COMPOSITIONS WITH IMPROVED UREASE-INHIBITING EFFECT COMPRISING (THIO)PHOSPHORIC ACID TRIAMIDE AND FURTHER COMPOUNDS
    1.
    发明申请
    COMPOSITIONS WITH IMPROVED UREASE-INHIBITING EFFECT COMPRISING (THIO)PHOSPHORIC ACID TRIAMIDE AND FURTHER COMPOUNDS 审中-公开
    具有改善的包含(THIO)磷酸三酰胺和其他化合物的促进抑制作用的组合物

    公开(公告)号:WO2015001457A2

    公开(公告)日:2015-01-08

    申请号:PCT/IB2014062667

    申请日:2014-06-27

    Abstract: An composition comprising: (A) a mixture comprising at least one (thio)phosphoric acid triamide according to the general formula (I) R1R2 N–P(X)(NH2 )2 wherein X is oxygen or sulfur; R1 is a C1 to C20 alkyl, C3 to C20 cycloalkyl, C6 to C20 aryl, or dialkylaminocarbonyl group; R2 is H, or R1 and R2 together with the nitrogen atom linking them define a 5-or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur, and (C) at least one amine selected from the group consisting of (C1) a polymeric polyamine,and (C2) an amine containing not more than one amino group and at least three alkoxy- or hydroxy-substituted C2 to C12 alkyl groups R21, wherein at least one of the groups R21 is different to the other groups R21, and (C3) an amine containing not more than one amino group and at least two alkoxy-or hydroxy-substituted C2 to C12 alkyl groups R22, wherein at least one of the groups R22 bears the alkoxy or hydroxy substituent at a secondary or tertiary carbon atom and wherein at least one of the groups R22 is different to the other group(s) R22,and (C4) an amine containing at least one saturated or unsaturated C8 to C40 alkyl group R23, and (C5) a saturated or unsaturated heterocyclic amine which contains at least one oxygen atom as ring atom and which does not contain a further alkoxy group.

    Abstract translation: 一种组合物,其包含:(A)包含至少一种根据通式(I)R 1 R 2 N-P(X)(NH 2)2的(硫代)磷酸三酰胺的混合物,其中X是氧或硫; R1是C1至C20烷基,C3至C20环烷基,C6至C20芳基或二烷基氨基羰基; R2是H,或R1和R2与连接它们的氮原子一起定义5-或6-元饱和或不饱和杂环基,其任选地包含1或2个另外选自氮,氧和硫的杂原子, 和(C)至少一种选自(C1)聚合多胺和(C2)含有不多于一个氨基和至少三个烷氧基或羟基取代的C 2至C 12烷基R 21的胺的胺 ,其中基团R21中的至少一个不同于其它基团R21,和(C3)含有不多于一个氨基和至少两个烷氧基或羟基取代的C 2至C 12烷基R 22的胺,其中至少 R 22中的一个在仲或叔碳原子上具有烷氧基或羟基取代基,并且其中基团R22中的至少一个不同于另一个基团R 22,和(C 4)含有至少一个饱和或 不饱和C8〜C40烷基R23,( C5)饱和或不饱和的杂环胺,其含有至少一个氧原子作为环原子,并且不含有另外的烷氧基。

    CHEMICAL CONVERSION METHOD WITH THE ADDITION OF METAL HALIDES
    2.
    发明申请
    CHEMICAL CONVERSION METHOD WITH THE ADDITION OF METAL HALIDES 审中-公开
    加入金属卤化物的化学实施方法

    公开(公告)号:WO2014135444A3

    公开(公告)日:2014-10-30

    申请号:PCT/EP2014053888

    申请日:2014-02-27

    Applicant: BASF SE

    Abstract: The invention relates to a method, preferably an isomerization method, for chemically converting at least one hydrocarbon in the presence of an ionic liquid. The chemical conversion is carried out in a device (V1), and at least one metal halide, preferably aluminum halide, is added into the device (V1) periodically or continuously. The anion of the ionic liquid which is used comprises at least one metal component and at least one halogen component. The anion of the ionic liquid matches the metal halide added into the device (V1) with regard to the respective halogen component and the metal component. Among others, the ionic liquid used in the respective chemical conversion, in particular in an isomerization method, can be regenerated using the method according to the invention.

    Abstract translation: 本发明涉及至少一种烃在离子液体存在下的化学转化方法,优选异构化方法。 化学反应在装置(V1)中进行,其中装置(V1)连续地或连续地加入至少一种金属卤化物,优选卤化铝。 所用离子液体的阴离子包含至少一种金属组分和至少一种卤素组分。 在这种情况下,添加到装置(V1)中的离子液体和金属卤化物的阴离子相对于各自的卤素组分和金属组分是相同的。 借助于根据本发明的方法,特别是在异构化中,可以(尤其是)再生用于特定化学反应的离子液体。

    METHOD FOR PRODUCING CYCLOHEXANE BY USING STARTING MATERIALS ORIGINATING FROM A STEAM CRACKING PROCESS
    4.
    发明申请
    METHOD FOR PRODUCING CYCLOHEXANE BY USING STARTING MATERIALS ORIGINATING FROM A STEAM CRACKING PROCESS 审中-公开
    用蒸汽裂解过程得到的提取物制备环己烷的方法

    公开(公告)号:WO2014060460A3

    公开(公告)日:2014-06-26

    申请号:PCT/EP2013071601

    申请日:2013-10-16

    Applicant: BASF SE

    Abstract: The invention relates to a method for producing cyclohexane by isomerizing a hydrocarbon mixture (KG1) containing methylcyclopentane (MCP) in the presence of a catalyst. The catalyst is preferably an acidic ionic liquid. A flow (S1) originating from a steam cracking process is used as a starting material. The hydrocarbon mixture (KG1) is obtained from said stream (S1) in a device for removing aromatics. The hydrocarbon mixture has a reduced aromatic content in comparison with the flow (S1). (KG1) can also be (nearly) free of aromatics. In dependence on the type and amount of the aromatics remaining in the hydrocarbon mixture (KG1), in particular if benzene is present, a hydrogenation of (KG1) additionally can be performed before the isomerization. Furthermore, additional purification steps can optionally be performed before or after the isomerization or hydrogenation in dependence on the presence of other components of (KG1). Preferably high-purity cyclohexane (in accordance with specifications) is isolated from the hydrocarbon mixture (KG2) arising during the isomerization, wherein the specifications are given, for example, by the use of the cyclohexane for the production of caprolactam known to the person skilled in the art.

    Abstract translation: 本发明涉及一种通过在催化剂存在下使含有甲基环戊烷(MCP)的烃混合物(KG1)异构化来制备环己烷的方法。 该催化剂优选为酸性离子液体。 使用的原料是来源于蒸汽裂化过程的物流(S1)。 从此流(S1),在一种用于具有降低的芳族含量相对于所述功率(S1),任选的(KG1)可以(几乎)是不含芳烃的芳烃分离而获得的烃类混合物(KG1)。 取决于残留在烃混合物(KG1)中的芳族化合物的性质和量,特别是在苯的存在下,(KG1)的氢化可以另外在异构化之前进行。 另外,取决于(KG1)的其它组分的存在,进一步的纯化步骤可以任选地在异构化或氢化之前或之后进行。 从异构化期间获得的烃混合物(KG2)优选是分离的高纯度(规格)环己烷,规格例如通过使用环己烷来制备己内酰胺以生产技术人员已知的。

    Composiciones con efecto mejorado de inhibición de ureasa que comprenden triamida de ácido (tio)fosfórico y compuestos adicionales

    公开(公告)号:ES2741280T3

    公开(公告)日:2020-02-10

    申请号:ES14819297

    申请日:2014-06-27

    Applicant: BASF SE

    Abstract: Una composicion que comprende: (A) una mezcla que comprende al menos una triamida de acido (tio)fosforico de acuerdo con la formula general (I) R1R2N-P(X)(NH2)2, en la que X es oxigeno o azufre; R1 es un grupo alquilo C1 a C20, cicloalquilo C3 a C20, arilo C6 a C20 o dialquilaminocarbonilo; R2 es H, o R1 y R2, junto con el atomo de nitrogeno que los une, definen un radical heterociclico saturado o insaturado de 5 o 6 miembros, que opcionalmente comprende 1 o 2 heteroatomos adicionales seleccionados del grupo que consiste en nitrogeno, oxigeno y azufre, Y (C) al menos una amina seleccionada del grupo que consiste en (C1) una poliamina polimerica, y (C2) una amina que contiene no mas de un grupo amino y al menos tres grupos R21 alquilo C2 a C12 sustituidos con alcoxi o hidroxi, en la que al menos uno de los grupos R21 es diferente de los otros grupos R21, y (C3) una amina que contiene no mas de un grupo amino y al menos dos grupos R22 alquilo C2 a C12 sustituidos con alcoxi o hidroxi, en la que al menos uno de los grupos R22 tiene el sustituyente alcoxi o hidroxi en un atomo de carbono secundario o terciario y en la que al menos uno de los grupos R22 es diferente de los otros grupos R22, y (C4) una amina que contiene al menos un grupo alquilo saturado o insaturado C8 a C40 R23, y (C5) una amina heterociclica saturada o insaturada que contiene al menos un atomo de oxigeno como atomo del anillo y que no contiene un grupo alcoxi adicional.

    COMPOSITIONS WITH IMPROVED UREASE-INHIBITING EFFECT COMPRISING (THIO)PHOSPHORIC ACID TRIAMIDE AND FURTHER COMPOUNDS

    公开(公告)号:CA2916529C

    公开(公告)日:2021-05-25

    申请号:CA2916529

    申请日:2014-06-27

    Applicant: BASF SE

    Abstract: An composition comprising: (A) a mixture comprising at least one (thio)phosphoric acid triamide according to the general formula (I) R1R2 NP(X)(NH2 )2 wherein X is oxygen or sulfur; R1 is a C1 to C20 alkyl, C3 to C20 cycloalkyl, C6 to C20 aryl, or dialkylaminocarbonyl group; R2 is H, or R1 and R2 together with the nitrogen atom linking them define a 5-or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur, and (C) at least one amine selected from the group consisting of (C1) a polymeric polyamine,and (C2) an amine containing not more than one amino group and at least three alkoxy- or hydroxy-substituted C2 to C12 alkyl groups R21, wherein at least one of the groups R21 is different to the other groups R21, and (C3) an amine containing not more than one amino group and at least two alkoxy-or hydroxy-substituted C2 to C12 alkyl groups R22, wherein at least one of the groups R22 bears the alkoxy or hydroxy substituent at a secondary or tertiary carbon atom and wherein at least one of the groups R22 is different to the other group(s) R22,and (C4) an amine containing at least one saturated or unsaturated C8 to C40 alkyl group R23, and (C5) a saturated or unsaturated heterocyclic amine which contains at least one oxygen atom as ring atom and which does not contain a further alkoxy group.

    تركيبات ذات تأثير تثبيط-إنزيم يورياز محسن تشتمل على تراي أميد حمض (ثيو)فوسفوريك ومركبات إضافية

    公开(公告)号:SA516370350B1

    公开(公告)日:2018-09-25

    申请号:SA516370350

    申请日:2016-01-04

    Applicant: BASF SE

    Abstract: يتعلقالاختراعالحاليبالمجالالتقنيلتركيباتمثبطيورياز‏urease inhibitor compositions‏‏المستخدمةفيمجالالزراعة،بصفةخاصةتركيباتذاتتأثيرتثبيط- يوريازمحسنتشتملعلى‏ترايأميدحمض (ثيو)فوسفوريك‏‎(thio)phosphoric acid triamide‎‏ومركباتإضافيةوباستخدام‏تلكالتركيباتكمادةإضافة‏additive‏أومادةطلاء‏coating material‏لأسمدةتحتويعلى‏نيتروجين‏nitrogen-containing fertilizers‏. يشملالاختراعتركيبةمشتملةعلى (‏A‏) خليط‏يشتملعلىترايأميدحمض (ثيو) فوسفوريك‏‎(thio)phosphoric acid triamide‎‏واحدعلىالأقل‏وفقاللصيغةالعامة (‏I‏) و‎(B)‎‏بوليأمينبوليمري‏polymeric polyamine‏. إضافةلذلك،يشمل‏الاختراعالحاليتركيبةتشتملعلى (‏A‏) خليطيشتملعلىترايأميدحمض (ثيو)فوسفوريك‏‎(thio)phosphoric acid triamide‎‏واحدعلىالأقلوفقاللصيغةالعامة‏I‏و‎(D)‎‏‏N،N‏- دايألكيل‏أميد‏N,N-dialkyl amide‏بناءعلىحمضلاكتيك‏lactic acid،حمضسيتريك‏citric acid،‏حمضطرطريك‏tartaric acid،حمضريسينوليك‏ricinoleic acid، 12-هيدروكسيحمض‏ستياريك‏‎12-hydroxy stearic acid،

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