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1.
公开(公告)号:JP2002317294A
公开(公告)日:2002-10-31
申请号:JP2002107478
申请日:2002-04-10
Applicant: LUCENT TECHNOLOGIES INC
Inventor: ABYS JOSEPH ANTHONY , BOGUSLAVSKY IRINA , STRASCHIL HEINRICH K
IPC: C25D3/56
Abstract: PROBLEM TO BE SOLVED: To provide an aqueous electroplating bath for electroplating of a palladium alloy in a mixed ligand system. SOLUTION: The first ligand forms a complex of palladium and the second ligand forms a complex of another metal, functioning to make the plating potentials of the two metals to proximate values. The palladium and the alloy metals exist as the complexes in different structures.
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公开(公告)号:JP2001107295A
公开(公告)日:2001-04-17
申请号:JP2000251780
申请日:2000-08-23
Applicant: LUCENT TECHNOLOGIES INC
Inventor: ABYS JOSEPH ANTHONY , DULLAGHAN CONOR ANTHONY , FAN CHONGLUN , SMITH BRIAN THOMAS
IPC: C25D3/12 , C25D3/56 , C25D3/62 , C25D5/12 , C25D15/00 , C25D15/02 , H01R13/00 , H01R13/03 , H05K3/24
Abstract: PROBLEM TO BE SOLVED: To provide a method for depositing a synthetic plating layer containing a noble metal having wear resistant grains and, to provide an electroplated surface finish having wear resistant grains as the one for an electric connector particularly having high reliability as for an article obtained as the result. SOLUTION: In an electric connector having a connector contact, the contact has a metal base and a surface finish layer formed on the metal base, and the surface finish layer has an electroplated synthetic having a composition of a noble metal in which wear resistant grains have been diffused.
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公开(公告)号:JP2001152385A
公开(公告)日:2001-06-05
申请号:JP2000286389
申请日:2000-09-21
Applicant: LUCENT TECHNOLOGIES INC
Inventor: ABYS JOSEPH ANTHONY , FAN CHONGLUN
Abstract: PROBLEM TO BE SOLVED: To provide a surface finish of a metallic substrate low in porosity and capable of preventing corrosion in every environment. SOLUTION: In this invention, a metallic substrate is coated with a multilayer surface finishing material containing an amorphous metallic lower layer, a corrosion resistant metallic intermediate layer and a one or more noble metal external layer in succession. In one embodiment, the metallic substrate is composed of a copper alloy, the amorphous metal lower layer is composed of Ni-P, the intermediate layer is composed of nickel, and the external layer is composed of palladium, respectively. The structure obtained as a result is particularly useful as an electric connector.
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公开(公告)号:JPH1060685A
公开(公告)日:1998-03-03
申请号:JP14911497
申请日:1997-06-06
Applicant: LUCENT TECHNOLOGIES INC
Inventor: ABYS JOSEPH ANTHONY , CHONGLUN FAN , IGOR VELJKO KADI JA
Abstract: PROBLEM TO BE SOLVED: To provide a nickel coating of a lead frame which is not cracked when applied with a stress corresponding to the packaging of an electronic device. SOLUTION: The metallic lead frame substrate of a lead frame consists of copper, copper alloy or nickel alloy, the lead frame 10 is coated with a conformal nickel coating, and the lead frame substrate is made resistant to cracking when bent through an angle of at least 82 with 150-300μm radius of curvature. When the lead frame 10 is bent by this method, the surface of the lead frame substrate is deformed. Provided that the depth of deformation does not exceed about 5μm, a crack passing through the thickness of the conformal nickel coating is not brought about.
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公开(公告)号:JP2000012755A
公开(公告)日:2000-01-14
申请号:JP16317099
申请日:1999-06-10
Applicant: LUCENT TECHNOLOGIES INC
Inventor: ABYS JOSEPH ANTHONY , BLAIR ALAN , FAN CHONGLUN
IPC: H01L23/50 , C23C28/00 , C23C28/02 , C25D3/50 , C25D3/52 , C25D5/12 , H01L21/48 , H01L21/607 , H01L23/495
Abstract: PROBLEM TO BE SOLVED: To provide a palladium surface coating suitable for wire bonding and the forming method of the palladium surface coating. SOLUTION: In this surface finish which provides an improved wire bonding efficiency on an integrated circuit package, the surface finish provided on a substrate has a palladium layer and one or more material layers 155. One or more material layers 155 are inserted between the substrate 100 and the palladium layer 150. The palladium layer 150 has a hardness which is less than 500 (KHN50), and one or more material layers 155 has a hardness of about 250 (KHN50).
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公开(公告)号:JPH11340252A
公开(公告)日:1999-12-10
申请号:JP11186199
申请日:1999-04-20
Applicant: LUCENT TECHNOLOGIES INC
Inventor: ABYS JOSEPH ANTHONY , FAN CHONGLUN
IPC: H01L21/52 , H01L23/495
Abstract: PROBLEM TO BE SOLVED: To prevent a resin from flowing to the surface of a substrate at solidification or a bonding agent, by processing an IC substrate with a material which reduces its interface energy, and decreasing the wettability on the surface of the IC substrate using the material. SOLUTION: A lead frame 100 forms an IC mounting region 110, and the region 110 is provided with a plurality of independent lead members 120 extending away from its adjoining part. An IC unit 125 is bonded to the IC mounting region 110 using a bonding agent 130, and the IC unit 125 is electrically connected to the lead frame 100 using a wire bond 135 formed between the IC unit 125 and the lead member 120. On the IC substrate of the lead frame 100, a material layer 105 which is a lower side interface energy layer is formed, and the material layer 150 decreases the wettability of the surface of the IC substrate.
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公开(公告)号:JP2002060989A
公开(公告)日:2002-02-28
申请号:JP2001173378
申请日:2001-06-08
Applicant: LUCENT TECHNOLOGIES INC
Inventor: DULLAGHAN CONOR ANTHONY , ABYS JOSEPH ANTHONY , EPSTEIN PETER , MAISANO JOSEPH JOHN
Abstract: PROBLEM TO BE SOLVED: To provide a palladium electroplating method free from the problems of the conventional method. SOLUTION: This electroplating bath includes a metal-sulfonic acid complex (where the metal is a noble metal) and free sulfonic acid. This noble metal includes Pd, Au, rigid Au (containing Ni or Co as a hardener), Pt, Rh, Ru and Ag and their alloys.
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公开(公告)号:JP2001026427A
公开(公告)日:2001-01-30
申请号:JP2000160159
申请日:2000-05-30
Applicant: LUCENT TECHNOLOGIES INC
Inventor: ABYS JOSEPH ANTHONY , DULLAGHAN CONOR ANTHONY , EPSTEIN PETER , MAISANO JOSEPH JOHN
Abstract: PROBLEM TO BE SOLVED: To obtain a replenishing agent for electroplating bath, which is low in corrosive properties by distillating a palladium nitrate solution formed from palladium and an excess amount of a nitrate solution at a specified temp. and then adding palladium sulfate and ammonium hydroxide. SOLUTION: A palladium nitrate solution is prepared by washing a prescribed amount of metal palladium with HCl of about 40 to 60 deg.C to activate the palladium and bringing the palladium into contact with an excess amount of a nitrate solution. The nitrate solution is prepared using nitric acid and the nitrate solution is used preferably in the range of about 15 to 50 g/l. The palladium nitrate solution is distilled at a low temp. of
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公开(公告)号:JP2000226686A
公开(公告)日:2000-08-15
申请号:JP2000027522
申请日:2000-02-04
Applicant: LUCENT TECHNOLOGIES INC
Inventor: ABYS JOSEPH ANTHONY , KENNETH J MULSKI , ZHANG YUN
Abstract: PROBLEM TO BE SOLVED: To provide an aq. electroplating soln. for electroplating the coating films of bright tin and tin-lead alloy solder at a high speed, especially an electroplating soln. having a simplified chemical action to minimize the effect of org. matter on the solder coating film. SOLUTION: An electroplating soln. for plating coating films of bright tin, lead or tin-lead alloy for use in high-speed electroplating contains an alkane or alkanolsulfonic acid electrolyte, a nonionic surfactant, a grain comminuting agent and two kinds of brighteners, i.e., an aromatic aldehyde and a carboxylic acid. In one way of using the electroplating soln., methanesulfonic acid is used as the sulfonic acid electrolyte, octylphenoxy(10)polyethoxyethanol as the nonioic surfactant, phenolphthalein as the grain comminuting agent, chlorobezaldehyde as the aromatic aldehyde and methacrylic acid as the carboxylic acid.
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10.
公开(公告)号:JPH11217690A
公开(公告)日:1999-08-10
申请号:JP32872498
申请日:1998-11-19
Applicant: LUCENT TECHNOLOGIES INC
Inventor: ABYS JOSEPH ANTHONY , BOGUSLAVSKY IRINA , STRASCHIL HEINRICH K
IPC: C25D3/56
Abstract: PROBLEM TO BE SOLVED: To obtain an electrochemically stable, lustrous and adhesive deposit by allowing a first ligand to form a Pd salt complex and a second ligand to form the complex of other alloy metal salts, making the electroplating reduction potential of the alloy metal close to that of Pd as compared with the alloy metal electroplating reduction potential using the first ligand only and that of Pd. SOLUTION: The alloy metal salt contains a base metal selected from a group consisting of Co and Fe, and the second ligand contains oxygen. More concretely, the one selected from mono-, di- and polycarboxylic acids or their derivatives, e.g. the acetate, citrate and ethylenediamine tetraacetate, is preferably used. The concn. of the Pd salt is appropriately controlled to >=0.01 mol/l, the first ligand should be ammonia, mono-, di- and polyamine, and the concn. is appropriately controlled to 0.01-2.0 mol/l. The plating bath is preferably controlled to pH3.0-10.0.
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