Abstract:
The advantage of sustained wavelength accuracy and mechanical simplicity of a spectrophotometer using a photodiode array as photometric detector and a fixed diffraction grating as dispersion means may be limited to a relatively short wavelength range by problems of stray light, second order errors and overloading of the detector at portions of the wavelength range. By utilizing repeat scanning of the array, each scan being modified by using a different source lamp and correction filters, freedom from the cited problems over part of each scanned wavelength range can be effected. A computer controls the scan sequence and combines the usable portion of each scan to produce error free operation over an extended range.
Abstract:
A spectrophotometer optical section is presented which employs a fine positioning beam director which corrects for any deflections of the output beam path and accurately positions the optical beam on the detector slit of the spectrograph. The detector slit is chosen to have a size slightly smaller than the size of the optical beam at the detector slit to have high slit throughput without introducing spurious absorption. The sample cells need not be rigidly mounted thereby enabling use of a sample cell and cell holder which allows quick, easy interchange of cells.
Abstract:
A spectrophotometer which can be used selectively as a single-beam and a double-beam type and comprises a light source, a monochromator, a chopper mirror for causing the monochromatic light beam from the monochromator to alternately advance along a first and a second path, in which a reference and a sample cell are disposed respectively, a beam combiner for causing the alternate beams to advance along a common path leading to a photoelectric detector, and a mirror movable for selective positioning in and out of the monochromatic light beam between the monochromator and the chopper mirror.
Abstract:
A beam directing device is provided which employs one or more mirrors mounted on a single rotatable shaft. The orientation of the shaft controls the rotational orientation of these directing mirror(s) to direct the beam toward any of a number of sample or reference cells. Behind each cell is a cube corner which reflects the beam back to the directing mirror(s) for reflection toward the detector. In one embodiment, a shaft encoded senses the orientation of the shaft, the encoder output being servoed against a position signal to coarsely rotate the shaft in order to direct the beam to a sample cell and thence to a spectrograph slit. A pair of slit diodes detect the beam overlap on each side of the slit and their output is used to accurately position the beam on the slit to within one second of arc and correct for deviations in beam direction.
Abstract:
An optical system for a spectroscopic analyzer. The system has a light source, a detector and a sample cell connected in a line, and in the sample cell or between the sample cell and one of the other elements is a light chopper device. The light chopper has a rotating element in the form of a disc-shaped member or members which periodically block light from the light source and pass light during the times it is not blocked. The rotating element is driven by a motor on the outside of the structure.
Abstract:
Monochromatic light emitted from a monochromator is split into two light beams. These light beams are detected by a photodetector and converted into corresponding electric signals after having been transmitted, respectively, through a sample to be analyzed and a reference placed in the respective beam paths. The signal corresponding to the light beam transmitted through the sample and the signal corresponding to the light beam transmitted through the reference are converted into digital signals which are subsequently stored in respective digital storages or memories. The signal corresponding to the light beam transmitted through the reference is compared with a value in a predetermined range. The resultant value is then converted into an analog signal for operating a sensitivity regulator thereby to adjust the sensitivity of the photodetector. Thus, the signal corresponding to the light beam transmitted through the reference (reference light signal) is so controlled as to lie in a predetermined range. From the digital signals stored in the digital memory, ratio between the sample light signal and the reference light signal is arithmetically calculated by a digital processor unit for determining the transmittance of the sample. Since the reference light signal is prevented from significant variation and the calculation of the signal ratio is effected on the basis of digital technique, the measurement accuracy is remarkably enhanced.
Abstract:
A tristimulus colorimeter employs a multiplexed dual slope integrator digital voltmeter wherein unknown and reference light beams are compared by sequentially applying unknown and reference electrical signals representative of the two respective light beams to the non-inverting and inverting inputs, respectively, of the integrator amplifier. Moreover, a compensating circuit provides for compensation of the colorimeter output signals with respect to reflectance error encountered in the optics portion of the colorimeter.
Abstract:
An electronic spectrophotometer for measuring the reflectance of colored samples relative to a reference standard. A switching mirror directs light from a monochromator on a sample and a reference standard that are spaced apart. Reflections therefrom fall on a common photoelectric detector and the resultant signals are amplified, separated and indicated as a quotient between sample and standard reflectance.
Abstract:
System for periodicially shifting a light beam between two axially displaced paths consists of a rotary assembly subdivided into at least three angularly displaced segments, one of the segments allowing the beam to pass through the assembly along one path, the other two segments comprising axially aligned radially spaced oppositely directed conically shaped reflectors arranged to axially displace the beam when it impinges on one of them.
Abstract:
A spectrometer according to this disclosure includes optical means for receiving radiation from a region which may or may not contain particular materials to be monitored. Spectrum display means is provided for displaying the spectrum of received radiation. A first output means having first apertures is disposed to pass an image of absorption lines associated with the particular material being monitored, and second output means having second apertures is disposed to pass an image of continuum associated with the particular material.