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公开(公告)号:DE4327359A1
公开(公告)日:1995-02-16
申请号:DE4327359
申请日:1993-08-14
Applicant: BASF AG
Inventor: SIEMENSMEYER KARL DR , WAGENBLAST GERHARD DR , ZENTEL RUDOLF PROF DR , BREHMER MARTIN
IPC: G02F1/137 , C08F12/00 , C08F12/14 , C08F16/12 , C08F16/14 , C08F16/32 , C08F18/04 , C08F20/10 , C08F20/30 , C08F218/02 , C08F283/12 , C08F290/00 , C08F299/00 , C08F299/08 , C08G77/38 , C08G77/42 , C08G77/442 , C09K19/38 , C09K19/40 , G02F1/13 , G02F1/141 , C08F8/00 , C08G77/20 , C08G85/00 , C08J3/24 , C08J3/28 , G03G5/028
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公开(公告)号:DE19613314A1
公开(公告)日:1997-10-09
申请号:DE19613314
申请日:1996-04-03
Applicant: BASF AG
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公开(公告)号:DE59500245D1
公开(公告)日:1997-06-26
申请号:DE59500245
申请日:1995-03-03
Applicant: BASF AG
Inventor: BECKMANN STEFAN DR , ZENTEL RUDOLF PROF DR , DOERR MICHAEL , EICH MANFRED DR
IPC: G02F1/35 , C08F8/00 , C08F8/30 , C08F26/00 , C08F222/40 , C08F226/02 , C09K19/38 , G02F1/355 , G02F1/361
Abstract: Copolymers of formula (I), based on dicarboxylic acid imides, alkenyl isocyanates and/or alkenyl urethanes are claimed, as are also (i) prepn. of (I) by free radical polymerisation of 30-70 mol.% monomer of formula (III) corresp. to the `b' units and 70-30 mol.% cyclic monomer of formula (IV) corresp to the `c' units, opt. with up to 50 mol.% comonomer, the copolymer thus obtd. then being reacted with H-X-Y-Z; and (ii) use of (I) in non-linear optics. In formulae (I), (III) and (IV), R -R = H or 1-20C alkyl (opt. substd. and/or opt. contg. a heteroatom); R = H, 1-10C alkyl (opt. substd. by Ph or OH), phenyl or benzyl (each opt. substd. by one to four 1-6C alkyl or alkoxy gps), 3-8C cycloalkyl, phenylethyl, diphenylmethyl, naphthyl, carbazoyl, isobornyl, adamantyl or 9-fluorenyl; X = O or NH; Y = 1-20C alkylene, (-CH2O)n-, -(CH2CH2O)n- or -(CH2CH(Me)O)n-, with n = 1-15; Z = H or an opt. substd. residue D with nonlinear optical (NLO) properties; M = comonomer; a and c = 0.3-0.7; and b and d = 0-0.3, with a+b+c+d = 1.
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公开(公告)号:DE19713638A1
公开(公告)日:1998-10-08
申请号:DE19713638
申请日:1997-04-02
Applicant: BASF AG
Inventor: KELLER HARALD DR , MAXEIN GEORG , MUELLER MANFRED DR , ZENTEL RUDOLF PROF DR
IPC: C08B13/00 , C09B67/00 , C09D5/36 , C09D101/32 , C09K19/00 , C09K19/38 , C08J3/28 , C09B67/20 , C09D11/02 , C09D17/00
Abstract: The invention relates to liquid crystalline or cholesteric mixed esters of a) hydroxyalkyl ethers of cellulose with b) saturated aliphatic or aromatic carboxylic acids and c) unsaturated mono- or dicarboxylic acids. The invention also relates to polymers obtained by radiation curing of the inventive mixed esters and to coating compounds, especially lacquers, containing the inventive mixed esters or pigments.
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公开(公告)号:DE4408199A1
公开(公告)日:1995-09-14
申请号:DE4408199
申请日:1994-03-11
Applicant: BASF AG
Inventor: BECKMANN STEFAN DR , ZENTEL RUDOLF PROF DR , DOERR MICHAEL , EICH MANFRED DR
IPC: G02F1/35 , C08F8/00 , C08F8/30 , C08F26/00 , C08F222/40 , C08F226/02 , C09K19/38 , G02F1/355 , G02F1/361 , C09B69/10
Abstract: Copolymers of formula (I), based on dicarboxylic acid imides, alkenyl isocyanates and/or alkenyl urethanes are claimed, as are also (i) prepn. of (I) by free radical polymerisation of 30-70 mol.% monomer of formula (III) corresp. to the `b' units and 70-30 mol.% cyclic monomer of formula (IV) corresp to the `c' units, opt. with up to 50 mol.% comonomer, the copolymer thus obtd. then being reacted with H-X-Y-Z; and (ii) use of (I) in non-linear optics. In formulae (I), (III) and (IV), R -R = H or 1-20C alkyl (opt. substd. and/or opt. contg. a heteroatom); R = H, 1-10C alkyl (opt. substd. by Ph or OH), phenyl or benzyl (each opt. substd. by one to four 1-6C alkyl or alkoxy gps), 3-8C cycloalkyl, phenylethyl, diphenylmethyl, naphthyl, carbazoyl, isobornyl, adamantyl or 9-fluorenyl; X = O or NH; Y = 1-20C alkylene, (-CH2O)n-, -(CH2CH2O)n- or -(CH2CH(Me)O)n-, with n = 1-15; Z = H or an opt. substd. residue D with nonlinear optical (NLO) properties; M = comonomer; a and c = 0.3-0.7; and b and d = 0-0.3, with a+b+c+d = 1.
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