公开(公告)号：DE3641603C2

公开(公告)日：1996-07-04

申请号：DE3641603

申请日：1986-12-05

Applicant: KAO CORP

Inventor： NOZAKI TOSHIO ,  KUROSAKI TOMIHIRO ,  WAKATSUKI JUNYA ,  AIMONO KIYOSHI

IPC: C07F9/11 ,  C07F9/02 ,  C07F9/09 ,  C07F9/113

公开(公告)号：DE69014040D1

公开(公告)日：1994-12-15

申请号：DE69014040

申请日：1990-03-30

Applicant: KAO CORP

Inventor： FUJITA TADAAKI ,  AIMONO KIYOSHI ,  HASHIBA KUNIZO ,  OHORI KOICHI

IPC: C07H1/06 ,  C07H15/04

Abstract: A process for the production of an alkyl glycoside or an aqueous solution thereof is disclosed, comprising the steps of (1) reacting a sugar with alcohol to obtain an alkyl glycoside reaction product containing unreacted alcohol, (2) establishing a moving liquid film of the alkyl glycoside reaction product and (3) contacting the moving liquid film with steam or an inert gas at a temperature of from 50 to 200 DEG C. The alkyl glycoside or aqueous solution thus obtained contains little unreacted alcohol and is excellent in hue and odor.

公开(公告)号：ES2050292T3

公开(公告)日：1994-05-16

申请号：ES90105156

申请日：1990-03-19

Applicant: KAO CORP

Inventor： YAMAMURO AKIRA ,  AMAU MAKOTO ,  FUJITA TAKAAKI ,  AIMONO KIYOSHI ,  KIMURA AKIO

IPC: C07H15/04

Abstract: A process is disclosed for the production of an alkyl glycoside excellent in hue, which comprises (1) reacting a sugar with alcohol to obtain an alkyl glycoside reaction product containing an unreacted higher alcohol, (2) reacting the resulting product with a metal/hydrogen complex represented by formula (I) M(BH4)x (I) wherein M is an alkali metal, Ca, Zn, or (CH3)4N; and x is 1 when M is an alkali metal or (CH3)4N and x is 2 when M is Ca or Zn; (3) separating the resulting reaction mixture into the alkyl glycoside and the unreacted higher alcohol, and (4) decomposing the remaining metal/hydrogen complex with an acid.

公开(公告)号：DE69006059T2

公开(公告)日：1994-06-30

申请号：DE69006059

申请日：1990-03-19

Applicant: KAO CORP

Inventor： YAMAMURO AKIRA ,  AMAU MAKOTO ,  FUJITA TAKAAKI ,  AIMONO KIYOSHI ,  KIMURA AKIO

IPC: C07H15/04

Abstract: A process is disclosed for the production of an alkyl glycoside excellent in hue, which comprises (1) reacting a sugar with alcohol to obtain an alkyl glycoside reaction product containing an unreacted higher alcohol, (2) reacting the resulting product with a metal/hydrogen complex represented by formula (I) M(BH4)x (I) wherein M is an alkali metal, Ca, Zn, or (CH3)4N; and x is 1 when M is an alkali metal or (CH3)4N and x is 2 when M is Ca or Zn; (3) separating the resulting reaction mixture into the alkyl glycoside and the unreacted higher alcohol, and (4) decomposing the remaining metal/hydrogen complex with an acid.

公开(公告)号：CH669198A5

公开(公告)日：1989-02-28

申请号：CH485486

申请日：1986-12-05

Applicant: KAO CORP

Inventor： NOZAKI TOSHIO ,  KUROSAKI TOMIHIRO ,  WAKATSUKI JUNYA ,  AIMONO KIYOSHI

IPC: C07F9/11 ,  C07F9/02 ,  C07F9/09 ,  C07F9/113

公开(公告)号：DE69014040T2

公开(公告)日：1995-04-27

申请号：DE69014040

申请日：1990-03-30

Applicant: KAO CORP

Inventor： FUJITA TADAAKI ,  AIMONO KIYOSHI ,  HASHIBA KUNIZO ,  OHORI KOICHI

IPC: C07H1/06 ,  C07H15/04

Abstract: A process for the production of an alkyl glycoside or an aqueous solution thereof is disclosed, comprising the steps of (1) reacting a sugar with alcohol to obtain an alkyl glycoside reaction product containing unreacted alcohol, (2) establishing a moving liquid film of the alkyl glycoside reaction product and (3) contacting the moving liquid film with steam or an inert gas at a temperature of from 50 to 200 DEG C. The alkyl glycoside or aqueous solution thus obtained contains little unreacted alcohol and is excellent in hue and odor.

公开(公告)号：ES2066894T3

公开(公告)日：1995-03-16

申请号：ES90106202

申请日：1990-03-30

Applicant: KAO CORP

Inventor： FUJITA TADAAKI ,  AIMONO KIYOSHI ,  HASHIBA KUNIZO ,  OHORI KOICHI

IPC: C07H1/06 ,  C07H15/04

Abstract: A process for the production of an alkyl glycoside or an aqueous solution thereof is disclosed, comprising the steps of (1) reacting a sugar with alcohol to obtain an alkyl glycoside reaction product containing unreacted alcohol, (2) establishing a moving liquid film of the alkyl glycoside reaction product and (3) contacting the moving liquid film with steam or an inert gas at a temperature of from 50 to 200 DEG C. The alkyl glycoside or aqueous solution thus obtained contains little unreacted alcohol and is excellent in hue and odor.

公开(公告)号：DE69516527T2

公开(公告)日：2000-11-23

申请号：DE69516527

申请日：1995-09-20

Applicant: KAO CORP

Inventor： TSUYUTANI SHINJI ,  SHIBATA KENGO ,  AIMONO KIYOSHI

IPC: C07F9/02 ,  C07F9/09 ,  C07F9/11

Abstract: PCT No. PCT/JP95/01890 Sec. 371 Date Mar. 20, 1997 Sec. 102(e) Date Mar. 20, 1997 PCT Filed Sep. 20, 1995 PCT Pub. No. WO96/09305 PCT Pub. Date Mar. 28, 1997An organic hydroxyl compound is reacted with polyphosphoric acid under such conditions that the ratio, as defined by formula (1), has a value exceeding 3.2; and phosphorus pentaoxide is added to the reaction product thus obtained in such an amount that the ratio, as defined by formula (1), has a value in the range of from 2.8 to 3.2: (1) If necessary, the obtained reaction product is deodorized by the removal of the organic hydroxyl compound unreacted therefrom. The process does not give any product of high-viscous gel and therefore enables the industrially easy manufacture of a phosphoric monoester having an extremely high purity, a lowered orthophosphoric acid content, and a good odor.

公开(公告)号：DE69516527D1

公开(公告)日：2000-05-31

申请号：DE69516527

申请日：1995-09-20

Applicant: KAO CORP

Inventor： TSUYUTANI SHINJI ,  SHIBATA KENGO ,  AIMONO KIYOSHI

IPC: C07F9/02 ,  C07F9/09 ,  C07F9/11

Abstract: PCT No. PCT/JP95/01890 Sec. 371 Date Mar. 20, 1997 Sec. 102(e) Date Mar. 20, 1997 PCT Filed Sep. 20, 1995 PCT Pub. No. WO96/09305 PCT Pub. Date Mar. 28, 1997An organic hydroxyl compound is reacted with polyphosphoric acid under such conditions that the ratio, as defined by formula (1), has a value exceeding 3.2; and phosphorus pentaoxide is added to the reaction product thus obtained in such an amount that the ratio, as defined by formula (1), has a value in the range of from 2.8 to 3.2: (1) If necessary, the obtained reaction product is deodorized by the removal of the organic hydroxyl compound unreacted therefrom. The process does not give any product of high-viscous gel and therefore enables the industrially easy manufacture of a phosphoric monoester having an extremely high purity, a lowered orthophosphoric acid content, and a good odor.

公开(公告)号：DE69006059D1

公开(公告)日：1994-03-03

申请号：DE69006059

申请日：1990-03-19

Applicant: KAO CORP

Inventor： YAMAMURO AKIRA ,  AMAU MAKOTO ,  FUJITA TAKAAKI ,  AIMONO KIYOSHI ,  KIMURA AKIO

IPC: C07H15/04

Abstract: A process is disclosed for the production of an alkyl glycoside excellent in hue, which comprises (1) reacting a sugar with alcohol to obtain an alkyl glycoside reaction product containing an unreacted higher alcohol, (2) reacting the resulting product with a metal/hydrogen complex represented by formula (I) M(BH4)x (I) wherein M is an alkali metal, Ca, Zn, or (CH3)4N; and x is 1 when M is an alkali metal or (CH3)4N and x is 2 when M is Ca or Zn; (3) separating the resulting reaction mixture into the alkyl glycoside and the unreacted higher alcohol, and (4) decomposing the remaining metal/hydrogen complex with an acid.