Abstract:
PROBLEM TO BE SOLVED: To provide an article made of a silicon substrate and a barrier layer which inhibits generation of gaseous chemical species of silicon by preventing water from penetrating a silicon surface, and from oxidation of the surface, when the article is exposed to an aquatic environment of high temperatures. SOLUTION: The barrier layer for the silicon substrate includes an aluminosilicate of alkaline-earth metals and an additive which can react with silica to prevent a reaction of the free silica with the barrier layer.
Abstract:
Coatings containing at least 85 % by volume crystalline mullite with less than 15 % by volume of amorphous material and mullite dissociation phases are plasma sprayed onto the surface of a silicon based ceramic substrate by closely controlling the plasma spray parameters including the mullite feed stock and its particle size, the nozzle outlet stand-off distance, movement of the substrate past the plasma flow, back side heating of the substrate and the powder feed rate through the plasma spray gun.
Abstract:
The oxidation resistance of a superalloy casting such as an equiaxed, directionally solidified, or single crystal casting, is improved by melting, pouring, or casting the alloy so as to react with a magnesium or calcium-bearing ceramic material. Magnesium or calcium is introduced into the alloy through a controlled reaction between the alloy and the magnesium or calcium-bearing ceramic material.
Abstract:
Coatings containing at least 85% by volume crystalline mullite with less than 15% by volume of amorphous material and mullite dissociation phases are plasma sprayed onto the surface of a silicon based ceramic substrate by closely controlling the plasma spray parameters including the mullite feed stock and its particle size, the nozzle outlet stand-off distance, movement of the substrate past the plasma flow, back side heating of the substrate and the powder feed rate through the plasma spray gun.
Abstract:
A bond layer (14) for use on a silicon based substrate 12 comprises an alloy comprising a refractory metal disilicide/silicon eutectic. The refractory metal disilicide is selected from the group consisting of disilicides of molybdenum, chromium, hafnium, niobium, tantalum, rhenium, titanium, tungsten, uranium, vanadium, yttrium and mixtures thereof. The refractory metal disilicide/silicon eutectic has a melting point of greater than 1300 DEG C.
Abstract:
Superalloy articles are made more oxidation resistant by a process which includes heat treating the article in the presence of foreign chemical species, at a temperature at which the foreign chemical species reacts with and modifies any oxide film present on the article surface. The heat treatment is best carried out at a temperature above the gamma prime solvus temperature of the article and below the incipient melting temperature of the article. Alternatively, the heat treatment may be carried out within the range defined by the incipient melting temperature of the article and about 150 DEG C. below the incipient melting temperature of the article. At such temperatures the foreign chemical species reacts with and modifies the oxide film on the article surface. Sulfur is then able to diffuse through such modified film, and a more oxidation resistant component is produced.
Abstract:
The oxidation resistance of a superalloy casting such as an equiaxed, directionally solidified, or single crystal casting, is improved by melting, pouring, or casting the alloy so as to react with a magnesium or calcium-bearing ceramic material. Magnesium or calcium is introduced into the alloy through a controlled reaction between the alloy and the magnesium or calcium-bearing ceramic material.
Abstract:
Superalloy articles are made more oxidation resistant by a process which includes heat treating the article in the presence of foreign chemical species, at a temperature at which the foreign chemical species reacts with and modifies any oxide film present on the article surface. The heat treatment is best carried out at a temperature above the gamma prime solvus temperature of the article and below the incipient melting temperature of the article. Alternatively, the heat treatment may be carried out within the range defined by the incipient melting temperature of the article and about 150 DEG C. below the incipient melting temperature of the article. At such temperatures the foreign chemical species reacts with and modifies the oxide film on the article surface. Sulfur is then able to diffuse through such modified film, and a more oxidation resistant component is produced.
Abstract:
OXIDATION RESISTANT SUPERALLOY CASTINGS The oxidation resistance of a superalloy casting such as an equiaxed, directionally solidified, or single crystal casting, is improved by melting, pouring, or casting the alloy so as to react with a magnesium or calcium-bearing ceramic material. Magnesium or calcium is introduced into the alloy through a controlled reaction between the alloy and the magnesium or calcium-bearing ceramic material.