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    ANTIOXIDANT ADDITIVE COMPOSITION, A SOLUTION THEREOF, AND A METHOD FOR IMPROVING THE STORAGE STABILITY OF BIODIESEL FUEL (VARIANTS)
    95.
    发明申请
    ANTIOXIDANT ADDITIVE COMPOSITION, A SOLUTION THEREOF, AND A METHOD FOR IMPROVING THE STORAGE STABILITY OF BIODIESEL FUEL (VARIANTS) 有权
    抗氧化剂添加剂组合物及其解决方案，以及用于改善生物柴油燃料（变体）的储存稳定性的方法，

    公开(公告)号：US20130232859A1

    公开(公告)日：2013-09-12

    申请号：US13788073

    申请日：2013-03-07

    Applicant: OTKRYTOE AKTSIONERNOE OBSCHESTVO "STERLITAMAXKY NEFTEKHIMICHESKY ZAVOD"

    Inventor： Roza Minizievna SALAVATOVA ,  Nikolai Arkadievich NIYAZ

    IPC: C10L1/185 ,  C10L1/183

    CPC classification number: C10L1/1857 ,  C10L1/183 ,  C10L1/1832 ,  C10L1/1835 ,  C10L2200/0476 ,  C10L2230/081

    Abstract: This invention relates to the petrochemical industry, in particular, to a method for improving the storage stability of biodiesel fuel via using an antioxidant additive.A method for improving the storage stability of biodiesel fuel, comprising addition of an alkylphenol-based antioxidant additive via providing an initial solution that contains 6 to 48 mass % of the alkylphenol-based composition comprised of, mass %: 2,6-di-tert-butyl-4-methylcyclohexanone—0.2-0.3; 2,6-di-tert-butylphenol—0.7-6.0; 2-sec-butyl-6-tert-butyl-p-cresol—1.5-5.0; 4,6-di-tert-butyl-o-cresol—3.0-8.0; 2,4-di-tert-butylphenol—0.3-0.5; 2,4-di-tort-butyl-6-dimethylaminomethylphenol—2.0-5.0; 4,4-methylene-bis(2,6-di-tert-butylphenol)—0.1-0.3; and 2,6-di-tert-butyl-4-methylphenol—to the balance, dissolved in biodiesel fuel; and adding the solution of the composition to the biodiesel fuel to reach a concentration of the composition of from 0.002 to 1.6 mass % based on the entire biodiesel fuel solution.The technical result consists of a considerable improvement of the storage stability of biodiesel fuel with a reduced amount of the antioxidant additive. The antioxidant additive used inhibits precipitation during the shelf life of biodiesel fuel for a longer period of time.

    Abstract translation: 本发明涉及石化工业，特别涉及通过使用抗氧化剂添加剂改善生物柴油燃料的储存稳定性的方法。 一种提高生物柴油燃料的储存稳定性的方法，包括通过提供含有6〜48质量％烷基酚类组合物的初始溶液添加烷基酚类抗氧化剂添加剂，所述初始溶液含有质量％：2,6-二 - 叔丁基-4-甲基环己酮-0.2-0.3; 2,6-二叔丁基苯酚-0.7-6.0; 2-仲丁基-6-叔丁基对甲酚1.5-5.0; 4,6-二叔丁基邻甲酚-3.0-8.0; 2,4-二叔丁基苯酚-0.3-0.5; 2,4-二 - 叔丁基-6-二甲基氨基甲基苯酚2.0-5.0; 4,4-亚甲基 - 双（2,6-二叔丁基苯酚）-0.1-0.3; 和2,6-二叔丁基-4-甲基苯酚，溶解于生物柴油中; 并将该组合物的溶液添加到生物柴油燃料中，使组合物的浓度相对于整个生物柴油燃料溶液为0.002〜1.6质量％。 技术结果包括生物柴油燃料的储存稳定性的显着改善，减少了抗氧化剂添加剂的量。 使用的抗氧化添加剂在生物柴油燃料的保质期内能够更长时间地沉淀。

    Additives for Cetane Improvement in Middle Distillate Fuels
    99.
    发明申请
    Additives for Cetane Improvement in Middle Distillate Fuels 审中-公开
    中间馏分燃料十六烷改进添加剂

    公开(公告)号：US20100325944A1

    公开(公告)日：2010-12-30

    申请号：US12793463

    申请日：2010-06-03

    Applicant: Jianzhong Yang ,  Michael J. Zetlmeisl ,  Paul J. Biggerstaff

    Inventor： Jianzhong Yang ,  Michael J. Zetlmeisl ,  Paul J. Biggerstaff

    IPC: C10L1/18 ,  C10L1/23

    CPC classification number: C10L10/12 ,  C10L1/143 ,  C10L1/1616 ,  C10L1/1641 ,  C10L1/1811 ,  C10L1/1824 ,  C10L1/183 ,  C10L1/1832 ,  C10L1/1857 ,  C10L1/231 ,  C10L10/02

    Abstract: The cetane number of middle distillate fuels may be increased using an additive composition including a polymer that may be a homopolymer or copolymer of olefins, and the like, where the polymer has a weight average molecular weight ranging from about 200,000 to about 5,000,000. The additive composition also includes a free radical initiator component, which may be an alkyl nitrate such as 2-ethylhexylnitrate (2-EHN), and/or a peroxide, such as t-butyl peroxide. In one non-limiting embodiment the amount of polymer in the additive composition is greater than the free radical initiator component. A solvent is also present, which the solvent may include alcohol, an alkyl substituted phenol and/or a heavy aromatic distillate.

    Abstract translation: 中间馏分燃料的十六烷值可以使用包括可以是烯烃的均聚物或共聚物的聚合物等的添加剂组合物来提高，其中聚合物的重均分子量为约20万至约5,000,000。 添加剂组合物还包括自由基引发剂组分，其可以是硝酸烷基酯如硝酸2-乙基己酯（2-EHN）和/或过氧化物，如叔丁基过氧化物。 在一个非限制性实施方案中，添加剂组合物中的聚合物的量大于自由基引发剂组分。 还存在溶剂，溶剂可包括醇，烷基取代的苯酚和/或重芳族馏分。

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