公开(公告)号：US20110305617A1

公开(公告)日：2011-12-15

申请号：US13202693

申请日：2010-02-24

Applicant: Ju-Hyung Lee ,  In-Sik Nam ,  Seong-Moon Jung ,  Jong-Sik Choi ,  Sun-Joo Kim ,  Ho-Yeon Lim ,  Joo-Hwan Seo

Inventor： Ju-Hyung Lee ,  In-Sik Nam ,  Seong-Moon Jung ,  Jong-Sik Choi ,  Sun-Joo Kim ,  Ho-Yeon Lim ,  Joo-Hwan Seo

IPC: B01D53/72 ,  B01J29/40 ,  B01J29/18 ,  B01J29/65 ,  B01J35/02 ,  B01J29/04

CPC classification number: B01J35/1019 ,  B01D53/8668 ,  B01D2255/102 ,  B01D2255/104 ,  B01D2255/50 ,  B01D2255/9205 ,  B01D2255/9207 ,  B01D2257/704 ,  B01J29/068 ,  B01J29/076 ,  B01J29/20 ,  B01J29/26 ,  B01J29/42 ,  B01J29/48 ,  B01J29/66 ,  B01J29/69 ,  B01J29/7415 ,  B01J29/7615 ,  B01J29/7815 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J35/1023 ,  B01J35/1028 ,  B01J37/0246 ,  B01J2229/42

Abstract: The present invention relates to a catalyst including a ceramic structure containing porous ceramic paper and a catalyst component supported on the ceramic structure, and to a method for removing formaldehyde using the catalyst. The present invention provides a catalyst in which a structure made of ceramic paper having excellent characteristics in terms of porosity, specific surface area, and the like is used as a support for the catalyst component to maximize an effective area for reacting the supported catalyst component with a substance to be treated, thereby improving catalyst performance. The present invention also provides a method of using the catalyst.

Abstract translation: 本发明涉及一种催化剂，包括含有多孔陶瓷纸的陶瓷结构体和负载在陶瓷结构体上的催化剂组分，以及使用该催化剂除去甲醛的方法。 本发明提供了一种催化剂，其中使用由孔隙率，比表面积等优异的特性的陶瓷纸制成的结构，作为催化剂成分的载体，使负载型催化剂成分与 待处理的物质，从​​而提高催化剂性能。 本发明还提供了使用该催化剂的方法。

公开(公告)号：US20110257006A1

公开(公告)日：2011-10-20

申请号：US13122420

申请日：2009-09-24

Applicant: Chloe Thieuleux ,  Malika Boualleg ,  Jean-Pierre Candy ,  Laurent Veyre ,  Jean-Marie Basset

Inventor： Chloe Thieuleux ,  Malika Boualleg ,  Jean-Pierre Candy ,  Laurent Veyre ,  Jean-Marie Basset

IPC: B01J35/10 ,  B01J21/08 ,  B82Y30/00

CPC classification number: B01J29/0308 ,  B01J23/42 ,  B01J23/462 ,  B01J29/041 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/18 ,  B82Y30/00 ,  C01B33/02 ,  C01G23/00 ,  C01G23/002 ,  C01P2002/72 ,  C01P2004/64 ,  C01P2004/84 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/17 ,  C07C5/03 ,  C07C2523/745 ,  C07C15/073

Abstract: The present invention relates to a process for producing a structured porous material comprising a structured inorganic framework made up of metal-oxide based walls in which nanoparticles of metal 0 are incorporated, which comprises the following steps: a) formation of a suspension of hydrophilic nanoparticles of metal 0 stabilized by non-exchangeable ligands that give the nanoparticles their hydrophilic character; b) growth of the inorganic framework from an inorganic precursor around the nanoparticles of metal 0 stabilized by the non-exchangeable hydrophilic ligands, in the presence of a pore-forming agent; and c) elimination of the pore-forming agent and at least partially of the non-exchangeable ligands that give the nanoparticles their hydrophilic character.

Abstract translation: 本发明涉及一种生产结构化多孔材料的方法，其包括由金属氧化物基壁形成的结构化无机骨架，其中纳入金属O的纳米颗粒，其包括以下步骤：a）形成亲水性纳米颗粒的悬浮液 的非可交换配体稳定的金属0，使纳米颗粒具有亲水性; b）在成孔剂存在下，通过由不可交换的亲水性配体稳定的金属0的纳米颗粒周围的无机前体生长无机骨架; 和c）消除造孔剂和至少部分不可交换的配体，使纳米颗粒具有亲水性。

公开(公告)号：US07931960B2

公开(公告)日：2011-04-26

申请号：US12372118

申请日：2009-02-17

Applicant: Michael Hesse ,  Ulrich Mueller ,  Omar Yaghi

Inventor： Michael Hesse ,  Ulrich Mueller ,  Omar Yaghi

IPC: B32B5/16

CPC classification number: F17C11/005 ,  B01J20/0244 ,  B01J20/226 ,  B01J20/28011 ,  B01J20/2803 ,  B01J20/28042 ,  B01J20/28057 ,  B01J20/3007 ,  B01J20/3035 ,  B01J20/3042 ,  B01J31/1691 ,  B01J35/1028 ,  B01J37/0009 ,  B01J2231/005 ,  B01J2531/26 ,  Y02E60/324 ,  Y10T428/249953 ,  Y10T428/249967 ,  Y10T428/24997 ,  Y10T428/25 ,  Y10T428/298

Abstract: The present invention relates to shaped bodies containing a metal-organic framework material (MOF) as well as a process for the preparation thereof and their use especially as catalyst or storage medium.

Abstract translation: 本发明涉及含有金属 - 有机骨架材料（MOF）的成型体以及其制备方法及其特别用作催化剂或储存介质的用途。

公开(公告)号：US20090227814A1

公开(公告)日：2009-09-10

申请号：US12392122

申请日：2009-02-25

Applicant: Masahiro HOSHINO ,  Nobufumi Watanabe ,  Keisuke Sugita

Inventor： Masahiro HOSHINO ,  Nobufumi Watanabe ,  Keisuke Sugita

IPC: C07C35/08 ,  C07C45/33

CPC classification number: B01J35/1061 ,  B01J23/38 ,  B01J23/70 ,  B01J23/75 ,  B01J29/0308 ,  B01J35/1023 ,  B01J35/1028 ,  B01J37/0018 ,  B01J37/033 ,  B01J37/10 ,  B01J2229/32 ,  C07C29/50 ,  C07C45/33 ,  C07C2601/14 ,  C07C35/08 ,  C07C49/403

Abstract: An object of the present invention is to provide a method capable of producing a cycloalkanol and/or a cycloalkanone with a favorable selectivity coefficient by oxidizing a cycloalkane with a favorable conversion ratio.Disclosed is a method for producing a cycloalkanol and/or a cycloalkanone, which comprises oxidizing a cycloalkane with oxygen in the presence of a mesoporous silica which contains at least one transition metal and has been also subjected to contact treatment with an amine and/or ammonia. Preferably, a crystal obtained by mixing a compound containing the metal, a silicon compound, a structure-directing agent and water is subjected to contact treatment with an amine and/or ammonia and then fired to obtain a mesoporous silica, and a cycloalkane is oxidized with oxygen in the presence of the mesoporous silica.

Abstract translation: 本发明的目的是提供一种通过以良好的转化率氧化环烷烃，能够制备具有良好选择性系数的环烷醇和/或环烷酮的方法。 公开了一种制备环烷醇和/或环烷酮的方法，其包括在含有至少一种过渡金属的介孔二氧化硅的存在下用氧氧化环烷烃，并且还已经用胺和/或氨进行接触处理 。 优选将通过混合含有金属，硅化合物，结构导向剂和水的化合物得到的晶体与胺和/或氨进行接触处理，然后烧制以获得介孔二氧化硅，并且环烷烃被氧化 在介孔二氧化硅存在下用氧气。

公开(公告)号：US20070287875A1

公开(公告)日：2007-12-13

申请号：US11383660

申请日：2006-05-16

Applicant: TA YEN CHING ,  JEFFERY GEE ,  RUTHANN M. HICKOX

Inventor： TA YEN CHING ,  JEFFERY GEE ,  RUTHANN M. HICKOX

IPC: C07C5/25 ,  C07C5/23 ,  B01J29/04

CPC classification number: B01J21/08 ,  B01J29/0308 ,  B01J29/041 ,  B01J31/0209 ,  B01J31/0225 ,  B01J31/0231 ,  B01J31/0232 ,  B01J31/0274 ,  B01J31/0275 ,  B01J31/1633 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J2229/32 ,  C07C5/2562 ,  C07C2531/025 ,  C07C2531/04 ,  C07C11/02

Abstract: A process for selectively making 2-alkenes from a NAO using a mesoporous catalyst that has been surface modified with a Brönsted acid compound. The Brönsted acid compound has a reactive silane connector, an organic linking group, and a Brönsted acid group. The mesoporous catalyst has an average pore diameter in a range of about 12 to about 100 Angstroms and a surface area of between about 400 to about 1400 m2/gram.

Abstract translation: 使用已经用布朗斯台德酸化合物表面改性的介孔催化剂从NAO选择性制备2-烯烃的方法。 布朗斯台德酸化合物具有反应性硅烷连接剂，有机连接基团和布朗斯台德酸基团。 介孔催化剂的平均孔径在约12至约100埃的范围内，表面积为约400至约1400平方米/克。

公开(公告)号：US20070172417A1

公开(公告)日：2007-07-26

申请号：US11642895

申请日：2006-12-21

Applicant: Qinglin Zhang ,  Ying Wu ,  Gregory Smith ,  Michael Binder

Inventor： Qinglin Zhang ,  Ying Wu ,  Gregory Smith ,  Michael Binder

IPC: B01J21/02

CPC classification number: B01J35/1009 ,  B01J21/18 ,  B01J23/8913 ,  B01J23/892 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1061 ,  C01B3/065 ,  H01M8/065 ,  Y02E60/362

Abstract: Supported catalysts and methods are provided to promote hydrogen generation from the hydrolysis of boron hydrides. The supported catalysts contain a supported metal comprising at least one transition metal selected from the group consisting of cobalt, ruthenium, zinc, molybdenum, manganese, titanium, tin, cadmium, and iridium, in an amount of from about 0.1 to about 20% by weight of the supported catalyst.

Abstract translation: 提供了支持的催化剂和方法以促进氢化硼水解产生氢气。 载体催化剂含有至少一种选自钴，钌，锌，钼，锰，钛，锡，镉和铱的过渡金属的载体金属，其量为约0.1至约20％ 载体催化剂的重量。

公开(公告)号：US07084087B2

公开(公告)日：2006-08-01

申请号：US10691358

申请日：2003-10-22

Applicant: Zhiping Shan ,  Peter Wilhelm Gerhard Waller ,  Bowden George Maingay ,  Philip J. Angevine ,  Jacobus Cornelis Jansen ,  Chuen Y. Yeh ,  Thomas Maschmeyer ,  Frits M. Dautzenberg ,  Leonardo Marchese ,  Heloise de Oliveira Pastore

Inventor： Zhiping Shan ,  Peter Wilhelm Gerhard Waller ,  Bowden George Maingay ,  Philip J. Angevine ,  Jacobus Cornelis Jansen ,  Chuen Y. Yeh ,  Thomas Maschmeyer ,  Frits M. Dautzenberg ,  Leonardo Marchese ,  Heloise de Oliveira Pastore

IPC: B01J29/06

CPC classification number: C10G11/04 ,  B01J21/06 ,  B01J21/12 ,  B01J23/26 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J29/005 ,  B01J29/0308 ,  B01J29/04 ,  B01J29/041 ,  B01J29/084 ,  B01J29/166 ,  B01J29/18 ,  B01J29/40 ,  B01J29/60 ,  B01J29/65 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/80 ,  B01J29/85 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J35/002 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0018 ,  B01J37/033 ,  B01J37/10 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/32 ,  B01J2229/36 ,  B01J2229/42 ,  B01J2229/62 ,  C01B13/366 ,  C01B33/126 ,  C01B37/005 ,  C01B37/02 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C07C2/66 ,  C07C45/46 ,  C07D215/227 ,  C07D301/06 ,  C07D301/10 ,  C10G2/332 ,  C10G11/05 ,  C10G27/04 ,  C10G29/205 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G45/68 ,  C10G47/00 ,  C10G47/14 ,  C10G47/16 ,  C10G49/02 ,  C10G49/08 ,  C10G50/00 ,  C10G2300/1096 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/04 ,  C10G2400/10 ,  C10G2400/30 ,  C07C15/073 ,  C07C49/84

Abstract: A catalytic material includes microporous zeolites supported on a mesoporous inorganic oxide support. The microporous zeolite can include zeolite Beta, zeolite Y (including “ultra stable Y”—USY), mordenite, Zeolite L, ZSM-5, ZSM-11, ZSM-12, ZSM-20, Theta-1, ZSM-23, ZSM-34, ZSM-35, ZSM-48, SSZ-32, PSH-3, MCM-22, MCM-49, MCM-56, ITQ-1, ITQ-2, ITQ-4, ITQ-21, SAPO-5, SAPO-11, SAPO-37, Breck-6, ALPO4-5, etc. The mesoporous inorganic oxide can be e.g., silica or silicate. The catalytic material can be further modified by introducing some metals e.g. aluminum, titanium, molybdenum, nickel, cobalt, iron, tungsten, palladium and platinum. It can be used as catalysts for acylation, alkylation, dimerization, oligomerization, polymerization, hydrogenation, dehydrogenation, aromatization, isomerization, hydrotreating, catalytic cracking and hydrocracking reactions.

Abstract translation: 催化材料包括负载在介孔无机氧化物载体上的微孔沸石。 微孔沸石可以包括沸石β，沸石Y（包括“超稳定Y”-USY），丝光沸石，沸石L，ZSM-5，ZSM-11，ZSM-12，ZSM-20，Theta-1，ZSM-23， ZSM-34，ZSM-35，ZSM-48，SSZ-32，PSH-3，MCM-22，MCM-49，MCM-56，ITQ-1，ITQ-2，ITQ-4，ITQ-21，SAPO- 5，SAPO-11，SAPO-37，Breck-6，ALPO 4 -5等。介孔无机氧化物可以是例如二氧化硅或硅酸盐。 催化材料可以通过引入一些金属进一步改性，例如 铝，钛，钼，镍，钴，铁，钨，钯和铂。 可用作酰化，烷基化，二聚，低聚，聚合，氢化，脱氢，芳构化，异构化，加氢处理，催化裂化和加氢裂化反应的催化剂。

公开(公告)号：US20060149097A1

公开(公告)日：2006-07-06

申请号：US10534075

申请日：2003-11-18

Applicant: Stuart Soled ,  Andrzel Malek ,  James Vartuli ,  Jennifer Feeley ,  Sabato Miseo ,  Luo Shifang ,  Richard Schlosberg ,  Joseph Baumgartner ,  Christine Kliewer ,  Steven Ragomo

Inventor： Stuart Soled ,  Andrzel Malek ,  James Vartuli ,  Jennifer Feeley ,  Sabato Miseo ,  Luo Shifang ,  Richard Schlosberg ,  Joseph Baumgartner ,  Christine Kliewer ,  Steven Ragomo

IPC: C07C51/42

CPC classification number: C08F8/04 ,  B01J23/462 ,  B01J23/75 ,  B01J35/0053 ,  B01J35/0066 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1061 ,  B01J37/0203 ,  B01J37/08 ,  B01J37/082 ,  C07C29/19 ,  C07C67/303 ,  C07C69/75

Abstract: The present invention is directed to a process for hydrogenating one or more organic compounds especially unsaturated organic compounds by bringing the compound into contact with a hydrogen-containing gas in the presence of a catalyst, which comprises one or more catalytically active metals applied to a porous catalyst support. The one or more catalytically active metals having been derived via a decomposed organic complex of the metal on the support, in particular amine complexes of the metal. The decomposed complex may be treated with hydrogen to activate the catalyst before use as a hydrogenation catalyst.

Abstract translation: 本发明涉及一种通过在催化剂存在下使化合物与含氢气体接触来氢化一种或多种有机化合物，特别是不饱和有机化合物的方法，所述催化剂包含一种或多种催化活性金属施加到多孔 催化剂载体。 一种或多种催化活性金属已经通过载体上的金属的分解的有机络合物，特别是金属的胺络合物衍生。 分解的络合物可以用氢处理以在使用前活化催化剂作为氢化催化剂。

公开(公告)号：US20060128555A1

公开(公告)日：2006-06-15

申请号：US11350156

申请日：2006-02-08

Applicant: Zhiping Shan ,  Peter Wilhelm ,  Bowden Maingay ,  Philip Angevine ,  Jacobus Jansen ,  Chuen Yeh ,  Thomas Maschmeyer ,  Frits Dautzenberg ,  Leonardo Marchese ,  Heloise Oliveira Pastore

Inventor： Zhiping Shan ,  Peter Wilhelm ,  Bowden Maingay ,  Philip Angevine ,  Jacobus Jansen ,  Chuen Yeh ,  Thomas Maschmeyer ,  Frits Dautzenberg ,  Leonardo Marchese ,  Heloise Oliveira Pastore

IPC: B01J29/06

CPC classification number: C10G11/04 ,  B01J21/06 ,  B01J21/12 ,  B01J23/26 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J29/005 ,  B01J29/0308 ,  B01J29/04 ,  B01J29/041 ,  B01J29/084 ,  B01J29/166 ,  B01J29/18 ,  B01J29/40 ,  B01J29/60 ,  B01J29/65 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/80 ,  B01J29/85 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J35/002 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0018 ,  B01J37/033 ,  B01J37/10 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/32 ,  B01J2229/36 ,  B01J2229/42 ,  B01J2229/62 ,  C01B13/366 ,  C01B33/126 ,  C01B37/005 ,  C01B37/02 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C07C2/66 ,  C07C45/46 ,  C07D215/227 ,  C07D301/06 ,  C07D301/10 ,  C10G2/332 ,  C10G11/05 ,  C10G27/04 ,  C10G29/205 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G45/68 ,  C10G47/00 ,  C10G47/14 ,  C10G47/16 ,  C10G49/02 ,  C10G49/08 ,  C10G50/00 ,  C10G2300/1096 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/04 ,  C10G2400/10 ,  C10G2400/30 ,  C07C15/073 ,  C07C49/84

Abstract: A catalytic material includes microporous zeolites supported on a mesoporous inorganic oxide support. The microporous zeolite can include zeolite Beta, zeolite Y (including “ultra stable Y”—USY), mordenite, Zeolite L, ZSM-5, ZSM-11, ZSM-12, ZSM-20, Theta-1, ZSM-23, ZSM-34, ZSM-35, ZSM-48, SSZ-32, PSH-3, MCM-22, MCM-49, MCM-56, ITQ-1, ITQ-2, ITQ-4, ITQ-21, SAPO-5, SAPO-11, SAPO-37, Breck-6, ALPO4-5, etc. The mesoporous inorganic oxide can be e.g., silica or silicate. The catalytic material can be further modified by introducing some metals e.g. aluminum, titanium, molybdenum, nickel, cobalt, iron, tungsten, palladium and platinum. It can be used as catalysts for acylation, alkylation, dimerization, oligomerization, polymerization, hydrogenation, dehydrogenation, aromatization, isomerization, hydrotreating, catalytic cracking and hydrocracking reactions.

Abstract translation: 催化材料包括负载在介孔无机氧化物载体上的微孔沸石。 微孔沸石可以包括沸石β，沸石Y（包括“超稳定Y”-USY），丝光沸石，沸石L，ZSM-5，ZSM-11，ZSM-12，ZSM-20，Theta-1，ZSM-23， ZSM-34，ZSM-35，ZSM-48，SSZ-32，PSH-3，MCM-22，MCM-49，MCM-56，ITQ-1，ITQ-2，ITQ-4，ITQ-21，SAPO- 5，SAPO-11，SAPO-37，Breck-6，ALPO 4 -5等。介孔无机氧化物可以是例如二氧化硅或硅酸盐。 催化材料可以通过引入一些金属进一步改性，例如 铝，钛，钼，镍，钴，铁，钨，钯和铂。 可用作酰化，烷基化，二聚，低聚，聚合，氢化，脱氢，芳构化，异构化，加氢处理，催化裂化和加氢裂化反应的催化剂。

公开(公告)号：US20050031520A1

公开(公告)日：2005-02-10

申请号：US10494313

申请日：2002-11-01

Applicant: Luc Fortier ,  Pierre Fournier ,  Serge Kaliaguine ,  Do Trong On

Inventor： Luc Fortier ,  Pierre Fournier ,  Serge Kaliaguine ,  Do Trong On

IPC: B01J20/10 ,  B01J29/03 ,  B01J29/04 ,  B01J29/89 ,  B01J35/10 ,  B01J37/03 ,  C01B37/00 ,  C01B37/02 ,  C01B33/26 ,  C01B33/18

CPC classification number: C01B37/02 ,  B01J20/10 ,  B01J20/103 ,  B01J20/28083 ,  B01J29/0308 ,  B01J29/041 ,  B01J29/89 ,  B01J35/002 ,  B01J35/1028 ,  B01J35/1047 ,  B01J35/1061 ,  B01J2229/40 ,  C01B37/00 ,  C01B37/005

Abstract: Highly ordered mesoporous silica molecular materials are prepared using sodium silicate as a silica source, sulfuric acid and nonionic poly(alkylene oxide) surfactants or nonionic amphiphilic bloc copolymers as structure-directing agents. The mesoporous silica materials obtained have hexagonal and cubic structures, uniform pore size and high surface areas.

Abstract translation: 使用硅酸钠作为二氧化硅源，硫酸和非离子聚（环氧烷）表面活性剂或非离子两亲性共聚物作为结构导向剂制备高度有序的介孔二氧化硅分子材料。 获得的介孔二氧化硅材料具有六方和立方结构，孔径均匀，表面积高。