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公开(公告)号:DE10137100B4
公开(公告)日:2005-07-07
申请号:DE10137100
申请日:2001-07-30
Applicant: INFINEON TECHNOLOGIES AG
Inventor: HOHLE CHRISTOPH , ROTTSTEGGE JOERG , ESCHBAUMER CHRISTIAN , SEBALD MICHAEL
Abstract: Chemically amplified photoresists exhibit increased transparency at a wavelength of 157 nm. The chemically amplified photoresist includes a polymer containing first repeating units derived from a cinnamic acid or a cinnamic ester, which are at least monofluorinated or substituted by fluoroalkyl groups. Processes for structuring substituents using transparency enhancement of resist copolymers for 157 nm photolithography using fluorinated cinnamic acid derivatives are also included.
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公开(公告)号:DE10259057A1
公开(公告)日:2004-07-15
申请号:DE10259057
申请日:2002-12-17
Applicant: INFINEON TECHNOLOGIES AG
Inventor: ELIAN KLAUS , ESCHBAUMER CHRISTIAN , JUTGLA ANGELA , HEUSINGER NICOLE , KERN MARION
Abstract: A photoresist composition containing, as carrier polymer, a copolymer of tert.-butyl methacrylate and 3-heptaisobutyl-POSS-propyl methacrylate (RTM: acrylic monomer with a polycyclic octasiloxane group in the side chain). A photo-resist composition (I) containing (a) a carrier polymer of formula (II), (b) a selected photo-acid generator and (c) a solvent. R = alkyl; x, y = 0.1-0.9 An Independent claim is also included for a method for the production of a photo-mask by coating a mask blank with composition (I), inscribing the blank, developing the composition on the blank and then plasma-etching the blank, preferably using a gas mixture containing oxygen and chlorine for the plasma.
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公开(公告)号:DE10142600A1
公开(公告)日:2003-04-03
申请号:DE10142600
申请日:2001-08-31
Applicant: INFINEON TECHNOLOGIES AG
Inventor: ROTTSTEGGE JOERG , HOHLE CHRISTOPH , ESCHBAUMER CHRISTIAN , SEBALD MICHAEL , DOMKE WOLF DIETER
Abstract: A chemically-enhanced photoresist comprising polymer, photo-acid generator and solvent, in which the polymer contains organosilyl side chains in addition to acid-labile groups and anchor groups for attachment of a post-enhancement agent. A chemically-enhanced photo-resist comprising (a) a polymer with (a1) acid-labile groups attached to polar groups, resulting in increased solubility of the polymer in polar developers after cleavage of the acid-labile groups and (a2) anchor groups for attachment of a post-enhancement agent, (b) a photo-acid generator and (c) a solvent. The polymer contains first repeat units of formula (I). A = a single bond, -O- or -COO-; B = -(CR R )n-, -(OCR R )n-, 5-20C cycloalkylene or 6-22C arylene, with the proviso that B is a CH2 group and R is H if A is a single bond, and that A and B do not form a Si-O-C group; R = H, 1-10C alkyl, CN or CF3; R -R = H, 1-10C alkyl, 5-20C cycloalkyl or 6-22C aryl (all optionally with acid-cleavable groups attached via ether links, ester links or acetals), or a siloxane group (not simultaneously methyl); R , R = 1-10C alkyl; n = 0-6. An Independent claim is also included for a method for the production of structured resists by (a) coating the above photo-resist onto a substrate; (b) removing solvent to form a light-sensitive film; (c) exposing parts of the film so as to liberate acid in the exposed parts; (d) contrasting the exposed film, with cleavage of acid-labile groups by the liberated acid; (e) developing with a developer to remove the exposed parts and form a structured resist; (f) optionally releasing the anchor groups; (g) applying a post-enhancer; and (h) removing excess post-enhancer.
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公开(公告)号:DE10131144A1
公开(公告)日:2003-04-03
申请号:DE10131144
申请日:2001-06-28
Applicant: INFINEON TECHNOLOGIES AG
Inventor: ROTTSTEGGE JOERG , ESCHBAUMER CHRISTIAN , HOHLE CHRISTOPH , HERBST WALTRAUD , SEBALD MICHAEL
Abstract: A process for the post-exposure amplification of resist structures uses amplification of resist structures of fluorinated resist polymers by structural growth of the structures by targeted chemical bonding of fluorinated oligomers. In the first step, a fluorine-containing resist is applied to a substrate. After exposure and development of the resist, bonding of an amplification agent chemically amplifies the resist structures. A fluorine-containing amplification agent is preferably used to achieve an improved reaction between polymer and amplification agent due to the improved miscibility of the molecular chains.
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公开(公告)号:DE10137100A1
公开(公告)日:2003-02-27
申请号:DE10137100
申请日:2001-07-30
Applicant: INFINEON TECHNOLOGIES AG
Inventor: HOHLE CHRISTOPH , ROTTSTEGGE JOERG , ESCHBAUMER CHRISTIAN , SEBALD MICHAEL
Abstract: Chemically-enhanced photo-resist (I) comprising a polymer with acid-labile groups which undergo cleavage to polar groups so as to increase solubility in aqueous alkaline developers, plus a photo-acid former and solvent, in which the polymer contains first repeat units derived from at least mono-fluorinated or fluoroalkyl-substituted cinnamic acid or cinnamate esters. An Independent claim is also included for a method for structuring substrates by coating the substrate with (I), exposing parts of the resulting photo-resist film to light with a wavelength of less than 200 nm and developing the exposed film to form a structure which is transferred to the substrate.
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公开(公告)号:DE10135246A1
公开(公告)日:2003-02-20
申请号:DE10135246
申请日:2001-07-19
Applicant: INFINEON TECHNOLOGIES AG
Inventor: ESCHBAUMER CHRISTIAN , HOHLE CHRISTOPH , SEBALD MICHAEL , ROTTSTEGGE JOERG
Abstract: A photoresist including a polymer obtained by polycondensation of at least one monomer with acid cleavable groups in its main chain, where at least one of the monomers contains one or more fluorine or fluoroalkyl groups, a photoacid builder, and a solvent is new.
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公开(公告)号:DE10131144B4
公开(公告)日:2006-01-19
申请号:DE10131144
申请日:2001-06-28
Applicant: INFINEON TECHNOLOGIES AG
Inventor: ROTTSTEGGE JOERG , ESCHBAUMER CHRISTIAN , HOHLE CHRISTOPH , HERBST WALTRAUD , SEBALD MICHAEL
Abstract: A process for the post-exposure amplification of resist structures uses amplification of resist structures of fluorinated resist polymers by structural growth of the structures by targeted chemical bonding of fluorinated oligomers. In the first step, a fluorine-containing resist is applied to a substrate. After exposure and development of the resist, bonding of an amplification agent chemically amplifies the resist structures. A fluorine-containing amplification agent is preferably used to achieve an improved reaction between polymer and amplification agent due to the improved miscibility of the molecular chains.
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公开(公告)号:DE10142590A1
公开(公告)日:2003-04-03
申请号:DE10142590
申请日:2001-08-31
Applicant: INFINEON TECHNOLOGIES AG
Inventor: ROTTSTEGGE JOERG , KUEHN EBERHARD , HERBST WALTRAUD , ESCHBAUMER CHRISTIAN , HOHLE CHRISTOPH , FALK GERTRUD , SEBALD MICHAEL
IPC: G03F7/40 , H01L21/027 , H01L21/308 , G03F7/00 , G03F7/26
Abstract: Production of resist structures comprises: applying a resist film on a substrate (1); forming a resist structure with bars from the film; and removing reinforced sections (8). The resist structure has reinforced side wall structures (6) and reinforced sections. Preferred Features: A covering layer of the bars is reinforced together with the side walls so that a reinforced covering layer is obtained which can be selectively removed. An intermediate layer is provided between two resist layers by which mixing of the resist layer is prevented.
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公开(公告)号:DE10129577A1
公开(公告)日:2003-01-16
申请号:DE10129577
申请日:2001-06-20
Applicant: INFINEON TECHNOLOGIES AG
Inventor: ROTTSTEGGE JOERG , FALK GERTRUD , ESCHBAUMER CHRISTIAN , HOHLE CHRISTOPH , SEBALD MICHAEL
Abstract: Re-amplification of resist structures uses a chemically amplified resist containing polymer (I) with acid-labile groups and (protected) anchor groups (AG) for co-ordination with amplifying agent (II), photoacid and solvent. The resist is exposed, heated, developed and treated with (II). (II) and AG each contain a polar or ionic group and form a non-covalent bond on co-ordination. Re-amplification of resist structures comprises: (1) coating a substrate with a chemically amplified resist containing a polymer (I) with acid-labile groups, which release a group increasing the solubility of (I) in aqueous alkaline developers, and also optionally protected anchor groups (AG) for co-ordination with amplifying agent (II), a photoacid and a solvent (III); (2) removing (III); (3) selective exposure to form a latent image; (4) heating to a first temperature to convert the latent image to a chemical profile; (5) development with an aqueous alkaline developer, which dissolves the areas formed by the chemical profile from the substrate, giving a structurized resist; (6) releasing AG from the protected AG if necessary; (7) applying (II) to the structurized resist; and (8) removing excess (II) by washing. (II) and AG each contain a polar or ionic group and form a non-covalent bond on co-ordination.
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公开(公告)号:DE10142600B4
公开(公告)日:2007-05-24
申请号:DE10142600
申请日:2001-08-31
Applicant: INFINEON TECHNOLOGIES AG
Inventor: ROTTSTEGGE JOERG , HOHLE CHRISTOPH , ESCHBAUMER CHRISTIAN , SEBALD MICHAEL , DOMKE WOLF DIETER
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