公开(公告)号：US09321033B2

公开(公告)日：2016-04-26

申请号：US14376356

申请日：2013-02-04

Applicant: HEESUNG CATALYSTS CORPORATION

Inventor： Hyun-sik Han ,  Seung Chul Na ,  Sang Yun Han

IPC: B01J23/00 ,  B01J21/04 ,  B01J37/08 ,  B01J23/44 ,  B01J37/02 ,  B01J23/42 ,  B01J37/03 ,  B01D53/94 ,  B01J35/04

CPC classification number: B01J21/04 ,  B01D53/944 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/2092 ,  B01J23/42 ,  B01J23/44 ,  B01J35/04 ,  B01J37/0201 ,  B01J37/038 ,  B01J37/08

Abstract: The present invention relates to an improvement in a process for the thermal fixation of a catalytically active component onto an alumina support and, more specifically, to an improvement in a process for the thermal fixation of a catalytically active component onto an alumina support for preparing a thermally stable catalyst for treating exhaust gas from an internal combustion engine, by means of thermally stable dispersion and fixation of the catalytically active component(s) for treating exhaust gas from an internal combustion engine, onto a surface or an internal space of the alumina support.

Abstract translation: 本发明涉及一种将催化活性组分热固定到氧化铝载体上的方法的改进，更具体地说，涉及用于将催化活性组分热固定到氧化铝载体上用于制备氧化铝载体的方法的改进 用于处理来自内燃机的废气的热稳定催化剂，通过热稳定的分散和固定用于处理来自内燃机的废气的催化活性组分到氧化铝载体的表面或内部空间 。

公开(公告)号：US20160090331A1

公开(公告)日：2016-03-31

申请号：US14862296

申请日：2015-09-23

Applicant: IFP Energies Nouvelles

Inventor： Etienne GIRARD ,  Amandine CABIAC ,  Damien DELCROIX

IPC: C07B33/00 ,  B01J21/02 ,  B01J21/06 ,  B01J23/34 ,  B01J23/42 ,  B01J23/755

CPC classification number: C07B33/00 ,  B01J21/02 ,  B01J21/063 ,  B01J21/066 ,  B01J23/002 ,  B01J23/34 ,  B01J23/42 ,  B01J23/58 ,  B01J23/6562 ,  B01J23/755 ,  B01J23/78 ,  B01J23/8906 ,  B01J37/0201 ,  B01J37/0236 ,  B01J37/18 ,  C07C27/04 ,  C07C29/132 ,  C07C29/60 ,  Y02P20/52 ,  C07C31/202 ,  C07C31/205 ,  C07C31/10 ,  C07C31/207 ,  C07C31/20

Abstract: Process for transformation of a feedstock of lignocellulosic biomass and/or the carbohydrates, into mono-oxidized or poly-oxidized compounds, wherein the feedstock is contacted, simultaneously, with a catalytic system that comprises one or more homogeneous catalysts selected from Brønsted acids and heterogeneous catalysts comprising at least one metal selected from groups 6 to 11 and 14 of the periodic table, and a substrate selected from perovskites of formula ABO3, in which A is Mg, Ca, Sr, Ba, and La, and B is selected from Fe, Mn, Ti and Zr, oxides of lanthanum, neodymium, yttrium, cerium, and niobium, or mixtures thereof, and mixed oxides of aluminates of zinc, copper, and cobalt, or mixtures thereof, in the same reaction chamber, with at least one solvent, being water or water with at least one other solvent, under reducing atmosphere, and temperature of 50° C. to 300° C., and pressure of 0.5 MPa to 20 MPa.

Abstract translation: 将木质纤维素生物质和/或碳水化合物的原料转化为单氧化或多氧化化合物的方法，其中原料同时与催化体系接触，所述催化体系包含一种或多种选自布朗斯台德酸和异构体的均相催化剂 包含选自元素周期表第6至11和14族中的至少一种金属的催化剂和选自式ABO3的钙钛矿的底物，其中A是Mg，Ca，Sr，Ba和La，B选自Fe ，Mn，Ti和Zr，镧，钕，钇，铈和铌的氧化物或其混合物，以及锌，铜和钴的铝酸盐或其混合物的混合氧化物或其混合物在至少相同的反应室中 一种溶剂，在还原气氛下，在50℃至300℃，压力为0.5MPa至20MPa的情况下，与水或水一起使用至少一种其它溶剂。

公开(公告)号：US20160074848A1

公开(公告)日：2016-03-17

申请号：US14785270

申请日：2014-04-14

Applicant: LOTTE CHEMICAL CORPORATION

Inventor： Joungmo CHO ,  In Ae Kim ,  Jae Yeon LEE ,  Seung Hee KANG ,  Young Jong SEO

IPC: B01J29/40 ,  C07C1/24

CPC classification number: B01J29/405 ,  B01J37/0201 ,  B01J37/28 ,  B01J2229/186 ,  C07C1/24 ,  C07C2529/40 ,  Y02P20/52 ,  C07C11/04

Abstract: Provided are an ethanol dehydration catalyst having a high ethylene yield even at a low temperature region, as an ethanol dehydration catalyst for converting a feedstock including anhydrous ethanol or hydrous ethanol to ethylene, and a method of preparing ethylene by using the same. In the ethanol dehydration catalyst for converting a feedstock including anhydrous ethanol or hydrous ethanol to ethylene of the present invention, the catalyst includes 0.1 wt % to 0.5 wt % of lanthanum (La) or 0.05 wt % to 1 wt % of gallium (Ga) in ZSM-5.

Abstract translation: 提供即使在低温区域也具有高乙烯产率的乙醇脱水催化剂，作为用于将包含无水乙醇或含水乙醇的原料转化为乙烯的乙醇脱水催化剂，以及使用该方法制备乙烯。 在本发明的含有无水乙醇或含水乙醇的原料的乙醇脱水催化剂中，催化剂含有0.1重量％〜0.5重量％的镧（La）或0.05重量％〜1重量％的镓（Ga） 在ZSM-5。

公开(公告)号：US20160068963A1

公开(公告)日：2016-03-10

申请号：US14836750

申请日：2015-08-26

Applicant: BYD Company Limited

Inventor： Qing GONG ,  Liang ZHOU ,  Weifeng MIAO ,  Xiong ZHANG

IPC: C23C18/16 ,  C23C18/20

CPC classification number: C23C18/1608 ,  B01J23/80 ,  B01J37/0201 ,  B01J37/34 ,  B01J37/349 ,  C23C18/1612 ,  C23C18/1641 ,  C23C18/1651 ,  C23C18/1653 ,  C23C18/182 ,  C23C18/204 ,  C23C18/36 ,  C23C18/405 ,  Y10T428/12569

Abstract: The present invention discloses a method for metallizing a plastic surface. The method may comprise the steps of: 1) gasifying the plastic surface to expose the electroless plating promoter; and 2) electroless plating a layer of copper or nickel on the plastic surface, followed by electroplating or a second electroless plating to form a metallized layer on the plastic surface. Further, the present invention discloses a method for preparing a plastic article and a plastic article as manufactured by the method as described.

Abstract translation: 本发明公开了一种金属化塑料表面的方法。 该方法可以包括以下步骤：1）气化塑料表面以暴露无电镀促进剂; 和2）在塑料表面上化学镀一层铜或镍，随后进行电镀或第二无电镀，以在塑料表面上形成金属化层。 此外，本发明公开了一种通过所述方法制造的塑料制品和塑料制品的制备方法。

公开(公告)号：US09278336B2

公开(公告)日：2016-03-08

申请号：US13487879

申请日：2012-06-04

Applicant: Sung Mu Choi ,  Hyo Kyung Lee

Inventor： Sung Mu Choi ,  Hyo Kyung Lee

IPC: B01D50/00 ,  B01J21/04 ,  B01J23/38 ,  F01N3/20 ,  F01N3/022 ,  F01N3/035 ,  B01J37/02 ,  B01J35/00 ,  B01J23/42 ,  B01J29/06 ,  B01J35/04 ,  B01J35/10 ,  B01J37/00 ,  B01D53/94

CPC classification number: B01J21/04 ,  B01D53/9418 ,  B01D53/944 ,  B01D53/9468 ,  B01D2255/102 ,  B01D2255/2092 ,  B01D2255/50 ,  B01D2255/9155 ,  B01D2255/9202 ,  B01J23/38 ,  B01J23/42 ,  B01J29/06 ,  B01J35/0006 ,  B01J35/04 ,  B01J35/1019 ,  B01J37/0036 ,  B01J37/0201 ,  B01J37/0244 ,  B01J37/0246 ,  F01N3/0222 ,  F01N3/035 ,  F01N3/2066 ,  F01N2510/063 ,  F01N2510/0684 ,  Y02T10/24 ,  Y10T156/10

Abstract: An SDPF (SCR on Diesel Particular Filter) includes a porous filter collecting PM (Particulate Materials) of diesel exhaust gas, an SCR (Selective Catalytic Reduction) catalyst layer coated on an exhaust gas inlet of the filter, an aluminum oxide layer coated on an exhaust gas outlet of the filter, and a precious metal catalyst layer coated on the surface of the aluminum oxide layer, and a method for producing the same.

Abstract translation: SDPF（柴油专用过滤器SCR）包括收集柴油机废气的PM（颗粒材料）的多孔过滤器，涂覆在过滤器的废气入口上的SCR（选择性催化还原）催化剂层，涂覆在过滤器的废气入口上的氧化铝层 过滤器的废气出口和涂覆在氧化铝层的表面上的贵金属催化剂层及其制造方法。

公开(公告)号：US20160051967A1

公开(公告)日：2016-02-25

申请号：US14782878

申请日：2014-04-11

Applicant: CLARIANT CORPORATION

Inventor： Valery Sokolovskii ,  David Michael Lowe ,  Deepti Machiraju ,  Hongyi C. Hou ,  Gerhard Mestl ,  Claus G. Lugmair ,  Aaron B. Miller ,  Anthony F. Volpe, JR.

IPC: B01J23/888 ,  B01J37/02 ,  C07C253/26 ,  B01J35/10 ,  C07C45/35 ,  B01J23/00 ,  B01J37/08

CPC classification number: B01J23/8885 ,  B01J21/08 ,  B01J23/002 ,  B01J23/8872 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0201 ,  B01J37/0215 ,  B01J37/08 ,  B01J2523/00 ,  C07C45/35 ,  C07C253/26 ,  Y02P20/52 ,  B01J2523/13 ,  B01J2523/22 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/847 ,  C07C255/08 ,  C07C47/22

Abstract: The present invention relates to a method for producing a supported catalyst, a catalyst which is obtainable using the method, and use thereof for the partial oxidation or ammoxidation of olefins, in particular for the oxidation of propene to acrolein, of isobutene to methacrolein, and/or the ammoxidation of propene to acrylonitrile. The method according to the invention includes the following steps: a) providing a solution in which precursor compounds of the catalytically active component are essentially completely dissolved in a suitable solvent; b) bringing the solution obtained in step a) into contact with a (chemically) inert, porous support having a specific surface of 1 to 500 m2/g; c) heat treatment of the material obtained in step b), in which the precursor compounds of the catalytically active component are converted to their oxides.

Abstract translation: 本发明涉及负载型催化剂的制造方法，使用该方法得到的催化剂及其用于将烯烃部分氧化或氨氧化成烯烃，特别是将丙烯氧化为丙烯醛的异丁烯与甲基丙烯醛的用途，以及 /或丙烯对丙烯腈的氨氧化。 根据本发明的方法包括以下步骤：a）提供其中催化活性组分的前体化合物基本上完全溶解在合适溶剂中的溶液; b）将步骤a）中获得的溶液与具有1至500m 2 / g比表面积的（化学）惰性多孔载体接触; c）对步骤b）中获得的材料进行热处理，其中将催化活性组分的前体化合物转化为其氧化物。

公开(公告)号：US09266096B2

公开(公告)日：2016-02-23

申请号：US14411878

申请日：2013-06-28

Applicant: Abengoa Bioenergía Nuevas Technolgías, S.A.

Inventor： Ricardo Arjona Antolín ,  Juan Luís Sanz Yagüe ,  Avelino Corma Canós ,  Marcelo Eduardo Domine

IPC: B01J23/825 ,  B01J37/16 ,  C07C29/34 ,  B01J23/08 ,  B01J37/08 ,  B01J37/18 ,  B01J23/62 ,  B01J23/00 ,  B01J37/02 ,  B01J37/10 ,  B01J37/03 ,  B01J35/10

CPC classification number: B01J23/825 ,  B01J23/00 ,  B01J23/007 ,  B01J23/08 ,  B01J23/62 ,  B01J35/10 ,  B01J35/1019 ,  B01J37/02 ,  B01J37/0201 ,  B01J37/03 ,  B01J37/031 ,  B01J37/08 ,  B01J37/082 ,  B01J37/16 ,  B01J37/18 ,  B01J2523/00 ,  C07C29/34 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/32 ,  B01J2523/824 ,  C07C31/12

Abstract: The present invention relates to a process for obtaining metal oxide catalysts comprising gallium which are capable of synthesizing higher alcohols from lower alcohols. The process for obtaining said catalysts is also disclosed.

Abstract translation: 本发明涉及一种获得能够从低级醇合成高级醇的含金属氧化物催化剂的方法。 还公开了获得所述催化剂的方法。

公开(公告)号：US09266095B2

公开(公告)日：2016-02-23

申请号：US14164656

申请日：2014-01-27

Applicant: Celanese International Corporation

Inventor： Heiko Weiner ,  Zhenhua Zhou ,  Dick Nagaki

IPC: B01J23/40 ,  B01J23/58 ,  B01J23/78 ,  B01J23/75 ,  B01J23/62 ,  B01J23/648 ,  C07C1/24 ,  C07C29/149 ,  B01J37/02 ,  B01J23/42 ,  B01J23/44 ,  B01J23/89 ,  B01J35/02

CPC classification number: B01J23/75 ,  B01J23/42 ,  B01J23/44 ,  B01J23/626 ,  B01J23/6482 ,  B01J23/892 ,  B01J23/8926 ,  B01J23/8966 ,  B01J35/026 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/0244 ,  B01J2523/00 ,  C07C1/24 ,  C07C29/149 ,  C07C51/12 ,  B01J2523/23 ,  B01J2523/41 ,  B01J2523/43 ,  B01J2523/828 ,  B01J2523/845 ,  C07C31/08 ,  C07C53/08

Abstract: A process for selective formation of ethanol from acetic acid by hydrogenating acetic acid in the presence of a catalyst comprising a modified support having cobalt and an alkaline earth support modifier. The active metals may include a first metal of palladium, platinum, and combinations thereof and a second metal of copper, iron, nickel, zinc, silver, chromium, tin, and combinations thereof.

Abstract translation: 一种通过在包含具有钴和碱土载体改性剂的改性载体的催化剂存在下氢化乙酸从乙酸中选择性形成乙醇的方法。 活性金属可以包括钯，铂及其组合的第一金属和铜，铁，镍，锌，银，铬，锡及其组合的第二金属。

公开(公告)号：US20160046553A1

公开(公告)日：2016-02-18

申请号：US14779918

申请日：2014-04-01

Applicant: MITSUI CHEMICALS, INC.

Inventor： Akira MATSUURA ,  Takuro WATANABE

IPC: C07C45/00 ,  B01J31/02 ,  B01J23/44 ,  C07D223/10

CPC classification number: C07C45/006 ,  B01J21/04 ,  B01J23/44 ,  B01J23/58 ,  B01J27/24 ,  B01J31/0237 ,  B01J31/0244 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/1066 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/0238 ,  C07C45/00 ,  C07D223/10 ,  C07C49/403

Abstract: The invention has an object of providing an economical and highly efficient process for producing a cyclohexanone compound such as cyclohexanone. An aspect of the invention resides in a process for producing a cyclohexanone compound by performing hydrogenation reaction of a phenol compound in a gas phase in the presence of a palladium catalyst supported on a carrier to produce the corresponding cyclohexanone compound, wherein the hydrogenation reaction is carried out in the presence of at least one nitrogen compound selected from ammonia, amine compounds and heteroaromatic compounds.

Abstract translation: 本发明的目的是提供一种用于生产环己酮化合物如环己酮的经济且高效的方法。 本发明的一个方面在于通过在负载在载体上的钯催化剂的存在下在气相中进行酚化合物的氢化反应以制备相应的环己酮化合物来制备环己酮化合物的方法，其中进行氢化反应 在至少一种选自氨，胺化合物和杂芳族化合物的氮化合物存在下进行。

公开(公告)号：US09254476B2

公开(公告)日：2016-02-09

申请号：US14524496

申请日：2014-10-27

Applicant: BASF Corporation

Inventor： Wolfgang Ruettinger ,  Richard Jacubinas

IPC: B01J21/04 ,  B01J21/08 ,  B01J21/12 ,  B01J23/02 ,  B01J23/04 ,  B01J23/10 ,  B01J23/26 ,  C07C5/333 ,  B01J37/03 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02

CPC classification number: B01J23/26 ,  B01J21/12 ,  B01J35/023 ,  B01J35/1014 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/035 ,  C07C5/3332 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2523/04 ,  C07C2523/26 ,  Y02P20/52 ,  C07C11/06 ,  C07C11/09 ,  C07C11/02

Abstract: Provided are methods of making dehydrogenation catalyst supports containing bayerite and silica. Silica-stabilized alumina powder, prepared by spray drying of bayerite powder, precipitating silica in a bayerite slurry with an acid, or impregnation or co-extrusion of bayerite with sodium silicate solution was found to be a superior catalyst support precursor. Catalysts prepared with these silica containing support materials have higher hydrothermal stability than current CATOFIN® catalysts. Also provided is a dehydrogenation catalyst comprising Cr2O3, an alkali metal oxide, SiO2 and Al2O3, and methods of using said catalyst to make an olefin and/or dehydrogenate a dehydrogenatable hydrocarbon.

Abstract translation: 提供了制备含有三羟铝石和二氧化硅的脱氢催化剂载体的方法。 发现通过喷雾干燥三羟铝石粉末，用酸沉淀二氧化硅沉淀二氧化硅，或用硅酸钠浸渍或共挤出三羟铝石制备的二氧化硅稳定的氧化铝粉末是优异的催化剂载体前体。 用这些含二氧化硅的载体材料制备的催化剂比目前的CATOFIN®催化剂具有更高的水热稳定性。 还提供了包含Cr 2 O 3，碱金属氧化物，SiO 2和Al 2 O 3的脱氢催化剂，以及使用所述催化剂制备烯烃和/或脱氢可脱氢烃的方法。