4.
    发明专利
    未知

    公开(公告)号:DE19903459A1

    公开(公告)日:2000-08-03

    申请号:DE19903459

    申请日:1999-01-28

    Applicant: BASF AG

    Abstract: Production of highly pure phytantriol (I) comprises rectification of (I) in a fine vacuum in columns with ordered metal fabric packing and duct distributors with ≥ 500 dripping points/m at an angle of 90 degrees to the layer of fabric just below them. There are 2 or more, 20-100 mm high packing elements with layers of fabric at 90 degrees to one another. Strictly adiabatic rectification with absolute exclusion of air is used. Production of highly pure phytantriol (I) comprises rectification of (I) contaminated with lower and/or higher boiling by-products in a fine vacuum in columns containing metal fabric packing with ordered structure. The liquid is distributed with duct distributors with ≥ 500 dripping points/m . The ducts are at an angle of 90 degrees to the layer of fabric directly below them in the packing. There are 2 or more packing elements with a height of 20-100 mm and layers of fabric at 90 degrees to one another, below the distributor. The process is operated with absolute exclusion of air. Strictly adiabatic rectification is used.

    5.
    发明专利
    未知

    公开(公告)号:DE59706478D1

    公开(公告)日:2002-04-04

    申请号:DE59706478

    申请日:1997-08-13

    Applicant: BASF AG

    Abstract: Chromanyl-ascorbic acid derivatives of formula (I) are new. R1 = 1-12C aliphatic hydrocarbyl; or 4-12C cycloalkyl, aryl or heterocyclyl (optionally substituted by one or more alkyl, alkoxy, OH, NH2 or mono- or dialkylamino); R2 = 8-30C (especially 12-24C) hydrocarbyl, 1-6C alkyl (optionally substituted by COOH); or 4-20C cycloalkyl, aryl or heterocyclyl (optionally substituted by one or more alkyl, alkoxy, OH, NH2 or mono- or dialkylamino); R3 = PO3H2 or glycosidyl; R3-R5 = H or 1-20C alkyl, cycloalkyl, aryl, aralkyl, cycloalkylalkyl or COR7 (sic); or R4 + R5 = alkylene optionally substituted by one or more alkyl; R6 = H or COR7; and R7 = H, 1-20C aliphatic hydrocarbyl or phenyl-vinyl. N.B. R3 is defined twice in the main claim, but in dependent claims is defined once with R4 and R5 (see "More Specifically").

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