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    SELECTIVELY FUNCTIONALIZED POROUS MATERIAL
    92.
    发明申请
    SELECTIVELY FUNCTIONALIZED POROUS MATERIAL 审中-公开

    公开(公告)号：US20170106362A1

    公开(公告)日：2017-04-20

    申请号：US14885514

    申请日：2015-10-16

    Applicant: International Business Machines Corporation

    Inventor： Geraud J. Dubois ,  Bruno Michel ,  Patrick Ruch ,  Sarmenio Saliba ,  Willi Volksen

    IPC: B01J35/10 ,  B01J21/08

    CPC classification number: B01J35/1061 ,  B01J21/08 ,  B01J35/1057 ,  B01J35/109

    Abstract: A porous substrate susceptible to one or both of hydroxylation and alkoxylation by a first protic solvent is exposed to a first relative pressure of the first protic solvent. The porous substrate includes a first plurality of pores having a first average pore diameter and a second plurality of pores having a second average pore diameter that is greater than the first average pore diameter. The first relative pressure is effective to one or both of hydroxylate or alkoxylate substantially only pores of the first average pore diameter to form a first modified porous substrate. The first modified porous substrate is reacted with a first functionalizing reagent that is effective to functionalize one or both of hydroxylated or alkoxylated surfaces, thereby functionalizing substantially only the first plurality of the pores, to form a first functionalized porous substrate.

    PHOTOCATALYST COATED BODY
    96.
    发明申请
    PHOTOCATALYST COATED BODY 审中-公开

    公开(公告)号：US20170087534A1

    公开(公告)日：2017-03-30

    申请号：US15281335

    申请日：2016-09-30

    Applicant: TOTO LTD.

    Inventor： Satoru KITAZAKI ,  Kyoko KATAOKA

    IPC: B01J21/06 ,  C09D7/12 ,  B01J37/02 ,  B01J35/00 ,  B01J35/02 ,  C09D1/00 ,  B01J21/08

    CPC classification number: B01J21/063 ,  B01J21/08 ,  B01J35/004 ,  B01J35/02 ,  B01J35/023 ,  B01J37/0244 ,  C09D1/00 ,  C09D7/61

    Abstract: The present invention provides a photocatalyst coated body which can realize a sufficient photocatalytic activity and adhesiveness with a substrate, without significantly impairing an appearance of a substrate, especially an exterior building material. The photocatalyst coated body has a structure including a substrate, an intermediate layer formed on the substrate, and a photocatalyst layer formed on the intermediate layer. The intermediate layer includes inorganic oxide particles having an average particle diameter of nanosize. The photocatalyst layer includes photocatalyst particles having an average particle diameter of more than 0 μm to less than 10 μm and inorganic oxide particles having an average particle diameter of nanosize. A sum of a film thickness of the intermediate layer and a film thickness of the photocatalyst layer is 0.3 μm or more to 1.5 μm or less.

    Process to make olefins and aromatics from organics
    100.
    发明授权
    Process to make olefins and aromatics from organics 有权
    从有机物中制备烯烃和芳烃的方法

    公开(公告)号：US09573859B2

    公开(公告)日：2017-02-21

    申请号：US14560451

    申请日：2014-12-04

    Applicant: TOTAL RESEARCH & TECHNOLOGY FELUY

    Inventor： Nikolai Nesterenko ,  Walter Vermeiren ,  Giacomo Grasso ,  Sander Van Donk ,  Wolfgang Garcia

    IPC: C07C1/20 ,  B01J21/16 ,  B01J27/14 ,  B01J29/89 ,  B01J29/90 ,  B01J29/80 ,  B01J21/08 ,  B01J29/18 ,  B01J29/40 ,  B01J29/65 ,  B01J38/12 ,  C07C1/26 ,  C07C1/32 ,  C07C2/86 ,  C07C4/06

    CPC classification number: C07C1/20 ,  B01J21/08 ,  B01J21/16 ,  B01J27/14 ,  B01J29/18 ,  B01J29/40 ,  B01J29/65 ,  B01J29/90 ,  B01J38/12 ,  B01J2229/16 ,  B01J2229/18 ,  B01J2229/36 ,  B01J2229/37 ,  C07C1/26 ,  C07C1/322 ,  C07C2/864 ,  C07C4/06 ,  C07C2529/40 ,  Y02P20/584 ,  Y02P30/42 ,  C07C15/02 ,  C07C11/02

    Abstract: The present invention relates to a process to make light olefins and aromatics, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising: a0) providing a first portion and a second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock, a) providing a catalyst comprising zeolitic molecular sieves containing at least 10 membered ring pore openings or larger in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting the first portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; d) separating said light olefins from said heavy hydrocarbon fraction; e) contacting said heavy hydrocarbon fraction and the second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the OC reactor with the catalyst at conditions effective to convert at least a portion of said heavy hydrocarbon fraction and oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to light olefins and aromatics.

    Abstract translation: 本发明涉及一种在组合的XTO-OC方法中由含氧，含卤素或含硫有机原料制备轻质烯烃和芳族化合物的方法，包括：a0）提供第一部分和第二部分 所述含氧，含卤素或含硫有机原料，a）提供包含在其微孔结构中含有至少10元环孔孔或更大的沸石分子筛的催化剂，b）提供XTO反应区，OC反应 区域和催化剂再生区，所述催化剂在三个区域中循环，使得至少一部分再生催化剂通过OC反应区，OC反应区中的至少一部分催化剂通过XTO 反应区和XTO反应区中的至少一部分催化剂通入再生区; c）在有效地转化至少一部分原料以形成包含轻质烯烃的XTO反应器流出物的条件下，将XTO反应器中的含氧卤化物或含硫有机原料的第一部分与催化剂接触， 重质烃馏分; d）从所述重质烃馏分中分离出所述轻质烯烃; e）在OC反应器中将所述重质烃部分和第二部分所述含氧卤化物或含硫有机原料与所述催化剂接触，所述条件有效地将至少一部分所述重质烃部分和氧 - 含有卤化物或含硫有机原料至轻质烯烃和芳族化合物。

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