIECHERS SVEN ,  GUENTHERBERG NORBERT ,  FISCHER WOLFGANG ,  LEBER LUDGER ,  ITTEMANN PETER ,  JUENGLING STEPHAN ,  DUIJZINGS WIL

    IPC: C08L51/04 ,  C08F279/02 ,  C08F279/04 ,  C08F285/00 ,  C08L55/02

    Abstract: The invention relates to thermoplastic moulding materials containing a mixture of (A) between 30 and 69 wt. %, in relation to the sum of the constituents (A), (B) and (C), of a methylmethacrylate polymer, (B) between 30 and 69 wt. %, in relation to the sum of the constituents (A), (B) and (C), of a copolymer that can be obtained by the polymerisation of a vinylaromatic monomer and a vinylcyanide, and (C) between 1 and 40 wt. %, in relation to the sum of the constituents (A), (B) and (C), of a graft copolymer that can be obtained from (C1) between 60 and 90 wt. %, in relation to (C), of a core, (C2) between 5 and 20 wt. %, in relation to (C), of a first graft envelope consisting of a vinylaromatic monomer, an alkylmethacrylate and optionally a cross-linking monomer, and (C3) between 5 and 20 wt. %, in relation to (C), of a second graft envelope consisting of an alkyl(meth)acrylate polymer, on the proviso that the quantitative ratio of (C2) to (C3) is between 2:1 and 1:2. The invention is characterised in that the average particle size D50 of the core (C1) is between 50 and 250 nm, the average particle size D90 of the core (C1) is between 60 and 1000 nm, the average particle size D90 of the core (C1) being larger than the average particle size D50 of the core (C1), by a factor between 1.15 and 20, and the core (C1) can be obtained by the polymerisation of a monomer mixture comprising (C11) between 65 and 89 wt. %, in relation to (C1), of a 1,3-diene, (C12) between 10 and 34.9 wt. %, in relation to (C1), of a vinylaromatic monomer, and (C13) between 0.1 and 5 wt. %, in relation to (C1), of an agglomeration polymer. The invention also relates to a method for producing said moulding masses, to the use thereof, and to the moulded bodies obtained therefrom.

    7.
    发明专利
    未知

    公开(公告)号：DE502004003730D1

    公开(公告)日：2007-06-14

    申请号：DE502004003730

    申请日：2004-12-14

    Applicant: BASF AG

    Inventor： STORK MARTIN ,  WEBER MARTIN ,  GOTTSCHALK AXEL ,  RIECHERS SVEN ,  GUENTHERBERG NORBERT ,  FISCHER WOLFGANG ,  LEBER LUDGER ,  ITTEMANN PETER ,  JUENGLING STEPHAN

    IPC: C08L33/12 ,  C08F257/02 ,  C08F279/02 ,  C08F285/00 ,  C08L25/12 ,  C08L35/06 ,  C08L51/00 ,  C08L51/04 ,  C08L55/02

    Abstract: The present invention relates to thermoplastic molding compositions comprising a mixture of (A) from 30 to 69% by weight, based on the sum of components (A), (B) and (C), of a methyl methacrylate polymer, (B) from 30 to 69% by weight, based on the sum of components (A), (B) and (C), of a copolymer obtainable by polymerizing a styrenic monomer and a vinyl cyanide, and (C) from 1 to 40% by weight, based on the sum of components (A), (B) and (C), of a graft copolymer obtainable from (C1) from 60 to 90% by weight, based on (C), of a core obtainable by polymerizing a 1,3-diene and a styrenic monomer, (C2) from 5 to 20% by weight, based on (C), of a first graft shell, and (C3) from 5 to 20% by weight, based on (C), of a second graft shell composed of an alkyl (meth)acrylate polymer, with the proviso that the ratio of (C2) to (C3) is in the range from 2:1 to 1:2.

    8.
    发明专利
    未知

    公开(公告)号：DE102004052874A1

    公开(公告)日：2006-05-04

    申请号：DE102004052874

    申请日：2004-11-02

    Applicant: BASF AG

    Inventor： STORK MARTIN ,  BRUCHMANN BERND ,  MALZ HAUKE ,  BREULMANN MICHAEL

    IPC: C08L51/04 ,  C08J5/10 ,  C08K5/205 ,  C08L55/02 ,  C08L75/12

    Abstract: Thermoplastic molding compositions, processes for making the same and articles made therewith are described wherein the compositions include at least one stabilizer comprising one or more polyisocyanates having an average of 2 to 10 isocyanate groups per molecule, wherein at least one active ingredient group is coupled to the one or more polyisocyanates in an amount of 0.1 to 1.0 mole per mole of isocyanate groups, the at least one active ingredient group selected from phenolic compounds, sterically hindered amines and mixture thereof; and wherein up to 0.9 mole of one or more auxiliary groups is coupled to the one or more polyisocyanates.

    Supported catalysts for ethylene and propylene polymerization
    10.
    发明专利
    Supported catalysts for ethylene and propylene polymerization 未知

    公开(公告)号：DE19821949A1

    公开(公告)日：1999-11-18

    申请号：DE19821949

    申请日：1998-05-15

    Applicant: BASF AG ,  MAX PLANCK GESELLSCHAFT

    Inventor： GREGORIUS HEIKE ,  RIEF URSULA ,  KRISTEN MARC OLIVER ,  MUELLEN KLAUS ,  KLAPPER MARKUS ,  STORK MARTIN

    IPC: C07F17/00 ,  C08F4/64 ,  C08F4/651 ,  C08F4/659 ,  C08F4/6592 ,  C08F4/76 ,  C08F10/00 ,  C08F12/00 ,  C08F210/00

    Abstract: Preparation of a supported catalyst by production of a copolymer with leaving group-containing comonomer units, polymer like reaction of the copolymer with an optionally substituted cyclopentadiene compound, and reaction of the copolymer with a mono-Cp-metallocene compound is new. A supported catalyst is prepared by: (1) Production of copolymer containing at least the monomer units of formula (I) and (II): A = a direct chemical bond or a group (A); X = H, optionally substituted aryl, optionally branched alkyl, or alkenyl; n = 1-8. (2) The polymer like reaction of the copolymer with a cyclopentadiene compound (III) to give a corresponding copolymer in which some of the exit groups X are substituted by a residue (III'). R -R = H, 1-10C alkyl, optionally substituted phenyl, or the residue group QR R X ; Q = C, CR R C, Ge, or Si, R , R each = H, Me, Et, or Ph, X = halogen, methoxy or ethoxy; and (3) the reaction of the copolymer modified under (2) with a metallocene compound (IV): Cp = optionally substituted cyclopentadienyl, Ti, Zr, or Hf; X = halogen, H, 1-10C alkyl, 1-10C alkoxy or amido, where the various X substituents have different meanings. Independent Claims are included for: (A) A supported metallocene catalyst; (B) a copolymer obtainable as in (1) and (2) above as a support material for metallocene catalysts; (C) a process for the polymerization of ethylene or propylene, or copolymerization of ethylene or propylene with 3-8C alpha-olefins in the presence of a supported metallocene catalyst.

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